Back to results
US 2020/0002301 A1Published application
Production of purified dialkyl-furan-2,5-dicarboxylate (dafd) in a retrofitted dmt plant
AssigneeEastman Chemical Company
InventorsKevin John Fontenot, Mesfin Ejerssa Janka, Kenny Randolph Parker, Ashfaq Shahanawaz Shaikh
Life of this patent
Estimating the term…
Abstract
Disclosed is a process to produce a purified vapor comprising dialkyl-furan-2,5-dicarboxylate (DAFD). Furan-2,5-dicarboxylic acid (FDCA) and an alcohol in an esterification zone to generate a crude diester stream containing dialkyl furan dicarboxylate (DAFD), unreacted alcohol, 5-(alkoxycarbonyl)furan-2-carboxylic acid (ACFC), and alkyl furan-2-carboxylate (AFC). The esterification zone comprises at least one reactor that has been previously used in an DMT process.
Claims20
A process for the manufacture of a DAFD vapor comprising:
- a) feeding a composition comprising furan-2,5-dicarboxylic acid (“FDCA”) in an amount greater than 90wt % to an esterification reaction zone;
- and
- b) in the presence of an alcohol compound, conducting an esterification reaction in the esterification reaction zone to react FDCA with said alcohol compound to form a crude diester composition comprising dialkyl furan-2,5-dicarboxylate (“DAFD”), the alcohol compound, 5-(alkoxycarbonyl)furan-2-carboxylic acid (ACFC), alkyl furan-2-carboxylate (AFC), and alkyl-5-formylfuran-2-carboxylate (AFFC);
- and wherein said esterification reactor zone comprises at least one reactor, wherein said reactor has been previously used in an DMT(dimethyl terephthalate) process;
- and wherein the process for the oxidation of the oxidizable material containing the furan group can be integrated with the process for the manufacture of the diester composition;
- and wherein an integrated process includes co-locating the two manufacturing facilities, one for oxidation and the other for esterification, within 10 miles.
3 more elements
Dependencies are inferred from the claim text.