Emm-31 materials and processes and uses thereof
AssigneeExxonMobil Research and Engineering Company
InventorsKirk D. Schmitt, Allen W. Burton, Hilda B. Vroman, Karl G. Strohmaier, Simon C. Weston, Michael A. Marella, Ross Mabon
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Abstract
The disclosure is related to EMM-31 materials, processes, and uses of the same as well as reagents used in the preparation of the EMM-31 materials, process and intermediates for preparing these reagents.
Claims30
A crystalline material having at least six XRD peaks selected from Table 1:
- TABLE 1
- degree 2-theta
- relative intensity
- (±0.2)
- [100 × I/(Io)]
- 6.39
- 60-100
- 7.78
- 60-80
- 8.22
- 20-40
- 8.82
- 20-40
- 9.34
- 10-30
- 9.89
- 5-25
- 13.31
- 20-40
- 19.40
- 60-100
- 23.13
- 60-90
- 23.71
- 15-35
- wherein part or all of a structure directing agent that is present in the material is removed.
A crystalline material having a framework defined by the following connectivities in Table 2 for the tetrahedral (T) atoms in the unit cell, the tetrahedral (T) atoms being connected by bridging atoms:
- TABLE 2
- T atom
- Connected to:
- T1
- T2, T4, T37, T100
- T2
- T1, T3, T6, T57
- T3
- T2, T5, T56, T99
- T4
- T1, T64, T95, T121
- T5
- T3, T6, T65, T94
- T6
- T2, T5, T66, T126
- T7
- T8, T10, T43, T104
- T8
- T7, T9, T12, T51
- T9
- T8, T11, T50, T103
- T10
- T7, T70, T89, T125
- T11
- T9, T12, T71, T88
- T12
- T8, T11, T72, T122
- T13
- T14, T16, T25, T108
- T14
- T13, T15, T18, T69
- T15
- T14, T17, T68, T107
- T16
- T13, T52, T83, T113
- T17
- T15, T18, T53, T82
- T18
- T14, T17, T54, T118
- T19
- T20, T22, T31, T112
- T20
- T19, T21, T24, T63
- T21
- T20, T23, T62, T111
- T22
- T19, T58, T77, T117
- T23
- T21, T24, T59, T76
- T24
- T20, T23, T60, T114
- T25
- T13, T26, T28, T116
- T26
- T25, T27, T30, T81
- T27
- T26, T29, T80, T115
- T28
- T25, T71, T88, T105
- T29
- T27, T30, T70, T89
- T30
- T26, T29, T90, T110
- T31
- T19, T32, T34, T120
- T32
- T31, T33, T36, T75
- T33
- T32, T35, T74, T119
- T34
- T31, T65, T94, T109
- T35
- T33, T36, T64, T95
- T36
- T32, T35, T96, T106
- T37
- T1, T38, T40, T124
- T38
- T37, T39, T42, T93
- T39
- T38, T41, T92, T123
- T40
- T37, T59, T76, T97
- T41
- T39, T42, T58, T77
- T42
- T38, T41, T78, T102
- T43
- T7, T44, T46, T128
- T44
- T43, T45, T48, T87
- T45
- T44, T47, T86, T127
- T46
- T43, T53, T82, T101
- T47
- T45, T48, T52, T83
- T48
- T44, T47, T84, T98
- T49
- T50, T52, T85, T124
- T50
- T9, T49, T51, T54
- T51
- T8, T50, T53, T123
- T52
- T16, T47, T49, T97
- T53
- T17, T46, T51, T54
- T54
- T18, T50, T53, T102
- T55
- T56, T58, T91, T128
- T56
- T3, T55, T57, T60
- T57
- T2, T56, T59, T127
- T58
- T22, T41, T55, T101
- T59
- T23, T40, T57, T60
- T60
- T24, T56, T59, T98
- T61
- T62, T64, T73, T116
- T62
- T21, T61, T63, T66
- T63
- T20, T62, T65, T115
- T64
- T4, T35, T61, T105
- T65
- T5, T34, T63, T66
- T66
- T6, T62, T65, T110
- T67
- T68, T70, T79, T120
- T68
- T15, T67, T69, T72
- T69
- T14, T68, T71, T119
- T70
- T10, T29, T67, T109
- T71
- T11, T28, T69, T72
- T72
- T12, T68, T71, T106
- T73
- T61, T74, T76, T108
- T74
- T33, T73, T75, T78
- T75
- T32, T74, T77, T107
- T76
- T23, T40, T73, T113
- T77
- T22, T41, T75, T78
- T78
- T42, T74, T77, T118
- T79
- T67, T80, T82, T112
- T80
- T27, T79, T81, T84
- T81
- T26, T80, T83, T111
- T82
- T17, T46, T79, T117
- T83
- T16, T47, T81, T84
- T84
- T48, T80, T83, T114
- T85
- T49, T86, T88, T100
- T86
- T45, T85, T87, T90
- T87
- T44, T86, T89, T99
- T88
- T11, T28, T85, T121
- T89
- T10, T29, T87, T90
- T90
- T30, T86, T89, T126
- T91
- T55, T92, T94, T104
- T92
- T39, T91, T93, T96
- T93
- T38, T92, T95, T103
- T94
- T5, T34, T91, T125
- T95
- T4, T35, T93, T96
- T96
- T36, T92, T95, T122
- T97
- T40, T52, T98, T100
- T98
- T48, T60, T97, T99
- T99
- T3, T87, T98, T100
- T100
- T1, T85, T97, T99
- T101
- T46, T58, T102, T104
- T102
- T42, T54, T101, T103
- T103
- T9, T93, T102, T104
- T104
- T7, T91, T101, T103
- T105
- T28, T64, T106, T108
- T106
- T36, T72, T105, T107
- T107
- T15, T75, T106, T108
- T108
- T13, T73, T105, T107
- T109
- T34, T70, T110, T112
- T110
- T30, T66, T109, T111
- T111
- T21, T81, T110, T112
- T112
- T19, T79, T109, T111
- T113
- T16, T76, T114, T116
- T114
- T24, T84, T113, T115
- T115
- T27, T63, T114, T116
- T116
- T25, T61, T113, T115
- T117
- T22, T82, T118, T120
- T118
- T18, T78, T117, T119
- T119
- T33, T69, T118, T120
- T120
- T31, T67, T117, T119
- T121
- T4, T88, T122, T124
- T122
- T12, T96, T121, T123
- T123
- T39, T51, T122, T124
- T124
- T37, T49, T121, T123
- T125
- T10, T94, T126, T128
- T126
- T6, T90, T125, T127
- T127
- T45, T57, T126, T128
- T128
- T43, T55, T125, T127
- wherein part or all of a structure directing agent that is present in the material is removed.
An as-made crystalline material having at least three XRD peaks selected from Table 3:
- TABLE 3
- degrees 2-theta
- relative intensity
- (±0.2)
- [100 × I/(Io)]
- 6.34
- 20-60
- 7.75
- 10-30
- 8.25
- 20-60
- 8.71
- 20-40
- 9.32
- 1-20
- 15.47
- 1-20
- 19.37
- 40-80
- 21.40
- 40-70
- 22.92
- 60-100
- 23.51
- 20-50
A structure directing agent compound having the following structure of Compound E:
- wherein A is an ion.
Dependencies are inferred from the claim text.