# US 2019/0355990 A1 · Alkaline secondary battery

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- Number: US 2019/0355990 A1
- Document ID: US20190355990A1
- Status: Published application
- Kind: A1
- Application number: 16/482,859
- Filed: 2018-03-12
- Published: 2019-11-21
- Earliest claimed: 2017-03-22
- Assignees: Maxell Holdings, Ltd.
- Applicants: Maxell Holdings, Ltd.
- Inventors: Yusuke INOUE; Mitsutoshi WATANABE
- Web page: https://patentgrep.com/patent/US20190355990A1

## CPC

- H01M 4/34: Silver oxide or hydroxide electrodes
- H01M 4/54: of silver
- H01M 10/32: Silver accumulators (H01M10/34 takes precedence)
- H01M 10/448: {End of discharge regulating measures}
- H01M 2004/028: {Positive electrodes}
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

An alkaline secondary battery disclosed in the present application includes a positive electrode containing a positive electrode active material, a negative electrode, and a separator. The positive electrode active material contains a mixture of a silver oxide and a silver-bismuth complex oxide. A discharge curve is obtained when the battery that is fully charged is discharged with a constant current until a battery voltage drops to 1.0 V. The battery voltage at a point on the discharge curve where x (%) of a total discharge capacity has been discharged from the battery since start of discharge is represented by Vx (V). The discharge curve satisfies V10−V70≤0.08, has a step in the range of 70≤x≤90, and shows that a size of the step represented by V70−V90 is 0.04 or more and 0.15 or less.

## Claims

### Claim 1

An alkaline secondary battery comprising:
a positive electrode containing a positive electrode active material;
a negative electrode; and
a separator,
wherein the positive electrode active material contains a mixture of a silver oxide and a silver-bismuth complex oxide, and
wherein a discharge curve is obtained when the battery that is fully charged is discharged with a constant current until a battery voltage drops to 1.0 V,
the battery voltage at a point on the discharge curve where x (%) of a total discharge capacity has been discharged from the battery since start of discharge is represented by Vx (V), and
the discharge curve satisfies V10−V70≤0.08, has a step in a range of 70≤x≤90, and shows that a size of the step represented by V70−V90 is 0.04 or more and 0.15 or less.

### Claim 2 (depends on 1)

The alkaline secondary battery according to claim 1, wherein the total discharge capacity is a discharge capacity of the battery obtained under the following charge and discharge conditions:
for charging, the battery is subjected to a constant-current and constant-voltage charge, which is a combination of a constant current charge where the battery that has been discharged to 1.0 V is charged with a current value C (mA) at which it takes 4±0.25 hours for the battery voltage to reach 1.85 V from start of charge, and a constant voltage charge where the battery is charged with a voltage of 1.85 V, and the charge of the battery is terminated when the current value is reduced to C/10 (mA);
for discharging, the battery is subjected to a constant current discharge where the battery is discharged with a current of C/2 (mA), and the discharge of the battery is terminated when the battery voltage is reduced to 1.0 V.

### Claim 3 (depends on 1)

The alkaline secondary battery according to claim 1, wherein there is an inflection point in the range of 70<x<90 of the discharge curve on which x (%) as a depth of discharge is represented by a horizontal axis and the battery voltage Vx (V) is represented by a vertical axis.

### Claim 4 (depends on 1)

The alkaline secondary battery according to claim 1, wherein a ratio of a total amount of bismuth to a total amount of silver contained in the mixture is more than 2% by mass and less than 9% by mass.

### Claim 5 (depends on 1)

The alkaline secondary battery according to claim 1, wherein an average valence of bismuth of the silver-bismuth complex oxide is 3.

### Claim 6 (depends on 1)

The alkaline secondary battery according to claim 1, wherein the silver-bismuth complex oxide is a complex oxide expressed by (Ag2O)1-t(Bi2O3)t.
