# US 2019/0169441 A1 · Curable composition, process for producing same, and article produced therewith

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- Number: US 2019/0169441 A1
- Document ID: US20190169441A1
- Status: Published application
- Kind: A1
- Application number: 16/315,219
- Filed: 2017-07-07
- Published: 2019-06-06
- Earliest claimed: 2016-07-08
- Assignees: Daikin Industries, Ltd.
- Applicants: Daikin Industries, Ltd.
- Inventors: Tsuneo YAMASHITA; Eiji SAKAMOTO; Saya NII; Makoto HANAZAWA
- Web page: https://patentgrep.com/patent/US20190169441A1

## CPC

- C08F 290/067: {Polyurethanes; Polyureas}
- C09D 5/00: Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes
- B32B 27/30: comprising vinyl {(co)polymers; comprising acrylic (co)polymers}
- C08F 290/00: Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08J 5/18: Manufacture of films or sheets
- C09D 4/06: {Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond} in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
- C09D 133/16: Homopolymers or copolymers of esters containing halogen atoms
- C09D 133/24: Homopolymers or copolymers of amides or imides
- C09D 175/14: Polyurethanes having carbon-to-carbon unsaturated bonds
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)

## Abstract

A curable composition including a compound having a perfluoropolyether group and a curable moiety, and a curable resin and/or a curable monomer, wherein an organic solvent having no radical reactive group is not substantially contained. The curable composition is capable of forming a surface-treating layer that is in a lower clouded state.

## Claims

### Claim 1

A curable composition comprising:
a compound having a perfluoropolyether group and a curable moiety; and
a curable resin and/or a curable monomer,
wherein an organic solvent having no radical reactive group is not substantially contained.

### Claim 2 (depends on 1)

The curable composition according to claim 1, wherein a viscosity at 25° C. is 5 to 100,000 mPa·s.

### Claim 3 (depends on 1)

The curable composition according to claim 1, wherein the compound having a perfluoropolyether group and a curable moiety further has a triisocyanate structure.

### Claim 4 (depends on 1)

The curable composition according to claim 1, wherein the compound having a perfluoropolyether group and a curable moiety further has an isocyanurate type polyisocyanate structure.

### Claim 5 (depends on 1)

The curable composition according to claim 1, wherein the compound having a perfluoropolyether group and a curable moiety is contained at 5 to 80% by mass relative to the total amount of curable composition.

### Claim 6 (depends on 1)

The curable composition according to claim 1, wherein the content of tin atoms, titanium atoms or zirconium atoms relative to 100% by mass of the curable composition is 10 ppm by mass or less.

### Claim 7 (depends on 1)

The curable composition according to claim 1, wherein the curable resin and/or the curable monomer has a halogen atom-containing curable resin and/or a halogen atom-containing curable monomer.

### Claim 8 (depends on 1)

The curable composition according to claim 1, wherein the curable resin and/or the curable monomer has a halogen atom-containing (meth)acrylate monomer.

### Claim 9 (depends on 8)

The curable composition according to claim 8, wherein the halogen atom-containing (meth)acrylate monomer is a monomer in which a hydrogen atom bonded to a carbon atom at an α-position is substituted with a halogen atom.

### Claim 10

A process for producing a curable composition comprising:
removing (C) an organic solvent having no radical reactive group from a mixture comprising
a reactive composition comprising (A) a compound having a perfluoropolyether group and a curable moiety and (C) the organic solvent, and
(B) a curable resin and/or a curable monomer.

### Claim 11

A process for producing a curable composition comprising:
mixing a reactive composition comprising (A) a compound having a perfluoropolyether group and a curable moiety and (C) an organic solvent having no radical reactive group with a solvent;
forming a precipitate containing the component (A);
separating the precipitate; and
mixing the separated precipitate with (B) a curable resin and/or a curable monomer.

### Claim 12 (depends on 10)

The process for producing a curable composition according to claim 10, further comprising reacting (a1) a compound having an isocyanate group and (b1) a compound having an active hydrogen to obtain a component (A).

### Claim 13 (depends on 1)

An article comprising:
a base material; and
a surface-treating layer which is derived from the curable composition according to claim 1 and formed on a surface of the base material.

### Claim 14

A film having a concavity and convexity structure on its surface,
wherein pencil hardness on the surface is 2H or more, a water contact angle on the surface is 140° or more, and an n-hexadecane contact angle on the surface is 70° or more.

### Claim 15 (depends on 11)

The process for producing a curable composition according to claim 11, further comprising reacting (a1) a compound having an isocyanate group and (b1) a compound having an active hydrogen to obtain a component (A).
