Compounds based on an element from the boron group, and use thereof in electrolyte compositions
AssigneeSCE France
InventorsVincent MORIZUR, Pauline HAYS, Arthur DELABOISSIERE, Julien PARVOLE, Sabrina PAILLET, Karim ZAGHIB
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Abstract
Compounds based on an element from Groupe IIIA (column 13) of the periodic table of the elements, such as boron, aluminum, gallium or indium, are here described, as well as their processes of preparation and their use as salts and/or additives, for instance, in combination with other salts in electrolyte compositions for electrochemical cells, inter alia, in electrolyte compositions in the presence of a liquid solvent and/or a solvating polymer, the electrolyte being in liquid, gel or solid form.
Claims39
A compound of Formula I, II, or III, and/or its salts:
- wherein:
- M is an atom selected from the elements of column 13 (Group IIIA) of the periodic table of the elements, for example, a boron, aluminum, gallium, indium or thallium atom, for example a boron, aluminum, gallium or indium atom, or a boron or aluminum atom;
- X is independently selected from O, S, NH, NR, or a C(O)O or S(O)2O group, wherein said group is attached to M by an oxygen atom;
- R is independently selected from substituted or unsubstituted, linear or branched alkyl, cycloalkyl and aryl groups, or 2 or 3 R groups combined with X radicals attached thereto form a 5 to 7 membered ring comprising M, or a bicyclic group having from 7 to 10 members comprising M, and/or at most one XR is a hydroxyl group;
- R1 is independently selected from substituted or unsubstituted, linear or branched alkyl, cycloalkyl and aryl groups;
- and
- A+ is a metallic cation or a cation of an organic base, and where the total molar ratio of A+ relative to the rest of the molecule is adjusted to achieve electroneutrality.
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Electrolyte composition according to claim 64, wherein the electrolyte is a liquid electrolyte, a gel polymer electrolyte or a solid polymer electrolyte.
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Electrochemical cell comprising an electrolyte composition as defined in claim 64, between an anode and a cathode.
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Dependencies are inferred from the claim text.