Semi-crystalline thermoplastic polyester for producing fibres
AssigneeRoquette Freres
InventorsHélène AMEDRO, René SAINT-LOUP
Life of this patent
Estimating the term…
Abstract
Use of a thermoplastic polyester for producing fibres, said polyester having at least one 1,4:3,6-dianhydrohexitol unit (A), at least one alicyclic diol unit (B) other than the 1,4:3,6-dianhydrohexitol units (A), at least one terephthalic acid unit (C), wherein the ratio (A)/[(A)+(B)] is at least 0.05 and at most 0.30, said polyester being free of non-cyclic aliphatic diol units or comprising a molar amount of non-cyclic aliphatic diol units, relative to the totality of monomeric units in the polyester, of less than 5%, and with a reduced viscosity in solution (25° C.; phenol (50 wt. %): ortho-dichlorobenzene (50 wt. %); 5 g/L of polyester) greater than 50 mL/g.
Claims16
1-11. (canceled)
A method for the production of a fiber, comprising the following steps of:
- Provision of a semicrystalline thermoplastic polyester comprising at least one 1,4:3,6-dianhydrohexitol unit (A), at least one alicyclic diol unit (B) other than the 1,4:3,6-dianhydrohexitol units (A), at least one terephthalic acid unit (C), wherein the (A)/[(A)+(B)] molar ratio is at least 0.05 and at most 0.30, said polyester not containing any aliphatic non-cyclic diol units or comprising a molar amount of aliphatic non-cyclic diol units, relative to all the monomer units of the polyester, of less than 5%, and the reduced solution viscosity (25° C.;
- phenol (50% m):ortho-dichlorobenzene (50% m);
- 5 of polyester) of said polyester being greater than 50 ml/g;
- Preparation of said fiber from the semicrystalline thermoplastic polyester obtained in the preceding step.
A fiber comprising a semicrystalline thermoplastic polyester comprising:
- at least one 1,4:3,6-dianhydrohexitol unit (A);
- at least one alicyclic diol unit (B) other than the 1,4:3,6-dianhydrohexitol units (A);
- at least one terephthalic acid unit (C);
- wherein the (A)/[(A)+(B)] molar ratio is at least 0.05 and at most 0.30;
- said polyester not containing any aliphatic non-cyclic diol units or comprising a molar amount of aliphatic non-cyclic diol units, relative to all the monomer units of the polyester, of less than 5%, and the reduced solution viscosity (25° C.;
- phenol (50% m):ortho-dichlorobenzene (50% m);
- 5 g/l of polyester) of said polyester being greater than 50 ml/g.
A method for the production of a textile, comprising the following steps of:
- Provision of a fiber comprising a semicrystalline thermoplastic polyester comprising:
- at least one 1,4:3,6-dianhydrohexitol unit (A);
- at least one alicyclic diol unit (B) other than the 1,4:3,6-dianhydrohexitol units (A);
- at least one terephthalic acid unit (C);
- wherein the (A)/[(A)+(B)] molar ratio is at least 0.05 and at most 0.30;
- said polyester not containing any aliphatic non-cyclic diol units or comprising a molar amount of aliphatic non-cyclic diol units, relative to all the monomer units of the polyester, of less than 5%, and the reduced solution viscosity (25° C.;
- phenol (50% m):ortho-dichlorobenzene (50% m);
- 5 g/l of polyester) of said polyester being greater than 50 μg;
- and
- Preparation of said textile from the fiber obtained in the preceding step.
A method for the production of a nonwoven, comprising the following steps of:
- Provision of a fiber comprising a semicrystalline thermoplastic polyester comprising:
- at least one 1,4:3,6-dianhydrohexitol unit (A);
- at least one alicyclic diol unit (B) other than the 1,4:3,6-dianhydrohexitol units (A);
- at least one terephthalic acid unit (C);
- wherein the (A)/[(A)+(B)] molar ratio is at least 0.05 and at most 0.30;
- said polyester not containing any aliphatic non-cyclic diol units or comprising a molar amount of aliphatic non-cyclic diol units, relative to all the monomer units of the polyester, of less than 5%, and the reduced solution viscosity (25° C.;
- phenol (50% m):ortho-dichlorobenzene (50% m);
- 5 g/l of polyester) of said polyester being greater than 50 μg;
- and
- Preparation of said nonwoven from the fiber obtained in the preceding step.
Dependencies are inferred from the claim text.