Transparent drawn article
AssigneeDsm IP Assets B.V.
InventorsCornelis Wilhelmus Maria BASTIAANSEN, John Richard SEVERN, Lihua SHEN
Life of this patent
Estimating the term…
Loading patent…
AssigneeDsm IP Assets B.V.
InventorsCornelis Wilhelmus Maria BASTIAANSEN, John Richard SEVERN, Lihua SHEN
Estimating the term…
The invention relates to a process for the production of a high strength transparent high density polyethylene article comprising the steps of (i) heating a high density polyethylene (HDPE) to a temperature above the melting temperature (Tm) of the HDPE; (ii) molding the heated HDPE obtained in step (i) to form a hot molded HDPE article; (iii) cooling the hot molded HDPE article to a temperature below Tm to form a melt-crystallized HDPE article; (iv) stretching the melt-crystallized HDPE article to a total draw ratio of at least 5 comprising at least one stretching step of the article at a temperature T1 below the melting temperature Tm to a draw ratio (DR1) of at least 2 to form an oriented HDPE article, wherein the HDPE has a melt flow index (MFI) measured at 21.6 kg and 190° C. according to ASTM D1238 of at most 1.5 g/I Omin, an isotropic density measured according to ISO 1 183-1 A of at most 0.955 g/cm3 and a Tm measured according to ISO 1 1357-3 of greater than 130° C. The invention also relates to high strength transparent HDPE articles and products comprising the high strength transparent HDPE article such as ballistic resistant articles, visors, car parts, train parts, plane parts, windshields, windows and radomes.
A process for the production of a high strength transparent high density polyethylene article comprising the steps of
A high strength transparent HDPE article wherein the HDPE has a melt flow index (MFI) measured at 21.6 kg and 190° C. according to ASTM D1238 of at most 1.5 dg/min, an isotropic density measured according to ISO 1183-1A of at most 0.955 g/cm3 and a Tm measured according to ISO 11357-3 of greater than 130° C., characterized in that said high strength transparent HDPE article has a tensile strength of at least 0.5 GPa and a transmittance of at least 70% when measured at a film thickness of 0.1 mm and at a wavelength of 550 nm.
Dependencies are inferred from the claim text.