Group iii base stocks and lubricant compositions
AssigneeExxonMobil Research and Engineering Company
InventorsDaniel J. EICHELSDOERFER, Richard C. DOUGHERTY, Charles L. BAKER, JR., Debra A. SYSYN
Life of this patent
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Abstract
Disclosed are Group III base stocks comprising greater than or equal to about 90 wt. % saturated hydrocarbons (saturates); a viscosity index from 120 to 145; a unique ratio of molecules with multi-ring naphthenes to single ring naphthenes (2R+N/1RN); a unique ratio of branched carbons to straight chain carbons (BC/SC); a unique ratio of branched carbons to terminal carbons (BC/TC); and unique MRV behavior as a function of base stock naphthene ratio (2R+N/1RN). A method for preparing the base stocks is also disclosed. Also disclosed is a lubricating oil having the base stock as a major component, and an additive as a minor component.
Claims27
A Group III base stock comprising;
- at least 90 wt. % saturated hydrocarbons:
- kinematic viscosity at 100° C. of 4.0 cSt to 5.0 cSt;
- a viscosity index of 120 to 140;
- a ratio of multi-ring naphthenes to single ring naphthenes (2R+N/1RN) of less than 0.52;
- and
- a ratio of branched carbons to straight chain carbons (BC/SC) less than or equal to 0.21.
A Group III base stock comprising:
- at least 90 wt. % saturated hydrocarbons;
- kinematic viscosity at 100° C. of 5.0 cSt to 12.0 cSt;
- a viscosity index of 120 to 140;
- a ratio of multi-ring naphthenes to single ring naphthenes (2R+N/1RN) of less than 0.59;
- and
- a ratio of branched carbons to straight chain carbons (BC/SC) less than or equal to 0.216.
A method for producing a diesel fuel and an API Group III base stock, comprising:
- providing a feed stock comprising a vacuum gas oil feed;
- hydrotreating the feed stock under first effective hydrotreating conditions to produce a first hydrotreated effluent;
- hydrotreating the first hydrotreated effluent under second effective hydrotreating conditions to produce a second hydrotreated effluent;
- fractionating the second hydrotreated effluent to produce at least a first diesel product fraction and a bottoms fraction;
- hydrocracking the bottoms fraction under effective hydrocracking conditions to produce a hydrocracked effluent;
- dewaxing the hydrocracked effluent under effective catalytic dewaxing conditions to produce a dewaxed effluent, the dewaxing catalyst including at least one non-dealuminated, unidimensional, 10-member ring pore zeolite, and at least one Group VI metal, Group VIII metal or combination thereof;
- hydrotreating the dewaxed effluent under third effective hydrotreating conditions to produce a third hydrotreated effluent;
- and
- fractionating the third hydrotreated effluent to form at least a second diesel product fraction and a base stock product fraction, wherein the Group III lubricant base stock product fraction includes greater than or equal to 90 wt. % saturated hydrocarbons, a kinematic viscosity at 100° C. between 4 cSt and 5 cSt and has a ratio of multi-ring naphthenes to single ring naphthenes (2R+N/1RN) of less than about 0.52, and a ratio of branched carbons to straight chain (BC/SC) carbons less than or equal to 0.21.
A method for producing a diesel fuel and a base stock, comprising:
- providing a feed stock comprising a vacuum gas oil feed;
- hydrotreating the feed stock under first effective hydrotreating conditions to produce a first hydrotreated effluent;
- hydrotreating the first hydrotreated effluent under second effective hydrotreating conditions to produce a second hydrotreated effluent;
- fractionating the second hydrotreated effluent to produce at least a first diesel product fraction and a bottoms fraction;
- hydrocracking the bottoms fraction under effective hydrocracking conditions to produce a hydrocracked effluent;
- dewaxing the hydrocracked effluent under effective catalytic dewaxing conditions to produce a dewaxed effluent, the dewaxing catalyst including at least one non-dealuminated, unidimensional, 10-member ring pore zeolite, and at least one Group VI metal, Group VIII metal or combination thereof;
- hydrotreating the dewaxed effluent under third effective hydrotreating conditions to produce a third hydrotreated effluent;
- and
- fractionating the third hydrotreated effluent to form at least a second diesel product fraction and a base stock product fraction, wherein the Group III lubricant base stock product fraction includes greater than or equal to 95 wt. % saturated hydrocarbons, a kinematic viscosity at 100° C. between 5 cSt and 12 cSt and has a ratio of multi-ring naphthenes to single ring naphthenes (2R+N/1RN) of less than about 0.59, and a ratio of branched carbons to straight chain (BC/SC) carbons less than or equal to 0.26.
Dependencies are inferred from the claim text.