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US 2019/0249091 A1Published application
Aromatization Processes Using Both Fresh and Regenerated Catalysts, and Related Multi-Reactor Systems
AssigneeChevron Phillips Chemical Company LP
InventorsRyan W. Snell, Gabriela D. Alvez-Manoli, Xianghong Hao
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Abstract
Multi-reactor systems with aromatization reactor vessels containing a catalyst with low surface area and pore volume, followed in series by aromatization reactor vessels containing a catalyst with high surface area and pore volume, are disclosed. Related reforming methods using the different aromatization catalysts also are described.
Claims19
An aromatization process comprising:
- (i) introducing a first hydrocarbon feed into at least one first reactor vessel comprising a first aromatization catalyst, and contacting the first hydrocarbon feed with the first aromatization catalyst under first reforming conditions to produce a first aromatic product;
- wherein:
- the first aromatization catalyst comprises platinum and a first catalyst support, the first aromatization catalyst characterized by:
- a first surface area in a range from about 80 m2/g to about 150 m2/g;
- and/or a first micropore volume in a range from about 0.01 cc/g to about 0.048 cc/g;
- (ii) discharging a first effluent comprising the first aromatic product from the at least one first reactor vessel;
- (iii) heating the first effluent to form a second hydrocarbon feed;
- (iv) introducing the second hydrocarbon feed into at least one second reactor vessel comprising a second aromatization catalyst, and contacting the second hydrocarbon feed with the second aromatization catalyst under second reforming conditions to produce a second aromatic product;
- wherein:
- the second aromatization catalyst comprises platinum and a second catalyst support, the second aromatization catalyst characterized by:
- a second surface area in a range from about 160 m2/g to about 260 m2/g;
- and/or
- a second micropore volume in a range from about 0.05 cc/g to about 0.09 cc/g;
- and
- (v) discharging a second effluent comprising the second aromatic product from the at least one second reactor vessel, wherein:
- the first aromatization catalyst is a regenerated catalyst;
- the first aromatization catalyst has a lower platinum dispersion than that of the second aromatization catalyst and
- the first aromatization catalyst has an aromatics selectivity that is substantially the same as or better than that of the second aromatization catalyst.
15 more elements
12-20. (canceled)
25 The process of claim 23, wherein:
- a weight ratio of the first aromatization catalyst to the second aromatization catalyst is in a range from about 1:2 to about 1:20;
- the first aromatization catalyst has from 10% to 30% lower platinum dispersion than that of the second aromatization catalyst;
- and
- the first aromatic product and the second aromatic product, independently, comprise benzene, toluene, or a combination thereof.
1 more element
Dependencies are inferred from the claim text.