Additive for hydraulically setting compositions
AssigneeConstruction Research & Technology GmbH
InventorsTorben GÄDT, Harald GRASSL, Luc NICOLEAU, Alfons SMEETS
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Abstract
The present invention relates to an additive for hydraulically setting compositions comprising a colloidally disperse preparation comprising at least one salt of a polyvalent metal cation with at least one organic phosphonate and/or phosphate compound as anion and at least one polymeric dispersant comprising anionic and/or anionogenic groups and polyether side chains. The additive is especially suitable as slump retainer and for improving early strength.
Claims19
An additive for hydraulically setting compositions, comprising a colloidally disperse preparation comprising
- a) at least one salt of at least one polyvalent metal cation with at least one organic phosphonate and/or organic phosphate compound as anion, optionally in a mixture with at least one compound capable of releasing an inorganic anion selected from carbonate, oxalate, silicate, phosphate, polyphosphate, phosphite, borate, aluminate and sulphate, which forms a sparingly soluble salt with the polyvalent metal cation and
- b) at least one polymeric dispersant comprising anionic and/or anionogenic groups and polyether side chains,
- wherein the polyvalent metal cation selected from Al3+, Fe3+, Fe2+, Zn2+, Mn2+,Cu2+, Mg2+, Ca2+, Sr2+, Ba2+ and mixtures thereof, and wherein the metal cation is present in an amount corresponding to the following formula (a):
- 0.1
- <
- Σ
- i
-
- z
- K
- ,
- i
- *
- n
- K
- ,
- i
- Σ
- j
-
- z
- S
- ,
- j
- *
- n
- S
- ,
- j
- <
- 50.
- (
- a
- )
- where
- zK,i is the magnitude of the charge of the polyvalent metal cation,
- nK,i is the number of moles of the polyvalent metal cation weighed in,
- zS,j is the magnitude of the charge of the anionic and anionogenic group present in the polymeric dispersant,
- nS,j is the number of moles of the anionic and anionogenic group present in the polymeric dispersant weighed in,
- the indices i and j are independent of one another and are an integer greater than 0, where i is the number of different kinds of polyvalent metal cations and j is the number of different kinds of anionic and anionogenic groups present in the polymeric dispersant.
Dependencies are inferred from the claim text.