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US 2019/0299494 A1Published application
Microwave welding of elastomer powder
AssigneeBASF SE
InventorsFrank PRISSOK, Michael HARMS
Life of this patent
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Abstract
A process for producing moldings from a powder based on thermoplastic elastomers, wherein the powder is placed on a mold or in a mold and by means of electromagnetic radiation is heated to an extent such that the powder undergoes at least partial melting and thus fuses to afford the molding and the frequency of the electromagnetic radiation is between 0.01 GHz and 300 GHz.
Claims21
1-21. (canceled)
22:
- A process for producing a molding from a powder based on a thermoplastic elastomer, the process comprising:
- placing the powder on or in a mold, and
- heating the powder with electromagnetic radiation, wherein a frequency of the electromagnetic radiation is between 0.01 and 100 GHz, such that the powder undergoes at least partial melting and fuses, to obtain the molding.
23:
- The process of claim 22, wherein the powder comprises:
- an elastomer that absorbs the electromagnetic radiation as a result of its chemical structure and/or
- at least one additive that absorbs the electromagnetic radiation.
24:
- The process of claim 23, wherein the elastomer is selected from the group consisting of a thermoplastic polyurethane (TPU), a thermoplastic polyester elastomer and a thermoplastic copolyamide.
25:
- The process of claim 24, wherein the thermoplastic polyester elastomer is selected from the group consisting of a polyetherester and a polyesterester and/or the thermoplastic copolyamide is selected from the group consisting of a polyetheramide and a polyesteramide.
26:
- The process of claim 22, wherein the elastomer is a thermoplastic polyurethane.
27:
- The process of claim 22, wherein an individual region of the molding is specifically heated with a maser or a targeted electromagnetic beam having a frequency between 0.01 GHz and 100 GHz.
28:
- The process of claim 27, wherein the powder is mixed with a pigment or a liquid dye prior to the heating.
29:
- The process of claim 28, wherein the pigment is inhomogeneously mixed with the powder and/or the powder is applied in at least two layers with different coloring.
30:
- The process of claim 22, wherein the molding is a hollow body produced by a rotational sintering process and the mold rotates in an electromagnetic radiation-emitting device or electromagnetic radiation is emitted inside a rotating mold by an antenna.
31:
- The process of claim 23, wherein the additive is glycerol triacetate, triethylene glycol, tripropylene glycol or citrate ester.
32:
- The process of claim 31, wherein the powder is produced by micropelletization.
33:
- The process of claim 31, wherein a maximum spatial extent of the powder is 200 μm to 1.0 mm.
34:
- The process of claim 31, wherein a total proportion of the elastomer and additive is 0.01% by weight to 30% by weight, based on a total weight of the powder.
35:
- The process of claim 31, wherein the elastomer is at least partially surrounded by a coating comprising the additive.
36:
- The process of claim 35, wherein the coating is based on a substance which has a boiling point above 120° C. and is soluble in the thermoplastic elastomer.
37:
- The process of claim 35, wherein a weight fraction of the coating is from 1% by weight to 5% by weight, based on a total weight of the powder.
38:
- The process of claim 31, wherein the powder has a poured density in a range from 200 kg/m3 to 900 kg/m3.
39:
- The process of claim 31, wherein the thermoplastic elastomer is selected from the group consisting of a thermoplastic polyurethane (TPU), a thermoplastic polyester elastomer and a thermoplastic copolyamide.
40:
- A molding, obtained by the process of claim 22.
41:
- A visible component, suitable for an automobile, an artificial leather, a bag, a packaging, a boot, a shoe, a shoe sole, a furnishing or furniture, and comprising the molding of claim 40.