# US 2019/0314838 A1 · Spray application system components comprising a repellent surface and methods

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- Number: US 2019/0314838 A1
- Document ID: US20190314838A1
- Status: Published application
- Kind: A1
- Application number: 16/451,702
- Filed: 2019-06-25
- Published: 2019-10-17
- Earliest claimed: 2014-10-28
- Assignees: 3M Innovative Properties Company
- Applicants: 3M Innovative Properties Company
- Inventors: Adam J. Meuler; Nicholas L. Untiedt; Stephen C.P. Joseph; Thomas P. Klun; Naiyong Jing; Paul B. Armstrong; David A. Gzik; Cheryl L.S. Elsbernd
- Web page: https://patentgrep.com/patent/US20190314838A1

## CPC

- B05B 7/2478: {Gun with a container which, in normal use, is located above the gun}
- B05B 7/2424: {the carried liquid and the main stream of atomising fluid being brought together downstream of the container before discharge (B05B7/2435 takes precedence)}
- B05B 7/2481: {with a flexible container for liquid or other fluent material}
- C09D 5/00: Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes
- C09D 7/61: inorganic
- C09D 7/63: organic
- C09D 127/06: Homopolymers or copolymers of vinyl chloride
- C09D 127/18: Homopolymers or copolymers of tetrafluoroethene
- C08K 3/36: Silica
- C08K 5/435: Sulfonamides
- C08K 5/5419: containing at least one Si—C bond
- C08K 9/02: Ingredients treated with inorganic substances
- C08K 9/06: with silicon-containing compounds
- B05B: SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES (spray-mixers with nozzles B01F25/72; processes for applying liquids or other fluent materials to surfaces by spraying B05D)
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)

## Abstract

Presently described are components of a spray application system. At least one component comprises a liquid repellent surface layer. The liquid repellent surface (e.g. layer) may comprise a porous layer and a lubricant impregnated into pores of the porous layer; a fluoropolymer; a fluorochemical material and an organic polymeric binder; or a fluorochemical material melt additive and a thermoplastic polymeric material component. The component is typically a liquid reservoir, a liquid reservoir liner, a lid for a liquid reservoir or liner, or a combination thereof. In some embodiments, the component comprises a thermoplastic polymeric material. In some favored embodiments, the component is a removable liquid reservoir or liner. In some favored embodiments, the component is a collapsible liquid reservoir or liner. The spray application system typically further comprises a gravity-fed spray gun. Also described are spray application systems, methods of using a spray application system, as well as methods of making a component of a spray application system wherein the component has a liquid repellent surface.

## Claims

### Claim 1

(canceled)

### Claim 2 (depends on 40)

The spray application system of claim 40 wherein the liquid repellent surface comprises a surface layer of a fluorochemical material.

### Claim 3 (depends on 40)

The spray application system of claim 40 wherein the liquid repellent surface layer further comprises a non-fluorinated organic polymeric binder.

### Claim 4 (depends on 2)

The spray application system of claim 2 wherein the fluorochemical material is a compound has the formula:
(Rf-L-P)nA
Rf is a fluorinated group;
L is independently an organic divalent linking group;
P is a catenary, divalent heteroatom-containing carbonyl moiety, such as —C(O)O—;
A is a hydrocarbon moiety;
and n typically ranges from 1 to 3.

### Claim 5 (depends on 4)

The spray application system of claim 4 wherein L is a hydrocarbon moiety comprising 4 to 40 carbon atoms.

### Claim 6

(canceled)

### Claim 7 (depends on 4)

The spray application system of claim 4 wherein Rf is CF3[CF2]3— for at least 50 wt.-% of the fluorochemical material.

### Claim at position 8

8-9. (canceled)

### Claim 10 (depends on 4)

The spray application system of claim 4 wherein n averages at least 2.

### Claim 11

(canceled)

### Claim 12 (depends on 3)

The spray application system of claim 3 wherein the non-fluorinated organic polymeric binder is selected from polystyrene, acrylic, polyester, polyurethane, polyolefin, and polyvinyl chloride.

### Claim 13

(canceled)

### Claim 14 (depends on 40)

The spray application system of claim 40 wherein the liquid repellent surface comprises a fluoropolymer, wherein the fluoropolymer is a copolymer of tetrafluoroethylene (TFE).

### Claim at position 14

15-21. (canceled)

### Claim 22 (depends on 40)

The spray application system of claim 40 wherein at least the liquid repellent surface of the component comprises a thermally processible polymer and a fluorochemical material melt additive.

### Claim 23

(canceled)

### Claim 24 (depends on 40)

The spray application system of claim 40, wherein the liquid repellent surface comprises a porous layer and a lubricant impregnated into pores of the porous layer.

### Claim 25

(canceled)

### Claim 26 (depends on 40)

The spray application system of claim 40 wherein the liquid reservoir and/or liner comprises a thermoplastic polymeric material.

### Claim 27 (depends on 40)

The spray application system of claim 40 wherein the liquid reservoir and/or liner is a removable liquid reservoir liner.

### Claim 28 (depends on 40)

The spray application system of claim 40 wherein the liquid reservoir and/or liner is a collapsible liquid reservoir or liner.

### Claim 29 (depends on 40)

The component spray application system of claim 40 wherein the liquid reservoir and/or liner spray application system further comprises a gravity-fed spray gun.

### Claim at position 23

30-31. (canceled)

### Claim 32 (depends on 40)

The spray application system of claim 40 wherein the organic solvent comprises one or more alcohol.

### Claim 33 (depends on 40)

The spray application system of claim 40 wherein the organic solvent comprises an alkylene glycol alkyl ether.

### Claim 34

(canceled)

### Claim 35 (depends on 40)

The spray application system of claim 40, wherein the liquid repellent surface repels the water-based paint such that the mass of retained paint is no greater than 0.01 g/cm2 after holding the liquid repellent surface vertically for 5 minutes.

### Claim 36

(canceled)

### Claim 37 (depends on 40)

The spray application system of claim 40, wherein the liquid repellent surface exhibits a receding contact angle with a solution containing 10% by weight of 2-n-butoxyethanol and 90% by weight deionized water of at least 40 degrees.

### Claim 38 (depends on 40)

The spray application system of claim 40, wherein a drop of the water-based paint slides off the surface when orientated vertically.

### Claim 39

(canceled)

### Claim 40

A spray application system comprising
a spray gun,
a liquid reservoir that attaches to the spray gun,
optionally a liner for the liquid reservoir, and
a lid for the liquid reservoir and/or liner;
wherein at least the liquid reservoir and/or liner comprises a liquid repellent surface such that the receding contact angle with water ranges from 90 degrees to 135 degrees and the liquid repellent surface repels water-based paint having a water soluble volatile organic solvent of at least 10 g/liter.
