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US 2020/0055984 A1Published application
Silane Modified Polymers With Improved Properties
AssigneesHenkel IP & Holding GmbH, Henkel AG & Co. KGaA
InventorsWu Suen, Andrea Keys Eodice, Claudia Meckel-Jonas, Johann Klein
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Abstract
The disclosure relates to moisture curable compositions based on a combination of silane-modified polymer and silane functional additive, their manufacture and use. The silane functional additive is preferably prepared from a water miscible polyol having a functionality of about 2 to about 4 and/or a polyol having a tertiary nitrogen atom in the backbone and a functionality equal or greater than about 2.
Claims14
A moisture curable composition comprising a physical blend of:
- a moisture curable, silane modified polymer of structure (I)
- B(-An-R—SiXYZ)I (I).
- wherein B is an organic backbone and B will not be a siloxane backbone,
- A is a divalent linking group linking the polymer backbone to the R1 group,
- I is an integer from 1 to 6,
- n is 0 or 1,
- R is a divalent C1-C12 hydrocarbon group that optionally comprises a heteroatom,
- at least one of X, Y and Z is a hydrolysable group;
- a moisture curable, silane functional additive that is the reaction product of a mixture comprising an isocyanotosilane and a polyol selected from a polyol having a linear ethylene oxide backbone and a functionality of 2 to 4, a polyol comprising at least one nitrogen atom in the backbone and a functionality equal or greater than 2 and combinations thereof, wherein the polyol is free of groups pendant from the backbone and propylene oxide;
- and
- a crosslinker;
- wherein cured reaction products of the moisture curable composition have greater strength and greater elongation compared to the moisture curable composition without the moisture curable, silane functional additive.
9 more elements
Dependencies are inferred from the claim text.