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US 2020/0045962 A1Published application
Method for preparing surfactant compositions comprising alkyl liduronamides d-glucuronamides and l-rhamnosides from ulvans
AssigneeEcole Nationale Superieure de Chimie
InventorsThierry BENVEGNU, Nouha SARI-CHMAYSSEM, Samir TAHA, Hiba MAWLAWI
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Abstract
The present invention relates to a novel process for preparing surfactant compositions based on alkyl L-iduronamides, alkyl L-rhamnosides and alkyl D-glucuronamides, to the compositions obtained via said process and to the uses thereof.
Claims17
1) Process for preparing a composition comprising a mixture of alkyl D-glucuronamides (I) in pyranoside form of formula (Ia) and in furanoside form of formula (Ib), of alkyl L-iduronamide of formula (II) and of alkyl L-rhamnoside of formula (III):
- in which
- R1 is a linear or branched, saturated or unsaturated alkyl chain of 2 to 22 carbon atoms;
- R2 is a hydrogen, R1, a linear or branched, saturated or unsaturated alkyl chain of 2 to 22 carbon atoms including an amine end function,
- and characterized in that said process comprises:
- a) a step of butanolysis reaction and of Fischer glycosylation starting with ulvans and/or green algae;
- b) a step of aminolysis reaction on the reaction medium obtained from step a), in the presence of a linear or branched, saturated or unsaturated amine of formula R′NH2 in which R′ is composed of from 2 to 22, preferably from 8 to 18, preferentially from 12 to 18 carbon atoms.
3 more elements
Dependencies are inferred from the claim text.