The present invention relates to compounds of the general formula (I)
in which Q, V, T, W, X, Y and A have the meanings given in the description—and to their use for controlling animal pests.
Drawings
Claims12
An intermediate of formula (X),
wherein
Q represents oxygen or sulphur,
V represents a radical selected from the group consisting of hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy and cyano,
W represents a radical selected from the group consisting of hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy and cyano,
X represents a radical selected from the group consisting of Cl, Br, I, and ethinyl,
Y represents a radical selected from the group consisting of hydrogen, cyano, optionally substituted alkyl, alkenyl or alkynyl, optionally substituted cycloalkyl which is optionally interrupted by heteroatoms and optionally substituted cycloalkylalkyl which is optionally interrupted by heteroatoms, arylalkyl or hetarylalkyl,
A represents a radical selected from the group consisting of hydrogen, optionally substituted alkyl, alkenyl or alkynyl and cycloalkyl or cycloalkylalkyl, optionally interrupted by heteroatoms and optionally substituted,
Having rings with three nitrogen atoms as the only ring hetero atoms: triazoles; Hydrogenated triazoles
Life of this patent
Term end not estimated
Priority claimedEP 16155132.0
Application filedUS 16/659,886
Assigned to Bayer Cropscience Aktiengesellschaftassignment of assignor's interest
Published
Description30,814 words
Summary438 words
#The present application relates to novel heterocyclic compounds, to intermediates for their preparation and their use for controlling animal pests.
#WO 2011/009804 A2 describes heterocyclic compounds including, inter alia, imidazolylcarboxamides which can be used as insecticides. However, imidazolylcarboxamides directly substituted at the imidazolyl radical by aryls or hetaryls are not described. The imidazolylcarboxamides listed in WO 2011/009804 A2 have considerable weaknesses in their insecticidal action.
#Modern insecticides have to meet many demands, for example in relation to extent, persistence and spectrum of their action and possible use. Questions of toxicity, sparing of beneficial species and pollinators, environmental properties, application rates, combinability with other active compounds or formulation auxiliaries play a role, as does the question of the effort required for the synthesis of an active compound; furthermore, resistances may occur, to mention only some parameters. For all these reasons alone, the search for novel crop protection compositions cannot be considered complete, and there is a constant need for novel compounds having improved properties compared to the known compounds, at least in relation to individual aspects.
Detailed description30,376 words
#Preferred substituents or ranges for the radicals shown in the compounds of the formula (I) are illustrated below. The combination thereof forms the range of preference (1-1). Q represents oxygen or sulphur, V represents a radical from the group consisting of hydrogen, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and cyano, W represents a radical from the group consisting of hydrogen, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and cyano, X represents a radical from the group consisting of aryl and hetaryl, optionally mono- to polysubstituted independently of one another by halogen, NL1L2, nitro, cyano or optionally substituted alkyl, haloalkyl, alkoxy, alkyl-S(O)m—, haloalkoxy, haloalkyl-S(O)m—, carboxy, aryl or hetaryl, where L1 represents a radical from the group consisting of hydrogen, optionally substituted alkyl, alkenyl, alkynyl and cycloalkyl, L2 represents a radical from the group consisting of hydrogen, optionally substituted alkyl, alkenyl, alkynyl and cycloalkyl,
#or L1 and L2 together with N represent an optionally substituted saturated, partially saturated or aromatic heterocycle which has 3 to 7 ring atoms and is attached via N, Y represents a radical from the group consisting of hydrogen, methyl, cyano, C1-C6-alkyl, C3-C6-alkenyl or C3-C6-alkynyl, optionally mono- to polysubstituted independently of one another by halogen, C1-C4-alkoxy, C1-C4-alkyl-S(O), or cyano, C3-C8-cycloalkyl, optionally mono- to disubstituted independently of one another by halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or cyano, straight-chain or branched C3-C8-cycloalkyl-C1-C4-alkyl, optionally interrupted once to twice independently of one another by O, S(O)m, CO or NR2 and optionally mono- to tetrasubstituted independently of one another by halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or cyano, and arylalkyl or hetarylalkyl, optionally mono- to trisubstituted independently of one another by halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkyl-S(O)m—, C1-C4-haloalkoxy, C1-C4-haloalkyl-S(O)m—, nitro or cyano, m represents a number 0, 1 or 2, A represents a radical from the group consisting of hydrogen, methyl, C1-C6-alkyl, C3-C6-alkenyl or C3-C6-alkynyl, optionally mono- to polysubstituted independently of one another by halogen, C1-C4-alkoxy, C1-C4-alkyl-S(O)m, or cyano and C3-C6-cycloalkyl, optionally mono- to disubstituted independently of one another by halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or cyano and straight-chain or branched C3-C8-cycloalkyl-C1-C4-alkyl, optionally mono- to disubstituted independently of one another by halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or cyano, R2 represents a radical from the group consisting of hydrogen, optionally substituted alkyl, alkenyl, alkynyl and cycloalkyl, T represents oxygen or an electron pair, and salts thereof.
#More preferred substituents or ranges for the radicals shown in the compounds of formula (I) are illustrated below. The combination thereof forms the range of preference (1-2).