Hardenable polymer composition

6:

• The polymer composition according to claim 5, wherein the acrylate polymer containing a functional group prone to photoinitiation comprises
• at least 60 mol-%, relative to 1 mol of the polymer, of repeating units of the following formula I:
• where in a part of the repeating units radical Rα is C1-C10-alkyl and in another part of the repeating units is a group of formula Rα.1
• where
• # is an attachment point to the remainder of the molecule;
• L is a bond or a spacer group of C1-C8-alkylene which is optionally bound to the phenyl ring via a linking group selected from the group consisting of —O—, —O—C(O)—, —C(O)—O—, —O—C(O)—O—, —NH—, —NH—C(O)—, —C(O)—NH—, —NH—C(O)—NH—, —O—C(O)—NH— and —NH—C(O)—O—;
• Rγ is OH, C1-C6-alkyl or C1-C6-alkoxy;
• and
• m is 0, 1, 2, 3, 4 or 5;
• and
• optionally repeating units of formulae II, III and/or IV:
• where Rα is independently as defined above.

7:

• The polymer composition according to claim 6, wherein the acrylate polymer containing a functional group prone to photoinitiation comprises
• from 80 to 99.9 mol-% of repeating units of the formula I wherein Rα is C1-C10-alkyl;
• from 0.01 to 20 mol-% of repeating units of the formula I wherein Rα is a benzophenone group of formula Rα.1;
• and
• from 0 to 15 mol-% of repeating units of formula III;
• relative to 1 mol of the polymer,
• wherein the mol percentages of repeating units of the formula I wherein Rα is C1-C10-alkyl, repeating units of the formula I wherein Rα is a benzophenone group, and repeating units of the formula III essentially sum up to 100 mol-%.

10:

• The polymer composition according to claim 1, wherein the silyl-terminated polymer is a polymer of formula 1
• [(R′)a(R″O)3-aSi-L1-Y]b—Po (I)
• where
• Po is a di-, tri- or tetravalent radical of a base polymer;
• each Y is independently selected from the group consisting of a bond, —NH—C(═O)—O—, —O—C(═O)—NH—, —C(═O)—NH-L2-NH—C(═O)—NH—, —NH—C(═O)—NH-L2-NH—C(═O)—, —O—C(═O)—, —C(═O)—O—, —NH—C(═O)—S—, —S—C(═O)—NH— and —O—;
• R′ and R″, independently of each other and independently of each occurrence, are C1-C6-alkyl;
• L1 is C1-C3-alkylene;
• L2 is a divalent aliphatic, cycloaliphatic or aromatic radical;
• each a is independently 0 or 1;
• and
• b is 2, 3 or 4.

13:

• The polymer composition according to claim 10, wherein
• Y is —NH—C(═O)—O—;
• R′ and R″, independently of each other and independently of each occurrence, are methyl or ethyl;
• and
• each L1 is independently —CH2— or C3-alkylene.

17:

• The polymer composition according to claim 16, wherein the photolatent initiator is
• a photolatent base, which is a Ba—Za compound, where Ba and Za are covalently bound, and where Ba is derived from a base selected from the group consisting of an amidine, a guanidine and a secondary amine, and Za is a photolytically removable group;
• or
• a photolatent acid generator, which is a Ab-Zb compound, where Ab and Zb are covalently bound, and where Ab is derived from an acid selected from the group consisting of an aliphatic sulfonic acid and an aromatic sulfonic acid, and Zb is a photolytically removable group;
• or an acylphosphine oxides;
• or an ionic photoacid generator;
• or
• a metal-based initiator, which is a titanium complex containing at least one photolytically removable ligand.

18:

• The polymer composition according to claim 17, wherein the photolatent initiator is a photolatent base, which is a compound of formulae PLB.1 to PLB.7:
• where
• each R18 is independently C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-alkylcarbonyl or C1-C6-alkoxycarbonyl;
• R19 is hydrogen or C1-C4-alkyl;
• and
• s is 0, 1, 2, 3, 4 or 5.

20:

• The polymer composition according to claim 17, wherein the photolatent initiator is a photolatent acid generator, which is an acylphosphine oxide of formula PAG.2
• where
• R22 is C1-C10-alkyl, C1-C10-alkoxy or phenyl which optionally comprises 1, 2, 3, 4 or 5 substituents selected from the group consisting of C1-C6-alkyl and C1-C6-alkoxy;
• R23 is C1-C10-alkyl, C1-C10-alkoxy, C(O)R25 or phenyl which optionally comprises 1, 2, 3, 4 or 5 substituents selected from the group consisting of C1-C6-alkyl and C1-C6-alkoxy;
• R24 is C1-C6-alkyl or C1-C6-alkoxy;
• R25 is C1-C10-alkyl, C1-C10-alkoxy or phenyl which optionally comprises 1, 2, 3, 4 or 5 substituents selected from the group consisting of C1-C6-alkyl and C1-C6-alkoxy;
• and
• q is 0, 1, 2, 3, 4 or 5.

21:

• The polymer composition according to claim 1, containing:
• (a) at least one acrylate compound:
• 1 to 98% by weight;
• (b) at least one silyl-terminated polymer:
• 1 to 98% by weight;
• (c) at least one photoinitiator:
• 0.0001 to 9% by weight;
• and
• (d) at least one further additive:
• 0 to 98% by weight;
• where the acrylate compound and the silyl-terminated polymer are used in a weight ratio of from 50:1 to 1:50;
• and the photoinitiator (c) and the polymer (a) or (b) which is used in lower amounts are used in a weight ratio of from 1:10 to 1:10000.