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US 2020/0264530 A1Published application
Photoresponsive low-molecular weight material, adhesive, toner, and image forming method
AssigneeKonica Minolta, Inc.
InventorsYukiko KUSANO, Haruo HORIGUCHI, Kouji SUGAMA, Seijiro TAKAHASHI, Toyoko SHIBATA, Hirofumi HAYATA, Tomohiro OSHIYAMA
Life of this patent
Estimating the term…
Abstract
Disclosed is a compound containing a specific structure having an azomethine part, the compound being reversibly fluidized and non-fluidized by being irradiated with light.
Claims40
A compound represented by a following Chemical Formula 1, the compound being reversibly fluidized and non-fluidized by being irradiated with light:
- wherein in the Chemical Formula 1,
- X represents NR10, O, or S;
- Z1 and Z2 each independently represent N or CH, while Z1≠Z2;
- R1 and R2 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acyl group, an alkoxycarbonyl group, a cyano group, a nitro group, or a hydroxy group;
- R3 and R4 each independently represent a group represented by Chemical Formula 2, a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acyl group, an alkoxycarbonyl group, a cyano group, a nitro group, or a hydroxy group;
- wherein either of R3 and R4 is a group represented by Chemical Formula 2;
- and
- R10 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxycarbonyl group, or a hydroxy group;
- in the Chemical Formula 2,
- R5 to R9 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acyl group, an alkoxycarbonyl group, a cyano group, a nitro group, or a hydroxy group;
- and
- wherein at least one of R5 to R9 represents an alkyl group having 1 to 18 carbon atoms, an alkoxy group having 1 to 18 carbon atoms, an acyl group having 2 to 19 carbon atoms, or an alkoxycarbonyl group having 2 to 19 carbon atoms.
9 more elements
A photoresponsive compound represented by a following General Formula (1), the photoresponsive compound being fluidized by being irradiated with light and reversibly non-fluidized:
- wherein in the General Formula (1), Z1 and Z2 each independently represent N or CH, while Z1≠Z2;
- A and B each independently represent a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted aromatic heterocyclic group;
- and
- an activation energy Ea represented by a following Formula (1) is 60 kJ/mol or greater:
- Ea(kJ/mol)=(Total energy of TS(kJ/mol))−(Total energy of cis-form(kJ/mol)) Formula (1):
- wherein in the Formula (1), TS represents a transition state represented by General Formula (2);
- and the cis-form represents an isomer represented by General Formula (3):
4 more elements
Dependencies are inferred from the claim text.