# US 2019/0355969 A1 · Non-Aqueous Electrolyte Secondary Battery

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- Number: US 2019/0355969 A1
- Document ID: US20190355969A1
- Status: Published application
- Kind: A1
- Application number: 16/308,024
- Filed: 2016-06-08
- Published: 2019-11-21
- Earliest claimed: 2016-06-08
- Assignees: Nissan Motor Co., Ltd.
- Applicants: Nissan Motor Co., Ltd.
- Inventors: Yuji Muroya; Fumihiro Kawamura; Manabu Nishijima; Yoshiaki Nitta
- Web page: https://patentgrep.com/patent/US20190355969A1

## CPC

- H01M 4/13: Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M 4/131: Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- H01M 4/133: Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M 4/505: of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
- H01M 4/525: of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
- H01M 10/05: Accumulators with non-aqueous electrolyte (H01M10/39 takes precedence)
- H01M 10/052: Li-accumulators
- H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- H01M 10/0585: of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
- H01M 2004/021: {Physical characteristics, e.g. porosity, surface area}
- H01M 2010/4292: {Aspects relating to capacity ratio of electrodes/electrolyte or anode/cathode}
- H01M 2300/004: Three solvents
- Y02E 60/10: Energy storage using batteries
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

Provided is a non-aqueous electrolyte secondary battery which has improved battery durability in the battery having a high capacity, a high density, and a large area. A non-aqueous electrolyte secondary battery including a power generating element including a positive electrode in which a positive electrode active material layer containing a positive electrode active material is formed on a surface of a positive electrode current collector, a negative electrode in which a negative electrode active material layer containing a negative electrode active material is formed on a surface of a negative electrode current collector, and a separator, a ratio of a rated capacity to a pore volume of the positive electrode active material layer being 1.40 Ah/cc or more, a ratio of a battery area to a rated capacity being 4.0 cm2/Ah or more, and a rated capacity being 30 Ah or more, wherein a variation in porosity in the positive electrode active material layer is 6.0% or less.

## Claims

### Claim 1

A non-aqueous electrolyte secondary battery comprising a power generating element including
a positive electrode in which a positive electrode active material layer containing a positive electrode active material is formed on a surface of a positive electrode current collector,
a negative electrode in which a negative electrode active material layer containing a negative electrode active material is formed on a surface of a negative electrode current collector, and
a separator,
a ratio of a rated capacity to a pore volume of the positive electrode active material layer being 1.40 Ah/cc or more, a ratio of a battery area to a rated capacity being 4.0 cm2/Ah or more, and a rated capacity being 30 Ah or more, wherein
a variation in porosity in the positive electrode active material layer is 6.0% or less.

### Claim 2 (depends on 1)

The non-aqueous electrolyte secondary battery according to claim 1, wherein the ratio of the rated capacity to the pore volume of the positive electrode active material layer is 2.20 Ah/cc or more, and the variation in porosity in the positive electrode active material layer is 5.0% or less.

### Claim 3 (depends on 1, 2)

The non-aqueous electrolyte secondary battery according to claim 1 or 2, wherein the variation in porosity in the positive electrode active material layer is 4.0% or less.

### Claim 4 (depends on 1, 2, 3)

The non-aqueous electrolyte secondary battery according to any one of claims 1 to 3, wherein the positive electrode active material is a lithium composite oxide having a composition represented by LiaNibMncCodMxO2 (provided that, in the formula, a, b, c, d, and x satisfy 0.9≤a≤1.2, 0<b<1, 0<c≤0.5, 0<d≤0.5, and 0≤x≤0.3; and M is at least one kind selected from Ti, Zr, Nb, W, P, Al, Mg, V, Ca, Sr, and Cr).

### Claim 5 (depends on 1, 2, 3, 4)

The non-aqueous electrolyte secondary battery according to any one of claims 1 to 4, wherein the non-aqueous electrolyte secondary battery is a flat type non-aqueous electrolyte secondary battery.
