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AssigneeResinate Materials Group, Inc.
InventorsShakti L. Mukerjee, Rick Tabor, Adam William Emerson, Kevin Anthony Rogers, Eric D. Vrabel, Matthew T. Brown, Matthew J. Beatty, Jack Rogers Kovsky, Michael D. Kellerman, Michael Robert Christy
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Polyester polyols made from thermoplastic polyesters are disclosed. The polyols can be made by heating a thermoplastic polyester such as virgin PET, recycled PET, or mixtures thereof, with a glycol to give a digested intermediate, which is then condensed with a dimer fatty acid to give the polyol. The invention includes a polyester polyol comprising recurring units of a glycol-digested thermoplastic polyester and a dimer fatty acid. The polyester polyol can also be made in a single step by reacting the thermoplastic polyester, glycol, and dimer acid under conditions effective to produce the polyol. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.
A process which comprises:
A process which comprises reacting a glycol-digested polyethylene terephthalate (PET) or glycol-modified polyethylene terephthalate (PETG) with a glycol selected from the group consisting of propylene glycol, diethylene glycol, 2-methyl-1,3-propanediol, sorbitol, neopentyl glycol, glycerol, 2,2,4,4-tetramethyl-1,3-cyclobutanediol, 3-methyl-1,5-pentanediol, 1,4-cyclohexanedimethanol, 1,3-cyclohexanedimethanol, bisphenol A ethoxylates, 1,6-hexanediol, block or random copolymers of ethylene oxide and propylene oxide, and mixture thereof, and an unsaturated dimer fatty acid to produce the polyol, wherein the molar ratio of dimer fatty acid to PET or PETG is within the range of 0.1 to 0.5, the molar ratio of glycol to PET or PETG is within the range of 2.5 to 4.5, and the polyol has a hydroxyl number within the range of 40 to 400 mg KOH/g.
Dependencies are inferred from the claim text.