Polyimide precursor resin composition
AssigneeAsahi Kasei Kabushiki Kaisha
InventorsTakayuki KANADA, Masaki MAITANI, Toshiaki OKUDA
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Abstract
Problem: The invention provides a polyimide precursor as well as a resin composition thereof that is excellent in coating properties of slit coating as well as productivity and also excellent in optical properties that are required for applications of flexible substrates. Solution: The polyimide precursor comprises a structure unit derived from a fluorene backbone and a silicon-containing structure unit, and a weight-average molecular weight of the polyimide precursor is 90,000 to 250,000.
Claims27
A polyimide precursor represented by formula (1):
- wherein P1 represents a divalent organic group, if P1 is plural, P1 each may be the same or different, P2 represents a tetravalent group represented by formula (2):
- wherein Q1 and Q2 are each independently at least one selected from the group consisting of an alkyl group, an aryl group, an arylalkyl group and a halogenated alkyl group, X is each independently at least one selected from the group consisting of —O—, —C(═O)—, —C(═O)O— and —C(═O)NH—, m and n are each independently an integer of 0 to 2, and 1 is an integer of 0 or 1;
- if P2 is plural, P2 each may be the same or different, and p is a positive integer,
- wherein the polyimide precursor has a structure unit represented by formula (3):
- wherein P3 and P4 are each independently a monovalent aliphatic hydrocarbon group of 1 to 5 carbon atoms or a monovalent aromatic group of 6 to 10 carbon atoms, if P3 is plural, P3 each may be the same or different, if P4 is plural, P4 each may be the same or different, and q is a positive integer, and has a weight-average molecular weight of 90,000 to 250,000.
A resin composition comprising a polyimide precursor and a solvent, wherein the polyimide precursor is represented by formula (1):
- wherein P1 represents a divalent organic group, if P1 is plural, P1 each may be the same or different, P2 represents a tetravalent group represented by formula (2):
- wherein Q1 and Q2 are each independently at least one selected from the group consisting of an alkyl group, an aryl group, an arylalkyl group and a halogenated alkyl group, X is each independently at least one selected from the group consisting of —O—, —C(═O)—, —C(═O)O— and —C(═O)NH—, m and n are each independently an integer of 0 to 2, and 1 is an integer of 0 or 1,
- if P2 is plural, P2 each may be the same or different and p is a positive integer, and has a structure unit represented by formula (3):
- wherein P3 and P4 are each independently a monovalent aliphatic hydrocarbon group of 1 to 5 carbon atoms or a monovalent aromatic group of 6 to 10 carbon atoms, if P3 is plural, P3 each may be the same or different, if P4 is plural, P4 each may be the same or different and q is a positive integer, and
- the resin composition comprises a compound represented by formula (4):
- wherein P5 and P6 are each independently a monovalent aliphatic hydrocarbon of 1 to 5 carbon atoms or an aromatic group of 6 to 10 carbon atoms and r is an integer of 3 or more, in an amount of greater than 0 ppm and 300 ppm or less based on a weight of the resin composition, and/or in an amount of greater than 0 ppm and 1500 ppm or less based on a solid content weight in the resin composition.
A resin composition comprising a polyimide precursor and a solvent, wherein the polyimide precursor is represented by formula (1):
- wherein P1 represents a divalent organic group, if P1 is plural, P1 each may be the same or different, P2 represents a tetravalent group represented by formula (2):
- wherein Q1 and Q2 are each independently at least one selected from the group consisting of an alkyl group, an aryl group, an arylalkyl group and a halogenated alkyl group, X is each independently at least one selected from the group consisting of —O—, —C(═O)—, —C(═O)O— and —C(═O)NH—, m and n are each independently an integer of 0 to 2, and 1 is an integer of 0 or 1;
- if P2 is plural, P2 each may be the same or different, and p is a positive integer, and has a structure unit represented by formula (3):
- wherein P3 and P4 are each independently a monovalent aliphatic hydrocarbon group of 1 to 5 carbon atoms or a monovalent aromatic group of 6 to 10 carbon atoms, if P3 is plural, P3 each may be the same or different, if P4 is plural, P4 each may be the same or different, and q is a positive integer,
- the resin composition comprises a compound represented by formula (4):
- wherein P5 and P6 are each independently a monovalent aliphatic hydrocarbon of 1 to 5 carbon atoms or an aromatic group of 6 to 10 carbon atoms and r is an integer of 3 or more,
- the polyimide precursor is a copolymer containing as monomer units:
- a silicon-containing compound represented by formula (5):
- wherein R1 is each independently, single bond or a divalent organic group of 1 to 10 carbon atoms, R2 and R3 are each independently a monovalent aliphatic hydrocarbon group of 1 to 5 carbon atoms, R4 and R5 are each independently a monovalent aromatic group of 6 to 10 carbon atoms, R6 and R7 are each independently a monovalent organic group of 1 to 10 carbon atoms, at least one of R6 and R7 is an organic group having an unsaturated aliphatic hydrocarbon group, L1 and L2 are each independently an amino group, an acid anhydride group, an isocyanate group, a carboxy group, an acid ester group, an acid halide group, a hydroxy group, an epoxy group or a mercapto group, i is an integer of 1 to 200, and j and k are each independently an integer of 0 to 200,
- tetracarboxylic dianhydride, and
- diamine;
- and
- a content of the compound represented by formula (4) in the resin composition is greater than 0 ppm and 450 ppm or less based on 100 parts by weight of a total weight of the silicon-containing compounds represented by formulas (4) and (5).
Dependencies are inferred from the claim text.