Compound for organic electronic element, organic electronic element using same and electronic device therefor
AssigneeDuk San Neolux Co., Ltd.
InventorsSoung Yun MUN, Jae Taek KWON, Jong Gwang PARK, Yun Suk LEE, Won Sam KIM, Seul Gi KIM, Jin Bae JEON, Jung Hwan PARK
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Abstract
Provided are an organic electronic element and an electronic device therefor, the organic electronic element having a mixture of a compound according to the present invention used as material for an organic layer thereof, thereby enabling the achievement of high light-emitting efficiency and low driving voltage of the organic electronic element, and enabling the life of the element to be greatly extended.
Claims21
An organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode,
- wherein the organic material layer comprises an emitting layer,
- wherein the emitting layer comprises a first host compound represented by Formula (1) and a second host compound represented by Formula (2) as a phosphorescent light emitting layer:
- wherein:
- 1) Ar1, Ar2, Ar3, Ar4 and Ar5 are each independently selected from the group consisting of a C6-C60 aryl group;
- a fluorenyl group;
- a C2-C60 heterocyclic group including at least one hetero atom of O, N, S, Si or P;
- a fused ring group of a C3-C60 aliphatic ring and a C6-C60 aromatic ring;
- a C1-C50 alkyl group;
- a C2-C20 alkenyl group;
- a C2-C20 alkynyl group;
- a C1-C30 alkoxyl group;
- a C6-C30 aryloxy group;
- and -L′-N(Ra)(Rb);
- and Ar1 and Ar2 or Ar3 and Ar4 may be bonded to each other to form a ring,
- 2) c and e are an integer of 0 to 10, and d is an integer of 0 to 2,
- 3) R3, R4 and R5 are the same or different from each other, and are each independently selected from the group consisting of hydrogen;
- deuterium;
- halogen;
- a C6-C60 aryl group;
- a fluorenyl group;
- a C2-C60 heterocyclic group including at least one heteroatom of O, N, S, Si or P;
- a fused ring group of a C3-C60 aliphatic ring and a C6-C60 aromatic ring;
- a C1-C50 alkyl group;
- a C2-C20 alkenyl group;
- a C2-C20 alkynyl group;
- a C1-C30 alkoxyl group;
- a C6-C30 aryloxy group;
- and -L′-N(Ra)(Rb);
- or in case c, d and e are 2 or more, and R3, R4 and R5 are each in plural being the same or different, and a plurality of R3 or a plurality of R4 or a plurality of R5 may be bonded to each other to form a ring,
- 4) L1, L2, L3, L4, L5 and L6 are each independently selected from the group consisting of a single bond;
- a C6-C60 arylene group;
- and a fluorenylene group;
- a fused ring group of a C3-C60 aliphatic ring and a C6-C60 aromatic ring;
- and a C2-C60 heterocyclic group;
- provided that except when L5 is a single bond,
- 5) A and B are each independently a C6-C60 aryl group or a C2-C20 heterocyclic group, provided that when both A and B are a substituted or unsubstituted C6 aryl group (phenyl group), d is 2, and R4s are bonded to each other to form an aromatic or heterocyclic group,
- 6) i and j are 0 or 1, with the proviso that i+j is 1 or more, and when i or j is 0, it means a direct bond,
- 7) X1 and X2 are each independently N-L7-Ar6, O, S, or CR6R7, wherein L7 is the same as L1 to L4 or L6, wherein Ar6 is the same as Ar1 to Ar5, and R6 and R7 are each independently hydrogen;
- a C6-C60 aryl group;
- a fluorenyl group;
- a C2-C60 heterocyclic group;
- or a C1-C50 alkyl group and R6 and R7 may combine to each other to form a spiro ring,
- 8) L′ is selected from the group consisting of a single bond;
- a C6-C60 arylene group;
- a fluorenylene group;
- a fused ring group of a C3-C60 aliphatic ring and a C6-C60 aromatic ring;
- and a C2-C60 heterocyclic;
- and Ra and Rb are each independently selected from the group consisting of a C6-C60 aryl group;
- a fluorenyl group;
- a fused ring group of a C3-C60 aliphatic ring and a C6-C60 aromatic ring;
- and a C2-C60 heterocyclic group containing at least one hetero atom of O, N, S, Si, or P,
- wherein, the aryl group, fluorenyl group, arylene group, heterocyclic group, fused ring group, alkyl group, alkenyl group, alkoxy group and aryloxy group may be substituted with one or more substituents selected from the group consisting of deuterium;
- halogen;
- a silane group substituted or unsubstituted with C1-C20 alkyl group or C6-C20 aryl group;
- siloxane group;
- boron group;
- germanium group;
- cyano group;
- nitro group;
- -L′-N(Ra)(Rb);
- a C1-C20 alkylthio group;
- C1-C20 alkoxyl group;
- C1-C20 alkyl group;
- C2-C20 alkenyl group;
- C2-C20 alkynyl group;
- C6-C20 aryl group;
- C6-C20 aryl group substituted with deuterium;
- a fluorenyl group;
- C2-C20 heterocyclic group;
- C3-C20 cycloalkyl group;
- C7-C20 arylalkyl group;
- and C8-C20 arylalkenyl group;
- wherein the substituents may combine each other and form a saturated or unsaturated ring, wherein the term ‘ring’ means C3-C60 aliphatic ring or C6-C60 aromatic ring or a C2-C60 heterocyclic group or a fused ring formed by the combination of thereof and includes a saturated or unsaturated ring.
The organic electric element according to claim 1 comprising a compound represented by the following Formula (3) where Ar1 and Ar2 in Formula (1) form a ring:
- wherein
- 1) L3, L4, L5, Ar3 and Ar4 are the same as defined in claim 1,
- 2) a and b are each independently an integer of 0 to 4,
- 3) R1 and R2 are the same or different from each other, and are each independently selected from the group consisting of hydrogen;
- deuterium;
- halogen;
- a C6-C60 aryl group;
- a fluorenyl group;
- a C2-C60 heterocyclic group including at least one heteroatom of O, N, S, Si or P;
- a fused ring group of a C3-C20 aliphatic ring and a C6-C20 aromatic ring;
- a C1-C20 alkyl group;
- a C2-C20 alkenyl group;
- a C2-C20 alkynyl group;
- a C1-C20 alkoxyl group;
- a C6-C30 aryloxy group;
- and -L′-N(Ra)(Rb);
- or in case a and b are 2 or more, R1 and R2 are each in plural being the same or different, and a plurality of R1 or a plurality of R2 may be bonded to each other to form a ring.
The organic electric element according to claim 1, wherein L1, L2, L3, L4 and L5 in Formula (1) are each independently any one of the following Formulas (A-1) to (A-13):
- wherein:
- 1) a′, c′, d′ and e′ are an integer of 0 to 4;
- and b′ is an integer of 0 to 6;
- and f′ and g′ are an integer of 0 to 3;
- and h′ is an integer of 0 or 1;
- and i′ is an integer of 0 to 2;
- and j′ is an integer of 0 to 4;
- 2) R8, R9, R10 and R15 are the same or different from each other, and are each independently selected from the group consisting of hydrogen;
- deuterium;
- halogen;
- a C6-C20 aryl group;
- a fluorenyl group;
- a C2-C20 heterocyclic group including at least one heteroatom of O, N, S, Si or P;
- a fused ring group of a C3-C20 aliphatic ring and a C6-C20 aromatic ring;
- a C1-C20 alkyl group;
- a C2-C20 alkenyl group;
- a C2-C20 alkynyl group;
- a C1-C20alkoxyl group;
- a C6-C30 aryloxy group;
- and -L′-N(Ra)(Rb), wherein e′, f′, g′, i′ and j′ are 2 or more, R8, R9, R10 and R15 are the same or different from each other, and a plurality of R8 or a plurality of R9 or a plurality of R10 or a plurality of R15 or two adjacent R8 and R9, or R9 and R10, or R10 and R15 may be combined to each other to form an aromatic ring or heteroaromatic ring,
- 3) Y is N-L8-Ar7, O, S or CR11R12, wherein L8 is the same as L1 to L6 defined in claim 1, Ar7 is the same as Ar1 to Ar5 defined in claim 1, and R11 and R12 are the same as R6 and R7 defined in claim 1,
- 4) Z1, Z2 and Z3 are CR13 or N and at least one is N, and R13 is the same as R8 and R10 defined in claim 1.
Dependencies are inferred from the claim text.