# US 2019/0169319 A1 · Method and system for the control of a plant for the continuous production of a polymer

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 2019/0169319 A1
- Document ID: US20190169319A1
- Status: Published application
- Kind: A1
- Application number: 16/321,849
- Filed: 2017-08-02
- Published: 2019-06-06
- Earliest claimed: 2016-08-03
- Assignees: Versalis S.P.A.
- Applicants: Versalis S.P.A.
- Inventors: Marianna SUAR
- Web page: https://patentgrep.com/patent/US20190169319A1

## CPC

- C08F 2/01: characterised by special features of the polymerisation apparatus used
- B01J 19/0033: {Optimalisation processes, i.e. processes with adaptive control systems (adaptive control systems per se G05B13/00)}
- B01J 19/06: Solidifying liquids (making microcapsules B01J13/02)
- B01J 19/2465: {externally, i.e. the mixture leaving the vessel and subsequently re-entering it}
- C08F 2/04: Polymerisation in solution (C08F2/32 takes precedence)
- C08F 2/38: Polymerisation using regulators, e.g. chain terminating agents {, e.g. telomerisation}
- C08F 2/44: Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
- B01J 2219/00164: controlling the flow
- B01J 2219/00186: controlling the composition of the reactive mixture
- C08F 2400/02: Control or adjustment of polymerization parameters
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

## Abstract

A method for the control of a plant (10) for the production in continuous of a polymer, wherein the plant (10) comprises at least one reactor (11) fed with at least a first monomer and a second monomer, a first stripper (12), a second stripper (17), a third stripper (18), at least one recycling vat (13) of the fine products, measurement equipment (14) and a control system comprising distributed control devices (15) controllable by at least one electronic processing and control unit (16) based on a plurality of control variables, the control method comprising the following steps: collecting data comprising recipe parameters, laboratory analysis results and predefined coefficients stored in a database (40); collecting the data measured by the measurement equipment (14); determining, by means of a first calculation module (20) a production potentiality value of the at least one reactor (11); determining, by means of a second calculation module (21) the polymer concentration in the at least one reactor (11), in the first stripper (12) and in the at least one recycling vat of the fine products (13); determining, by means of a third calculation module (22) the flow-rate of oil for feeding the second stripper (17); determining, by means of a fourth calculation module (23), the flow-rate of the chain terminator (TERM) for feeding the at least one reactor (11), controlling the plant (10) on the basis of the plurality of control variables.

## Claims

### Claim 1

A method for the control of a plant for the production in continuous of a polymer, wherein said plant comprises a reaction section comprising at least one reactor fed with at least a first monomer and a second monomer, a stripping section comprising a first high-pressure stripper, a second low-pressure stripper, a third low-pressure stripper, a finishing section comprising at least one recycling vat of the fine products, a plurality of measurement equipment of the operational conditions of said plant and a control system comprising a plurality of distributed control devices controlled by at least one electronic processing and control unit on the basis of a plurality of control variables comprising at least the oil flow-rate for feeding said first stripper, and the flow-rate of chain terminator for feeding said at least one reactor, and the vent flow-rate of a thermostatic circuit of said at least one reactor, said plurality of control variables being calculated by a plurality of calculation modules, said control method comprising:
collecting a plurality of data, comprising recipe parameters, results of laboratory analyses and predefined coefficients stored in databases;
collecting the data measured by said measurement equipment;
determining, by a first calculation module of said plurality of calculation modules, a production potentiality value of said at least one reactor on the basis of said recipe parameters, said laboratory analysis results, said predefined coefficients and said data measured by said measurement equipment;
determining, by a second calculation module of said plurality of calculation modules, the polymer concentration in said at least one reactor, in said first stripper and in said at least one recycling vat of the end products, based on the production potentiality value of the at least one reactor determined by said first calculation module, said recipe parameters, said laboratory analysis results, said predefined coefficients and said data measured by said measurement equipment;
determining, by a third calculation module of said plurality of calculation modules, said oil flow-rate for feeding said second stripper, in order to obtain a weight percentage fraction of oil equal to a respective recipe parameter called target weight percentage fraction of oil on the basis of said production potentiality value of the at least one reactor determined by said first calculation module, of the concentration value of the polymer in the first stripper determined by the second calculation module, said recipe parameters, said laboratory analysis results, said predefined coefficients and said data measured by the measurement equipment;
determining, by a fourth calculation module of said plurality of calculation modules, the flow-rate of the chain terminator (TERM) for feeding said at least one reactor, in order to obtain a substantially constant viscosity value of the polymer and equal to a respective recipe parameter called target viscosity of the polymer, and a TERM molar percentage fraction value equal to a respective recipe parameter called target TERM molar percentage fraction, based on the production potentiality value of said at least one reactor determined by said first calculation module, said recipe parameters, said laboratory analysis results, said predefined coefficients and said data measured by the measurement equipment;
controlling said plant on the basis of said plurality of control variables determined.

### Claim 2 (depends on 1)

The method according to claim 1, wherein said production potentiality value of said at least one reactor is calculated as a ratio between the recycling flow-rate to the reactor detected by one of said measurement apparatuses and a conversion factor.

### Claim 3 (depends on 1)

The method according to claim 1, wherein said plurality of control variables comprises the flow-rate of a third monomer for feeding said at least one reactor, said method comprising:
determining, by a fifth calculation module of said plurality of calculation modules, the flow-rate of the third monomer in order to obtain a concentration of said third monomer equal to a recipe parameter called third monomer target concentration based on the production potentiality value of the at least one reactor determined by said first calculation module, said recipe parameters, said laboratory analysis results, said predefined coefficients and said data measured by the measurement equipment.

### Claim 4 (depends on 1)

The method according to claim 1, wherein said plurality of control variables comprises the flow-rate of antipacking agent for feeding said first stripper, said method comprising:
determining, by a sixth calculation module of said plurality of calculation modules, the flow-rate of antipacking agent in order to obtain a weight percentage fraction of antipacking agent equal to a respective recipe parameter called target weight percentage fraction of antipacking agent based on the production potentiality value of the at least one reactor determined by said first calculation module, said recipe parameters, said laboratory analysis results, said predefined coefficients and said data measured by the measurement equipment.

### Claim 5 (depends on 1)

The method according to claim 1, wherein said plurality of control variables comprises the flow-rate of said second monomer in a mixture with a diluent for feeding a process tank, said method comprising:
determining, by a seventh calculation module of said plurality of calculation modules, the flow-rate of the second monomer in a mixture with a diluent in order to obtain a concentration of the diluent equal to a respective recipe parameter called target concentration of the diluent based on the production potentiality value of the at least one reactor determined in the first calculation module, the recipe parameters, the laboratory analysis results and the predefined coefficients and said data measured by the measurement equipment.

### Claim 6 (depends on 1)

The method according to claim 1, wherein said plurality of control variables comprises the flow-rate of antioxidant for feeding said first stripper, said method comprising:
determining, by an eighth calculation module of said plurality of calculation modules, the flow-rate of antioxidant in order to obtain a weight percentage fraction of antioxidant equal to a respective recipe parameter called target weight percentage fraction of antioxidant based on the production potentiality value of the at least one reactor determined in the first calculation module, the recipe parameters, the laboratory analysis results and the predefined coefficients and said data measured by the measurement equipment.

### Claim 7 (depends on 1)

The method according to claim 1, wherein said plurality of control variables comprises the flow-rate of pH-adjusting agent for feeding said first stripper, said method comprising:
determining, by a ninth calculation module of said plurality of calculation modules, the flow-rate of pH-adjusting agent in order to obtain a stripping bath with a pH equal to a respective recipe parameter called target pH on the basis of the recipe parameters, the laboratory analysis results and the predefined coefficients and said data measured by the measurement equipment.

### Claim 8 (depends on 1)

The method according to claim 1, wherein said plurality of control variables comprises the flow-rate of said first monomer for feeding said at least one reactor, said method comprising:
determining, by means of a tenth calculation module of said plurality of calculation modules, the flow-rate of said first monomer with which to fed said at least one reactor (11) in order to obtain a molar ratio between the monomers deriving from the type of catalysis used on the basis of the recipe parameters, the laboratory analysis results and the predefined coefficients and said data measured by the measurement equipment.

### Claim 9 (depends on 1)

A system for controlling a plant for the production in continuous of a polymer, wherein said plant comprises a reaction section comprising at least one reactor fed with at least a first monomer and a second monomer, a stripping section comprising a first high-pressure stripper, a second low-pressure stripper, a third low-pressure stripper, a finishing section comprising at least one recycling vat of the fine products, a plurality of measurement equipment of the operational conditions of said plant, said control system comprising:
a plurality of distributed control devices and
at least one electronic processing and control unit suitable for controlling said plurality of distributed control devices and configured for implementing the control method according to claim 1.

### Claim 10 (depends on 9)

A plant for the production in continuous of a polymer comprising:
a reaction section comprising at least one reactor fed with at least a first monomer and a second monomer;
a stripping section comprising a first high-pressure stripper, a second low-pressure stripper, a third low-pressure stripper;
a finishing section comprising at least one recycling vat of the fine products;
a plurality of measurement equipment of the operational conditions of said plant; and
a control system according to claim 9.

### Claim 11 (depends on 1)

A computer program downloadable in the internal memory of a digital computer, comprising portions of code for implementing the control method according to claim 1, when said program is run by said computer.