# US 2019/0315898 A1 · Power transmission belt

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- Number: US 2019/0315898 A1
- Document ID: US20190315898A1
- Status: Published application
- Kind: A1
- Application number: 16/466,528
- Filed: 2017-12-05
- Published: 2019-10-17
- Earliest claimed: 2016-12-05
- Assignees: Dayco Europe S.R.L.; Arlanxeo Deutschland GmbH
- Applicants: Dayco Europe S.R.L.; Arlanxeo Deutschland GmbH
- Inventors: Giacomo Casagrande; Ivonne Lucchese; Marco Di Meco; Massimiliano Delli Rocioli; Alessandro D'Auria
- Web page: https://patentgrep.com/patent/US20190315898A1

## CPC

- C08C 19/02: Hydrogenation
- C08F 236/12: with nitriles
- C08K 7/14: Glass
- F16G 1/08: with reinforcement bonded by the rubber
- F16G 1/28: with a contact surface of special shape, e.g. toothed
- F16H 57/0475: {Engine and gearing, i.e. joint lubrication or cooling or heating thereof}
- C08F 236/06: Butadiene
- C08F 2800/20: as weight or mass percentages
- C08C: TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)
- F16G: BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
- F16H: GEARING

## Abstract

Power transmission belts have a hydrogenated nitrile-butadiene-PEG acrylate copolymer of 25% to 38% by weight by weight of at least one α,β-ethylenically unsaturated nitrile unit, 40% to 60% by weight by weight of at least one conjugated diene unit and 10% to 25% by weight by weight of at least one PEG acrylate unit derived from a PEG acrylate of the general formula (I) where R is hydrogen or branched or unbranched C1-C20-alkyl, preferably methyl, ethyl, butyl or ethylhexyl, n is 1 to 8, preferably 2 to 8, more preferably 2 to 5 and most preferably 3 and R1 is hydrogen or CH3-, where the hydrogenated nitrile-butadiene-PEG acrylate copolymer, if n is 1, does not contain any further copolymerizable monomer unit having a free carboxylic acid group.

## Claims

### Claim 1

A power transmission belt comprising:
a hydrogenated nitrile-butadiene-PEG acrylate copolymer comprising:
a) 25% to 38% by weight by weight of at least one α,β-ethylenically unsaturated nitrile unit,
b) 40% to 60% by weight by weight of at least one conjugated diene unit, and
c) 10% to 25% by weight by weight of at least one PEG acrylate unit derived from a PEG acrylate of the general formula (I)
where
R is hydrogen or branched or unbranched C1-C20-alkyl, preferably methyl, ethyl, butyl or ethylhexyl,
n is 1 to 8, preferably 2 to 8, more preferably 2 to 5 and most preferably 3 and
R1 is hydrogen or CH3-,
where the hydrogenated nitrile-butadiene-PEG acrylate copolymer, if n is 1, does not contain any further copolymerizable monomer unit having a free carboxylic acid group.

### Claim 2 (depends on 1)

The power transmission belt according to claim 1, wherein the nitrile units (a) are 29% to 33% by weight.

### Claim 3 (depends on 1)

The power transmission belt according to claim 1, wherein the α,β-ethylenically unsaturated nitrile units (a) is acrylonitrile, methacrylonitrile, ethacrylonitrile or a mixtures thereof.

### Claim 4 (depends on 1)

The power transmission belt according to claim 1, wherein the conjugated diene units (b) are 1,3-butadiene, isoprene, 2,3-dimethylbutadiene, 1,3-pentadiene (piperylene) or mixtures thereof.

### Claim 5 (depends on 1)

The power transmission belt according to claim 1, wherein the PEG acrylate unit (c) is methoxy, ethoxy, butoxy or ethylhexoxy polyethylene glycol (meth)acrylate having 2 to 8 repeat ethylene glycol units.

### Claim 6 (depends on 1)

The power transmission belt according to claim 1, wherein the level of hydrogenation of the conjugated diene units (b) is more than 50%.

### Claim 7 (depends on 1)

The power transmission belt according to claim 1, wherein the hydrogenated nitrile-butadiene-PEG acrylate copolymer is within the mixture forming the body of the power transmission belt.

### Claim 8 (depends on 1)

The power transmission belt according to claim 1, wherein hydrogenated nitrile-butadiene-PEG acrylate copolymer is constituted by more than 50% by weight, calculated on the total weight of elastomer of the mixture forming the body of the power transmission belt.

### Claim 9 (depends on 1)

The power transmission belt according to claim 1, wherein said material is loaded with fibres in a quantity of between 1% and 50% by weight of the total non-elastomeric material.

### Claim 10 (depends on 1)

The power transmission belt according to claim 1, wherein the power transmission belt is a toothed power transmission belt.

### Claim 11 (depends on 1)

An assembly comprising an engine, a power transmission belt according to claim 1, and oil lubricating the engine; wherein, during operation of the engine, the oil continuously contacts the power transmission belt.

### Claim 12 (depends on 1)

A system comprising a power transmission belt according to claim 1 and oil, wherein said power transmission belt is in direct contact with oil or is partially immersed in oil.

### Claim 13 (depends on 1)

The power transmission belt according to claim 1, wherein the hydrogenated nitrile-butadiene-PEG acrylate copolymer comprises 27% to 37% by weight by weight of at least one α,β-ethylenically unsaturated nitrile unit, 42% to 58% by weight by weight of at least one conjugated diene unit, and 11% to 22% by weight by weight of at least one PEG acrylate unit derived from a PEG acrylate of the general formula (I).

### Claim 14 (depends on 1)

The power transmission belt according to claim 1, wherein the hydrogenated nitrile-butadiene-PEG acrylate copolymer comprises 29% to 36% by weight of at least one α,β-ethylenically unsaturated nitrile unit, 44% to 59% by weight of at least one conjugated diene unit, and 12% to 20% by weight of at least one PEG acrylate unit derived from a PEG acrylate of the general formula (I).

### Claim 15 (depends on 3)

The power transmission belt according to claim 3, wherein the α,β-ethylenically unsaturated nitrile units (a) is acrylonitrile.

### Claim 16 (depends on 4)

The power transmission belt according to claim 4, wherein the conjugated diene units (b) are 1,3-butadiene.

### Claim 17 (depends on 5)

The power transmission belt according to claim 5, wherein the PEG acrylate unit (c) is methoxy or ethoxy polyethylene glycol (meth)acrylate having 2 to 5 repeat ethylene glycol units.

### Claim 18 (depends on 5)

The power transmission belt according to claim 5, wherein the PEG acrylate unit (c) is methoxy or ethoxy polyethylene glycol (meth)acrylate having 3 repeat ethylene glycol units.

### Claim 19 (depends on 6)

The power transmission belt according to claim 6, wherein the level of hydrogenation of the conjugated diene units (b) is 90% or more.

### Claim 20 (depends on 6)

The power transmission belt according to claim 6, wherein the level of hydrogenation of the conjugated diene units (b) is 99% or more.
