# US 2019/0173213 A1 · Anticorrosive agent and terminal fitted electric wire

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- Number: US 2019/0173213 A1
- Document ID: US20190173213A1
- Status: Published application
- Kind: A1
- Application number: 16/060,060
- Filed: 2016-12-21
- Published: 2019-06-06
- Earliest claimed: 2016-01-07
- Assignees: Autonetworks Technologies, Ltd.; Sumitomo Wiring Systems, Ltd.; Sumitomo Electric Industries, Ltd.; Kyushu University
- Applicants: Autonetworks Technologies, Ltd.; Sumitomo Wiring Systems, Ltd.; Sumitomo Electric Industries, Ltd.; Kyushu University
- Inventors: Yutaka TAKATA; Takehiro HOSOKAWA; Tatsuya HASE; Naoyuki OSHIUMI; Takuya YAMASHITA; Makoto MIZOGUCHI
- Web page: https://patentgrep.com/patent/US20190173213A1

## CPC

- H01R 13/03: characterised by the material, e.g. plating, or coating materials
- C08K 5/521: Esters of phosphoric acids, e.g. of H3PO4
- C09D 5/08: Anti-corrosive paints
- C09D 7/40: Additives
- C23F 11/00: Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent (adding inhibitors to mineral oil, fuels, or lubricants C10; adding inhibitors to pickling solutions C23G)
- C23F 11/1673: {Esters of phosphoric or thiophosphoric acids}
- H01B 7/2806: {Protection against damage caused by corrosion}
- H01R 4/185: {combined with a U-shaped insulation-receiving portion}
- H01R 4/70: Insulation of connections (end caps H01R4/22)
- H01R: ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- C23F: NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE (working metal by laser beams B23K26/00; desurfacing by applying flames B23K7/00; working of metal by electro-erosion B23H; producing decorative effects by removing surface material, e.g. by engraving, by etching, B44C1/22; electrolytic etching or polishing C25F); INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- H01B: CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES (selection for magnetic properties H01F1/00; waveguides H01P {; printed circuits H05K})

## Abstract

An anticorrosive agent maintains its anticorrosion property when the agent is applied to the connection part of the terminal-fitted electric wire containing a covering member containing a plasticizer, and is exposed to high temperature. A terminal-fitted electric wire improves in anticorrosion property by using the agent. The anticorrosive agent contains a base oil (A) having a viscosity of 30 mPa·s or higher at 100° C., and a metal adsorbent (B) containing a phosphorus compound. The mass composition ratio (A):(B) of the base oil (A) and the metal adsorbent (B) is within a range of 50:50 to 98:2. In the terminal-fitted electric wire, an electric connection part between a terminal and an electric conductor is covered with a film of the anticorrosive agent.

## Claims

### Claim 1

An anticorrosive agent comprising:
a base oil (A) having a viscosity of 100 mPa·s or higher at 100° C., and
a metal adsorbent (B) comprising a phosphorus compound,
wherein a mass composition ratio (A):(B) of the base oil (A) and the metal adsorbent (B) is within a range of 50:50 to 98:2.

### Claim 2 (depends on 1)

The anticorrosive agent according to claim 1, wherein the metal adsorbent (b) is a composition of a phosphorus compound comprising one or more compounds represented by the general formulae (1) and (2) and a metal:
where X1 to X7 each represent independently an oxygen atom or a sulfur atom, R11 to R13 each represent independently a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms, among which at least one is a hydrocarbon group having 1 to 30 carbon atoms, and R14 to R16 each represent independently a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atom among which at least one is a hydrocarbon group having 1 to 30 carbon atoms.

### Claim 3 (depends on 1)

The anticorrosive agent according to claim 1, wherein the phosphorus compound has one or more branched linear structures or one or more carbon-carbon double bond structures in the structure of the hydrocarbon groups.

### Claim 4 (depends on 1)

The anticorrosive agent according to claim 1, wherein the metal forming the composition together with the phosphorus compound is at least one selected from alkali metals, alkaline earth metals, aluminum, titanium, and zinc.

### Claim 5 (depends on 1)

The anticorrosive agent according to claim 1, wherein the composition of the phosphorus compound and the metal has a molecular weight of 3000 or lower.

### Claim 6 (depends on 1)

A terminal-fitted electric wire, wherein an electric connection part between a terminal and an electric conductor is covered with the anticorrosive agent according to claim 1.

### Claim 7 (depends on 2)

The anticorrosive agent according to claim 2, wherein the phosphorus compound has one or more branched linear structures or one or more carbon-carbon double bond structures in the structure of the hydrocarbon groups.

### Claim 8 (depends on 7)

The anticorrosive agent according to claim 7, wherein the metal forming the composition together with the phosphorus compound is at least one selected from alkali metals, alkaline earth metals, aluminum, titanium, and zinc.

### Claim 9 (depends on 8)

The anticorrosive agent according to claim 8, wherein the composition of the phosphorus compound and the metal has a molecular weight of 3000 or lower.

### Claim 10 (depends on 9)

A terminal-fitted electric wire, wherein an electric connection part between a terminal and an electric conductor is covered with the anticorrosive agent according to claim 9.
