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US 2019/0338108 A1Published application
Polethylene composition having high swell ratio
AssigneeBasell Polyolefine GmbH
InventorsDIANA DOETSCH, BERND LOTHAR MARCZINKE, GERHARDUS MEIER, ULF SCHUELLER, RAINER SATTEL, PETER BISSON
Life of this patent
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Abstract
A polyethylene composition for producing blow-molded hollow articles, having the following features: 1) density from 0.940 to 0.955 g/cm3 determined according to ISO 1183 at 23° C.; 2) ratio MIF/MIP from 12 to 30; 3) Mz from 2,000,000 to 4,500,000 g/mol; 4) η0.02 from 160,000 to 300,000 Pa·s; and 5) long-chain branching index, LCBI, equal to or greater than 0.75.
Claims10
A polyethylene composition having the following features:
- 1) density from 0.940 to 0.955 g/cm3 determined according to ISO 1183 at 23° C.;
- 2) ratio MIF/MIP from 12 to 30, where MIF is the melt flow index at 190° C. with a load of 21.60 kg and MIP is the melt flow index at 190° C. with a load of 5 kg, both determined according to ISO 1133;
- 3) Mz from 2,000,000 to 4,500,000 g/mol, where Mz is the z-average molecular weight measured by GPC;
- 4) η0.02 from 160,000 to 300,000 Pa·s wherein η0.02 is the complex shear viscosity at an angular frequency of 0.02 rad/s, measured with dynamic oscillatory shear in a plate-plate rotational rheometer at a temperature of 190° C.;
- and
- 5) long-chain branching index, LCBI, equal to or greater than 0.75, wherein LCBI is the ratio of the measured mean-square radius of gyration Rg, measured by GPC-MALLS, to the mean-square radius of gyration for a linear PE having the same molecular weight.
3 more elements
Dependencies are inferred from the claim text.