Stable Formulation of Pesticidal Pyridazinpyrazolamides

An agrochemical composition comprising

• a) propylene carbonate
• b) up to 10 wt % of water;
• and
• c) compound (I)
• or a salt, a tautomer, or an enantiomer thereof;
• wherein the variables have the meaning
• R1 H, C1-C2-alkyl, or C1-C2-alkoxy-C1-C2-alkyl;
• R2 H, halogen, CN, or NO2;
• C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkynyl, which are unsubstituted, halogenated, or substituted with Rx;
• ORa, SRa, C(Y)Rb, C(Y)ORc, S(O)Rd, S(O)2Rd, NReRf, C(Y)NRgRh;
• heterocyclyl, hetaryl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, or phenyl, which are unsubstituted, or substituted with Ry, or Rx;
• R3 H, halogen, CN, NO2;
• C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkynyl, which are unsubstituted, halogenated, or substituted with Rx;
• ORa, SRa, C(Y)Rb, C(Y)ORc, S(O)Rd, S(O)2Rd, NReRf, C(Y)NRgRh;
• heterocyclyl, hetaryl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl or phenyl, which are unsubstituted, or substituted with Ry, or Rx;
• RN H, CN, NO2;
• C1-C10-alkyl, C2-C10-alkenyl, or C2-C10-alkynyl, which are unsubstituted, halogenated, or substituted with Rx;
• ORa, SRa, C(Y)Rb, C(Y)ORc, S(O)Rd, S(O)2Rd, NReRf, C(Y)NRgRh, S(O)mNReRf, C(Y)NRiNReRf, C1-C5-alkylen-ORa, C1-C5-alkylen-CN, C1-C5-alkylen-C(Y)Rb, C1-C5-alkylen-C(Y)ORc, C1-C5-alkylen-NReRf, C1-C5-alkylen-C(Y)NRgRh, C1-C5-alkylen-S(O)mRd, C1-C5-alkylen-S(O)mNReRf, C1-C5-alkylen-NRiNReRf;
• heterocyclyl, hetaryl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, heterocyclyl-C1-C5-alkyl, hetaryl-C1-C5-alkyl, C3-C10-cycloalkyl-C1-C5-alkyl, C3-C10-cycloalkenyl-C1-C5-alkyl, phenyl-C1-C5-alkyl, or phenyl, in which groups the rings are unsubstituted, or substituted with Ry;
• Ra, Rb, Rc independently H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl;
• or
• heterocyclyl, heterocyclyl-C1-C4-alkyl, phenyl, hetaryl, phenyl-C1-C4-alkyl, hetaryl-C1-C4-alkyl, in which groups the ring is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;
• Rd C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl;
• or
• heterocyclyl, heterocyclyl-C1-C4-alkyl, phenyl, hetaryl, phenyl-C1-C4-alkyl, and hetaryl-C1-C4-alkyl, in which groups the ring is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;
• Re, Rf independently H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl;
• heterocyclyl, heterocyclyl-C1-C4-alkyl, heterocyclylcarbonyl, heterocyclylsulfonyl, phenyl, phenylcarbonyl, phenylsulfonyl, hetaryl, hetarylcarbonyl, hetarylsulfonyl, phenyl-C1-C4-alkyl, and hetaryl-C1-C4-alkyl, in which groups the ring is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, and C1-C4-haloalkoxy;
• or
• Re and Rf are together with the nitrogen atom to which they are bound form a 5- or 6-membered, saturated, or unsaturated heterocycle, in which heterocycle none, or one ring member atom is replaced by O, S or N, and wherein the heterocycle is unsubstituted or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;
• Rg, Rh independently H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl;
• heterocyclyl, heterocyclyl-C1-C4-alkyl, phenyl, hetaryl, phenyl-C1-C4-alkyl, and hetaryl-C1-C4-alkyl, in which groups the ring is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;
• Ri H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C1-C4-alkoxy-C1-C4-alkyl;
• or
• phenyl, phenyl-C1-C4-alkyl, in which groups the phenyl rings is unsubstituted, or substituted with halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, or C1-C4-haloalkoxy;
• Rx CN, NO2, C1-C4-alkoxy, C1-C4-haloalkoxy, S(O)mRd, S(O)mNReRf, C1-C10-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-haloalkoxycarbonyl;
• or
• C3-C6-cycloalkyl, 5- to 7-membered heterocyclyl, 5- or 6-membered hetaryl, phenyl, C3-C6-cycloalkoxy, 3- to 6-membered heterocyclyloxy, phenoxy, which are unsubstituted, or substituted with Ry;
• Ry halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, S(O)mRd, S(O)mNReRf, C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-haloalkoxycarbonyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, or C1-C4-alkoxy-C1-C4-alkyl;
• Y O or S;
• and
• m is 0, 1 or 2.