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US 2019/0292099 A1Published application
Chemically strengthened glass and method for manufacturing chemically strengthened glass
AssigneeAGC Inc.
InventorsSuguru MURAYAMA, Yuriko BANNO
Life of this patent
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Abstract
A chemically strengthened glass having a thickness t of 2 mm or less, having a compressive stress value (CS90) at a portion of 90 μm deep from a glass surface being 25 MPa or more, and satisfying a number of fragments generated within a size of 25 mm×25 mm being 20 or less in a fracture test according to an indenter indentation test under a condition of holding a load ranging from 5 kgf to 10 kgf for 15 seconds with a pyramidal diamond indenter having an indenter angle of a facing angle of 60°.
Claims21
1-14. (canceled)
15:
- A chemically strengthened glass having a thickness t of 2 mm or less,
- having a compressive stress value (CS40) at a portion of 40 μm deep from a glass surface being 60 MPa or more, and having a surface compressive stress value (CS) being 450 MPa or more, and
- satisfying ΔCSDOL-20 (unit:
- MPa/μm) being 4.0 or less,
- wherein ΔCSDOL-20 is calculated according to the following expression using a compressive stress value CSDOL-20 at a depth closer to a glass surface side by 20 μm from DOL:
- ΔCSDOL-20=CSDOL-20/20,
- wherein the chemically strengthened glass has a matrix composition comprising, in terms of molar percentage on the basis of oxides, from 58 to 72% of SiO2, from 7 to 20% of Al2O3, from 3 to 15% of Li2O, from 0 to 10% of Na2O, from 0 to 8% of K2O, from 0 to 10% of MgO, from 0 to 3% of CaO, from 0 to 3% of SrO, from 0 to 3% of BaO, from 0 to 10% of ZnO, and from 0 to 4% of ZrO2.
4 more elements
16:
- The chemically strengthened glass according to claim 15, satisfying a number of fragments generated within a size of 25 mm×25 mm being 20 or less in a fracture test according to an indenter indentation test under a condition of holding a load ranging from 5 kgf to 10 kgf for 15 seconds with a pyramidal diamond indenter having an indenter angle of a facing angle of 60°.
17:
- The chemically strengthened glass according to claim 15, wherein the ΔCSDOL-20 (unit:
- MPa/μm) is 0.4 or more.
18:
- The chemically strengthened glass according to claim 15, wherein the ΔCSDOL-20 (unit:
- MPa/μm) is 1.6 or less.
19:
- The chemically strengthened glass according to claim 15, having a fracture stress value σa (bending strength, unit:
- MPa) being 150 MPa or more obtained by performing a four-point bending test under conditions of an under spun of 30 mm, an upper spun of 10 mm, and a crosshead speed of 0.5 mm/minute after the glass surface is flawed by pressing a diamond indenter (indenter angle of facing angle:
- 110°) thereto for 15 seconds at a load of 0.5 kgf.
20:
- The chemically strengthened glass according to claim 15, having a fracture stress value σc (bending strength, unit:
- MPa) being 150 MPa or more obtained by performing a four-point bending test under conditions of an under spun of 30 mm, an upper spun of 10 mm, and a crosshead speed of 0.5 mm/minute after the glass surface is flawed by pressing a diamond indenter (indenter angle of facing angle:
- 110°) thereto for 15 seconds at a load of 2 kgf.
21:
- The chemically strengthened glass according to claim 15, wherein the CS40 is 200 MPa or less.
22:
- The chemically strengthened glass according to claim 15, having a compressive stress value (CS90) at a portion of 90 μm deep from the glass surface being 40 MPa or more.
23:
- The chemically strengthened glass according to claim 22, wherein the CS90 is 75 MPa or less.
24:
- The chemically strengthened glass according to claim 22, satisfying ΔCS100-90 (unit:
- MPa/μm) being 0.4 or more,
- wherein ΔCS100-90 is calculated according to the following expression using CS90 and a compressive stress value (CS100) at a portion of 100 μm deep from the glass surface,
- ΔCS100-90=(CS90−CS100)/(100−90).
1 more element
25:
- The chemically strengthened glass according to claim 24, wherein the ΔCS100-90 (unit:
- MPa/μm) is 4.0 or less.
26:
- The chemically strengthened glass according to claim 25, wherein the ΔCS100-90 (unit:
- MPa/μm) is 1.6 or less.
27:
- The chemically strengthened glass according to claim 15, wherein the surface compressive stress value is 1500 MPa or less.
28:
- The chemically strengthened glass according to claim 15, having a depth of a compressive stress layer (DOL) being 120 μm or more and 180 μm or less.
29:
- The chemically strengthened glass according to claim 15, wherein the matric composition comprises, in terms of molar percentage on the basis of oxides, from 60 to 72% of SiO2, from 7 to 18% of Al2O3, from 0 to 3% of B2O3, from 0 to 3% of P2O5, from 6 to 13% of Li2O, from 3 to 10% of Na2O, from 0 to 2% of K2O, from 0 to 10% of MgO, from 0 to 0.2% of CaO, from 0 to 3% of SrO, from 0 to 3% of BaO, from 0 to 2% of ZnO, and from 0 to 2% of ZrO2.
30:
- The chemically strengthened glass according to claim 29, wherein MgO is contained.
31:
- The chemically strengthened glass according to claim 29, wherein the matrix composition comprises 0.5% or more of K2O.
32:
- The chemically strengthened glass according to claim 29, wherein the content of Li2O is 10% or less.
33:
- The chemically strengthened glass according to claim 29, wherein P2O5 is contained.
34:
- The chemically strengthened glass according to claim 29, wherein the matrix composition comprises 0.5% or more of ZrO2.