# US 2019/0315643 A1 · Method and apparatus for biologically treating nitrogen > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2019/0315643 A1 - Document ID: US20190315643A1 - Status: Published application - Kind: A1 - Application number: 16/289,678 - Filed: 2019-03-01 - Published: 2019-10-17 - Earliest claimed: 2018-04-12 - Assignees: Doosan Heavy Industries Construction Co., Ltd - Applicants: Doosan Heavy Industries & Construction Co., Ltd. - Inventors: Seong Ju Kim; Hwan Chul Cho; Yang Oh Jin - Web page: https://patentgrep.com/patent/US20190315643A1 ## CPC - C02F 3/302: {Nitrification and denitrification treatment (C02F3/308 takes precedence)} - C02F 9/00: Multistage treatment of water, waste water or sewage - C02F 3/006: {Regulation methods for biological treatment} - C02F 3/2826: {using anaerobic filters} - C02F 3/2833: {using fluidized bed reactors} - C02F 3/303: {characterised by the nitrification} - C02F 3/305: {characterised by the denitrification} - C02F 3/307: {characterised by direct conversion of nitrite to molecular nitrogen, e.g. by using the Anammox process} - C02F 2101/16: Nitrogen compounds, e.g. ammonia - C02F 2209/14: NH3-N - C02F 2209/15: N03-N - C02F 2209/44: Time - C02F 2305/06: Nutrients for stimulating the growth of microorganisms - Y02W 10/10: Biological treatment of water, waste water, or sewage - C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes) - Y02W: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT ## Abstract A method for biologically treating nitrogen while minimizing energy and carbon source usage uses an aerobic tank, a first anoxic tank, and a second anoxic tank. The method includes introducing feed water by dividedly introducing the feed water to the aerobic tank and the first anoxic tank; converting ammonia nitrogen into nitrate nitrogen in the aerobic tank; converting the nitrate nitrogen into nitrite nitrogen through partial denitrification in the first anoxic tank using organic material contained in the feed water; and converting the nitrite nitrogen and ammonia into nitrogen gas in the second anoxic tank using an anammox microorganism. The ammonia nitrogen is converted by determining aeration intensity, aeration time, and/or aeration amount depending on an ammonia concentration in the aerobic tank. The nitrate nitrogen is converted by determining a reaction time of the first anoxic tank based on nitrate and nitrite concentrations in the first anoxic tank. ## Claims ### Claim 1 A method of biologically treating nitrogen using an apparatus comprising an aerobic tank, a first anoxic tank, and a second anoxic tank, the method comprising: introducing feed water; converting ammonia nitrogen into nitrate nitrogen in the aerobic tank; converting the nitrate nitrogen into nitrite nitrogen through partial denitrification in the first anoxic tank using an organic material contained in the feed water; and converting the nitrite nitrogen and ammonia into nitrogen gas in the second anoxic tank using an anammox microorganism. ### Claim 2 (depends on 1) The method of claim 1, wherein the feed water is introduced by dividedly introducing an amount of the feed water to the aerobic tank and an amount of the feed water to the first anoxic tank. ### Claim 3 (depends on 2) The method of claim 2, wherein 40% to 60% of the feed water is introduced to the aerobic tank and a remainder of the feed water is introduced to the first anoxic tank. ### Claim 4 (depends on 2) The method of claim 2, further comprising: adjusting the amount of the feed water introduced to the aerobic tank and the amount of the feed water introduced to the first anoxic tank, based on at least one of an ammonia concentration in the aerobic tank and concentrations of nitrate and nitrite in the first anoxic tank. ### Claim 5 (depends on 1) The method of claim 1, wherein the ammonia nitrogen is converted into the nitrate nitrogen by determining at least one of an aeration intensity, an aeration time, and an aeration amount depending on an ammonia concentration in the aerobic tank. ### Claim 6 (depends on 5) The method of claim 5, further comprising: measuring the ammonia concentration using an ammonia (NH4) sensor provided to the aerobic tank. ### Claim 7 (depends on 5) The method of claim 5, wherein the aeration intensity is determined at a starting point in the aerobic tank and at a position immediately before the first anoxic tank, and wherein the aeration intensity determined at the starting point in the aerobic tank and the aeration intensity determined at the position immediately before the first anoxic tank are different from each other. ### Claim 8 (depends on 5) The method of claim 5, wherein at least one of the aeration intensity and the aeration amount is decreased over time. ### Claim 9 (depends on 1) The method of claim 1, wherein the nitrate nitrogen is converted into the nitrite nitrogen by determining a reaction time of the first anoxic tank based on a nitrate concentration and a nitrite concentration in the first anoxic tank. ### Claim 10 (depends on 9) The method of claim 9, wherein the reaction time of the first anoxic tank is determined to be less than one hour in order to minimize a proportion of the nitrite nitrogen that is converted into nitrogen gas. ### Claim 11 (depends on 9) The method of claim 9, wherein the nitrite nitrogen and the ammonia are converted into the nitrogen gas by determining a reaction time of the second anoxic tank, and wherein the reaction time of the first anoxic tank and the reaction time of the second anoxic tank are determined so as to be different from each other based on the nitrate concentration and the nitrite concentration. ### Claim 12 (depends on 1) The method of claim 1, wherein the ammonia nitrogen and the nitrite nitrogen in the second anoxic tank are reacted at a molar ratio of 1:1 to 1:3. ### Claim 13 An apparatus for biologically treating nitrogen, the apparatus comprising: an aerobic tank for converting ammonia nitrogen of feed water into nitrate nitrogen; a first anoxic tank for converting the nitrate nitrogen into nitrite nitrogen; and a second anoxic tank for converting the nitrite nitrogen into nitrogen gas using an anammox microorganism. ### Claim 14 (depends on 13) The apparatus of claim 13, further comprising an ammonia (NH4) sensor provided to the aerobic tank. ### Claim 15 (depends on 13) The apparatus of claim 13, further comprising a nitrate (NO3) sensor and a nitrite (NO2) sensor respectively provided to the first anoxic tank. ### Claim 16 (depends on 13) The apparatus of claim 13, further comprising a feed water line provided so as to be branched to the aerobic tank and to the first anoxic tank. ### Claim 17 (depends on 13) The apparatus of claim 13, further comprising an external carbon source line for supplying an external carbon source to the first anoxic tank. ### Claim 18 (depends on 17) The apparatus of claim 17, wherein the external carbon source includes at least one selected from among glycerol, methanol, ethanol, and acetic acid. ### Claim 19 (depends on 13) The apparatus of claim 13, wherein the second anoxic tank is one of a fluidized-bed and a fixed-bed biofilm reactor. ### Claim 20 (depends on 13) The apparatus of claim 13, further comprising a return line connecting the second anoxic tank and the aerobic tank, wherein the ammonia nitrogen or the nitrite nitrogen is returned to the aerobic tank from the second anoxic tank via the return line.