Urethane coating composition for metal substrates
AssigneeSwimc LLC
InventorsDonald W. Boespflug, Tapan DebRoy, Dan Hartinger
Life of this patent
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Abstract
A urethane composition useful in a variety of applications such as, for example, as a direct-to-metal coating, i.e. a coating composition that can be applied directly to the surface of a metal substrate without a primer or pretreatment is described. The coating composition preferably includes a polyol that is the reaction product of a resin of general formula (I) with an acid or a diol respectively, with the reaction being carried out in the presence of a catalyst. The coating composition also includes an isocyanate-functional compound as a crosslinker. The coating composition forms a corrosion-resistant film when applied directly to the substrate surface without a pretreatment or primer.
Claims20
A urethane coating composition, comprising:
- (1) a polyol that is the reaction product of
- a) a resin having the general formula (I)
- wherein:
- each A is independently a substituted or unsubstituted divalent aliphatic group having from 1 to about 6 carbon atoms, an unsubstituted divalent aromatic group having from 6 to about 10 carbon atoms, a divalent aromatic group substituted with an organic group having from 1 to 4 carbon atoms (C1-C4 alkyl or alkenyl), a halogen, —OR′O, wherein R′ is unsubstituted or substituted C1-C4 alkyl, —C(O)—, —O—, —S—, —S(O)—, or —S(O)2;
- each Ph is independently a an unsubstituted phenylene ring, or a phenylene ring substituted with H, C1-C4 alkyl, Cl, Br, or —OR;
- each R is independently H, C1-C4 alkyl, or an epoxide of the formula
- wherein R1 is independently H, unsubstituted C1-C4 alkyl, or C1-C4 alkyl substituted with —OH, or C1-C4 alkoxy;
- m is 0 or 1;
- and
- n is between 0 and 6;
- and
- (b) an acid or diol present in an amount sufficient to react substantially all the epoxide groups, if present, in component (a), wherein the reaction is carried out in the presence of a reaction catalyst;
- and
- an isocyanate-functional compound.
Dependencies are inferred from the claim text.