Process for producing foam molded parts with aesthetic surfaces by foam injection molding
AssigneeIneos Styrolution Group GmbH
InventorsBastian RAITHEL, Norbert NIESSNER, Achim BERNHARDT, Stefan ROETTEL, Pierre JUAN, Andreas POPP
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Abstract
The invention relates to a process for producing a foam molded part, wherein a foamable material S comprising a thermoplastic polymer matrix M and at least one foaming agent F is foamed by foam injection molding. The polymer matrix M is preferably based on at least one thermoplastic styrene copolymer, such as ABS and ASA, and wherein the at least one foaming agent F is selected from chemical foaming agents, releasing carbon dioxide, and physical foaming agents, being carbon dioxide or nitrogen.
Claims15
1-16. (canceled)
A process for producing a foam molded part by foam injection molding, which comprises the following steps:
- a) providing a melt of a foamable material S comprising a thermoplastic polymer matrix M and at least one foaming agent F selected from chemical foaming agents releasing carbon dioxide and physical foaming agents selected from nitrogen and carbon dioxide,
- wherein the thermoplastic polymer matrix M comprises at least one thermoplastic styrene copolymer P consisting of, based on P:
- 1.1 5-95% by weight of a copolymer A consisting of, based on A:
- 1.1.1 70-76% by weight, of one or more vinyl aromatic monomer(s) A1 selected from styrene and substituted styrenes,
- 1.1.2 24-30% by weight, of one or more vinyl cyanide monomer(s) A2 selected from acrylonitrile, methacrylonitrile, or mixtures thereof, and
- 1.1.3 0-6% by weight, of one or more unsaturated copolymerizable monomers A3,
- 1.2 5-60% by weight of a graft rubber B consisting of, based on B:
- 1.2.1 10-95% by weight of a graft base B1 comprising, based on B1:
- 1.2.1.1 80-100% by weight of one or more rubber type monomer(s) B11 selected from butadiene, isoprene, and C1-C10 alkyl acrylates, and
- 1.2.1.2 0-20% by weight of one or more polyfunctional crosslinking monomer(s) B12, and
- 1.2.2 5-90% by weight of a graft shell B2 comprising, based on B2:
- 1.2.2.1 75-85% by weight of one or more vinyl aromatic monomer(s) B21 selected from styrene and substituted styrenes,
- 1.2.2.2 15-25% by weight of one or more vinyl cyanide monomer(s) B22 selected from acrylonitrile, methacrylonitrile, or mixtures thereof, and
- 1.2.2.3 0-10% by weight of one or more unsaturated copolymerizable monomers B23;
- b) filling a mold cavity K with the melt of the foamable material S by injection;
- c) foaming the foamable material S in the mold cavity K by reduction of pressure and/or increase in temperature;
- d) taking out the foam molded part;
- and
- e) optionally further working of the foam molded part;
- wherein the melt temperature is in the range of 255° C. to 300° C., and wherein the mold temperature is in the range of 50° C. to 150° C.
Dependencies are inferred from the claim text.