Radical generating catalyst, method for producing radical, method for producing oxidation reaction product, drug, and drug for use in agriculture and livestock industry
AssigneeAcenet Inc.
InventorsKiyoto TAKAMORI, Takekatsu SHIBATA
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Abstract
The present invention is intended to provide a radical generating catalyst that can generate (produce) radicals under mild conditions. In order to achieve the above object, the first radical generating catalyst of the present invention includes: at least one selected from the group consisting of amino acids, peptides, phospholipids, and salts thereof. The second or third radical generating catalyst of the present invention includes an ammonium salt represented by the following chemical formula (XI) (excluding peroxodisulfate) and having a Lewis acidity of 0.4 eV or more.
Claims72
A radical generating catalyst comprising:
- at least one selected from the group consisting of amino acids, proteins, peptides, phospholipids, and salts thereof, wherein
- the radical generating catalyst catalyzes radical generation from a radical source, and
- the radical source comprises an oxoacid or an ion or salt thereof.
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A radical generating catalyst comprising:
- at least one selected from the group consisting of amino acids, proteins, peptides, phospholipids, and salts thereof, and further comprising:
- ammonium, wherein
- the ammonium salt is an ammonium salt represented by the following chemical formula (XIV):
- where in the chemical formula (XIV),
- R100 may form a ring structure, which may be saturated or unsaturated, aromatic or non-aromatic, and may or may not have one or more substituents, and
- R11 is a hydrogen atom or an aromatic ring, or an alkyl group, the alkyl group may comprise an ether bond, a carbonyl group, an ester bond, or an amide bond, or an aromatic ring
- and X− is an anion (excluding peroxodisulfate ion).
A radical generating catalyst comprising:
- peptides.
A radical generating catalyst comprising:
- phospholipids.
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A radical generating catalyst comprising:
- an ammonium salt represented by the following chemical formula (XI) (excluding peroxodisulfate) and having a Lewis acidity of 0.4 eV or more, wherein
- the radical generating catalyst catalyzes radical generation from a radical source in a liquid that is not acidic, and
- the radical source is at least one selected from the group consisting of halogenous acids, halite ions, and halites:
- where in the chemical formula (XI),
- R11, R21, R31, and R41 are each a hydrogen atom or an aromatic ring, or an alkyl group, the alkyl group may comprise an ether bond, a carbonyl group, an ester bond, or an amide bond, or an aromatic ring, and R11, R21, R31, and R41 may be identical to or different from each other, or
- two or more of R11, R21, R31, and R41 may be integrated to form a ring structure with N+ to which they are bonded, and the ring structure may be saturated or unsaturated, aromatic or non-aromatic, and may or may not have one or more substituents, and
- X− is an anion (excluding peroxodisulfate ion).
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A method for producing a radical, the method comprising:
- a mixing step of mixing a Lewis acid having a Lewis acidity of 0.4 eV or more (excluding peroxodisulfate) with a radical source;
- and
- a reaction step of reacting the Lewis acid with the radical source in a liquid that is not acidic, wherein
- the radical source is at least one selected from the group consisting of halogenous acids, halite ions, and halites.
The method according to claim 66, wherein
- the halogenous acids are at least one selected from the group consisting of chlorous acid, bromous acid, and iodous acid.
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A method for producing a radical, the method comprising:
- a mixing step of mixing a Lewis acid having a Lewis acidity of 0.4 eV or more (excluding peroxodisulfate) with a radical source;
- and
- a reaction step of reacting the Lewis acid with the radical source in a liquid, wherein
- the Lewis acid having a Lewis acidity of 0.4 eV or more comprises an inorganic substance, and
- the radical source is at least one selected from the group consisting of halogenous acids, halite ions, and halites.
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Dependencies are inferred from the claim text.