# US 2019/0166847 A1 · Molecules having pesticidal utility, and intermediates, compositions, and processes related thereto

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- Number: US 2019/0166847 A1
- Document ID: US20190166847A1
- Status: Published application
- Kind: A1
- Application number: 16/251,699
- Filed: 2019-01-18
- Published: 2019-06-06
- Earliest claimed: 2016-10-12
- Assignees: Dow AgroSciences LLC
- Inventors: Ronald J. Heemstra; Ronald Ross, JR.; Timothy P. Martin; Nicolaas Vermeulen; John F. Daeuble, SR.; Joseph D. Eckelbarger; Alex Nolan; Kaitlyn Gray; David A. Demeter; Ricky Hunter; Tony K. Trullinger
- Web page: https://patentgrep.com/patent/US20190166847A1

## CPC

- A01N 53/00: Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
- C07C 237/42: having nitrogen atoms of amino groups bound to the carbon skeleton of the acid part, further acylated
- C07C 237/52: having the nitrogen atom of at least one of the carboxamide groups further acylated
- C07C 243/38: with acylating carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C07C 255/19: containing cyano groups and carboxyl groups, other than cyano groups, bound to the same saturated acyclic carbon skeleton
- C07C 255/46: to carbon atoms of non-condensed rings
- C07C 255/58: containing cyano groups and singly-bound nitrogen atoms, not being further bound to other hetero atoms, bound to the carbon skeleton
- C07C 255/60: at least one of the singly-bound nitrogen atoms being acylated
- C07C 271/18: to carbon atoms of hydrocarbon radicals substituted by doubly-bound oxygen atoms
- C07C 271/22: to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
- C07C 271/28: to a carbon atom of a non-condensed six-membered aromatic ring
- C07C 271/66: Y being a hetero atom
- C07C 281/02: Compounds containing any of the groups [IMAGE cpc-sch-C07C-0972.gif], e.g. carbazates
- C07C 281/06: Compounds containing any of the groups [IMAGE cpc-sch-C07C-0973.gif], e.g. semicarbazides
- C07C 311/09: the carbon skeleton being further substituted by at least two halogen atoms
- C07C 311/10: of a saturated carbon skeleton containing rings
- C07C 311/21: having the nitrogen atom of at least one of the sulfonamide groups bound to a carbon atom of a six-membered aromatic ring
- C07C 311/48: having nitrogen atoms of sulfonamide groups further bound to another hetero atom
- C07C 317/24: having sulfone or sulfoxide groups and doubly-bound oxygen atoms bound to the same carbon skeleton
- C07C 337/06: Compounds containing any of the groups [IMAGE cpc-sch-C07C-0987.gif], e.g. thiosemicarbazides
- C07C 381/00: Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/00 - C07C337/00
- C07D 213/77: Hydrazine radicals
- C07D 213/81: Amides; Imides
- C07D 237/20: Nitrogen atoms (nitro radicals C07D237/12)
- C07D 239/42: One nitrogen atom (nitro radicals C07D239/30)
- C07D 307/68: Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
- C07D 333/38: Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07C 2601/02: with a three-membered ring
- C07C 2601/04: with a four-membered ring
- C07C 2601/08: the ring being saturated
- C07C 2601/16: the ring being unsaturated
- Y02A 50/30: Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07D: HETEROCYCLIC COMPOUNDS (macromolecular compounds C08)
- Y02A: TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE

## Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

## Claims

### Claim 1

A molecule having the following formula
wherein:
(A) R1 is H;
(B) R2 is (C1-C3 )haloalkyl;
(C) R3 is H;
(D) R4 is (C1-C3)haloalkyl;
(E) R5 is H;
(F) R6 is H;
(G) R7 is CI;
(H) R8 is CI;
(I) R9 is H;
(J) Q1 is O;
(K) Q2 is O;
(L) R10 is H;
(M) R11 is H;
(N) R12 is H;
(O) R13 is CI;
(P) R14 is H;
(Q) X3 is:
(1) N(R15a)(R15b) wherein
(a) said R15a is H, and
(b) said R15b is a substituted phenyl, said substituted phenyl has one or more substituents selected from the group consisting of H, F, and N(R15c)C(=O)X4,
(1) said R15c is H,
(2) said X4 is (C1-C6)haloalkyl;
and N-oxides, agriculturally acceptable acid addition salts, salt derivatives, solvates, ester derivatives, crystal polymorphs, isotopes, resolved stereoisomers, tautomers, pro-insecticides, of the molecules of Formula Two.

### Claim 2 (depends on 1)

A molecule according to claim 1 wherein said molecule is the (R,R)-enantiomer of F1802:

### Claim 3 (depends on 1)

A composition comprising a molecule according to claim 1 and a carrier.

### Claim 4 (depends on 2)

A composition comprising a molecule according to claim 2 and a carrier.

### Claim 5 (depends on 3)

A composition according to claim 3 further comprising an active ingredient.

### Claim 6 (depends on 4)

A composition according to claim 4 further comprising an active ingredient.

### Claim 7 (depends on 5)

A composition according to claim 5 wherein said active ingredient is selected from the group consisting of acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(1R)-trans-isomers], deltamethrin, empenthrin [(EZ)-(1R)-isomers], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, permethrin, phenothrin [(1R)-trans-isomer], prallethrin, pyrethrins (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R)-isomers], tralomethrin, and transfluthrin, and methoxychlor.

### Claim 8 (depends on 6)

A composition according to claim 6 wherein said active ingredient is selected from the group consisting of acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(1R)-trans-isomers], deltamethrin, empenthrin [(EZ)-(1R)-isomers], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, permethrin, phenothrin [(1R)-trans-isomer], prallethrin, pyrethrins (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R)-isomers], tralomethrin, and transfluthrin, and methoxychlor.

### Claim 9 (depends on 7)

A composition according to claim 7 wherein said active ingredient is bifenthrin.

### Claim 10 (depends on 8)

A composition according to claim 8 wherein said active ingredient is bifenthrin.

### Claim 11 (depends on 7)

A composition according to claim 7 wherein said active ingredient is lambda-cyhalothrin.

### Claim 12 (depends on 8)

A composition according to claim 8 wherein said active ingredient is lambda-cyhalothrin.

### Claim 13 (depends on 9)

A composition according to claim 9 wherein the weight ratio of said molecule to said active ingredient is 3:1 to 1:3.

### Claim 14 (depends on 10)

A composition according to claim 10 wherein the weight ratio of said molecule to said active ingredient is 3:1 to 1:3.

### Claim 15 (depends on 11)

A composition according to claim 11 wherein the weight ratio of said molecule to said active ingredient is 3:1 to 1:3.

### Claim 16 (depends on 12)

A composition according to claim 12 wherein the weight ratio of said molecule to said active ingredient is 3:1 to 1:3.

### Claim 17 (depends on 7)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 7.

### Claim 18 (depends on 8)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 8.

### Claim 19 (depends on 9)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 9.

### Claim 20 (depends on 10)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 10.

### Claim 21 (depends on 11)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 11.

### Claim 22 (depends on 12)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 12.

### Claim 23 (depends on 17)

A process according to claim 17 wherein said pest is selected from the group consisting of ants, aphids, bed bugs, beetles, bristletails, caterpillars, cockroaches, crickets, earwigs, fleas, flies, grasshoppers, grubs, leafhoppers, lice, locusts, maggots, mites, nematodes, planthoppers, psyllids, sawflies, scales, silverfish, slugs, snails, spiders, springtails, stink bugs, symphylans, termites, thrips, ticks, wasps, whiteflies, and wireworms.

### Claim 24 (depends on 18)

A process according to claim 18 wherein said pest is selected from the group consisting of ants, aphids, bed bugs, beetles, bristletails, caterpillars, cockroaches, crickets, earwigs, fleas, flies, grasshoppers, grubs, leafhoppers, lice, locusts, maggots, mites, nematodes, planthoppers, psyllids, sawflies, scales, silverfish, slugs, snails, spiders, springtails, stink bugs, symphylans, termites, thrips, ticks, wasps, whiteflies, and wireworms.

### Claim 25 (depends on 23)

A process according to claim 23 wherein said pest are thrips.

### Claim 26 (depends on 24)

A process according to claim 24 wherein said pest are thrips.

### Claim 27 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Coleoptera.

### Claim 28 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Cerotoma spp., Colaspis spp., Curculio spp., Diabrotica spp., and Meligethes spp.

### Claim 29 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Cerotoma trifurcata, Conoderus scalaris, Conoderus stigmosus, Epilachna varivestis, and Leptinotarsa decemlineata.

### Claim 30 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Diptera.

### Claim 31 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Bactrocera spp., Ceratitis spp., Contarinia spp., Culex spp., Delia spp., Drosophila spp., Liriomyza spp., and Musca spp.

### Claim 32 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Agromyza frontella, Anastrepha suspensa, Anastrepha ludens, Anastrepha obliqua, Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera invadens, Bactrocera zonata, Ceratitis capitata, Delia platura, Liriomyza brassicae, Liriomyza sativa, Musca autumnalis, Musca domestica, Psila rosae, Rhagoletis cerasi, Rhagoletis pomonella, and Rhagoletis mendax.

### Claim 33 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Hemiptera.

### Claim 34 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Aphis spp., Bemisia spp., Coccus spp., Empoasca spp., Euschistus spp., Lygus spp., Macrosiphum spp., Nephotettix spp., Nezara spp., Nilaparvata spp., Piezodorus spp., Planococcus spp., Pseudococcus spp., Rhopalosiphum spp., Saissetia spp., Toxoptera spp., Trialeurodes spp., Triatoma spp., and Unaspis spp.

### Claim 35 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Acyrthosiphon pisum, Aleyrodes proletella, Aleurodicus dispersus, Aonidiella aurantii, Aphis fabae, Aphis gossypii, Aphis glycines, Aphis pomi, Bactericera cockerelli, Bagrada hilaris, Bemisia argentifolii, Bemisia tabaci, Blissus leucopterus, Brevicoryne brassicae, Cacopsylla pyri, Cacopsylla pyricola, Cimex hemipterus, Cimex lectularius, Coccus pseudomagnoliarum, Dichelops furcatus, Diaphorina citri, Dysaphis plantaginea, Dysdercus suturellus, Edessa meditabunda, Empoasca vitis, Eriosoma lanigerum, Erythroneura elegantula, Eurygaster maura, Euschistus conspersus, Euschistus heros, Euschistus servus, Halyomorpha halys, Jacobiasca formosana, Lygus hesperus, Macrosiphum euphorbiae, Macrosiphum granarium, Macrosiphum rosae, Mahanarva frimbiolata, Myzus persicae, Nasonovia ribisnigri, Nephotettix cincticeps, Nezara viridula, Nilaparvata lugens, Paratrioza cockerelli, Piezodorus guildinii, Planococcus citri, Planococcus ficus, Pseudococcus brevipes, Quadraspidiotus perniciosus, Rhopalosiphum maidis, Rhopalosiphum padi, Schizaphis graminum, Sitobion avenae, Sogatella furcifera, Trialeurodes vaporariorum, Trialeurodes abutiloneus, and Unaspis yanonensis.

### Claim 36 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Hymenoptera.

### Claim 37 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Atta spp., Formica spp., Polistes spp., Solenopsis spp., Vespula spp., and Vespa spp.

### Claim 38 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Atta texana, Solenopsis invicta, Solenopsis geminata, Solenopsis molesta, Solenopsis richtery, and Solenopsis xyloni.

### Claim 39 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Isoptera.

### Claim 40 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is Reticulitermes spp.

### Claim 41 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Reticulitermes banyulensis, Reticulitermes grassei, Reticulitermes flavipes, Reticulitermes hageni, Reticulitermes hesperus, Reticulitermes santonensis, Reticulitermes speratus, Reticulitermes tibialis, and Reticulitermes virginicus.

### Claim 42 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Lepidoptera.

### Claim 43 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Adoxophyes spp., Agrotis spp., Argyrotaenia spp., Cacoecia spp., Caloptilia spp., Chilo spp., Chrysodeixis spp., Colias spp., Crambus spp., Diaphania spp., Diatraea spp., Earias spp., Ephestia spp., Epimecis spp., Feltia spp., Gortyna spp., Helicoverpa spp., Heliothis spp., Indarbela spp., Lithocolletis spp., Loxagrotis spp., Malacosoma spp., Nemapogon spp., Peridroma spp., Phyllonorycter spp., Pseudaletia spp., Plutella spp., Sesamia spp., Spodoptera spp., Synanthedon spp., and Yponomeuta spp.

### Claim 44 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Achaea janata, Adoxophyes orana, Agrotis ipsilon, Alabama argillacea, Amorbia cuneana, Amyelois transitella, Anacamptodes defectaria, Anarsia lineatella, Anomis sabulifera, Anticarsia gemmatalis, Archips argyrospila, Archips rosana, Argyrotaenia citrana, Autographa gamma, Bonagota cranaodes, Borbo cinnara, Bucculatrix thurberiella, Capua reticulana, Carposina niponensis, Chlumetia trans versa, Choristoneura rosaceana, Cnaphalocrocis medinalis, Conopomorpha cramerella, Corcyra cephalonica, Cossus cossus, Cydia caryana, Cydia funebrana, Cydia molesta, Cydia nigricana, Cydia pomonella, Darna diducta, Diaphania nitidalis, Diatraea saccharalis, Diatraea grandiosella, Earias insulana, Earias vittella, Ecdytolopha aurantianum, Elasmopalpus lignosellus, Ephestia cautella, Ephestia elutella, Ephestia kuehniella, Epinotia aporema, Epiphyas postvittana, Erionota thrax, Estigmene acrea, Eupoecilia ambiguella, Euxoa auxiliaris, Galleria mellonella, Grapholita molesta, Hedylepta indicata, Helicoverpa armigera, Helicoverpa zea, Heliothis virescens, Hellula undalis, Keiferia lycopersicella, Leucinodes orbonalis, Leucoptera coffeella, Leucoptera malifoliella, Lobesia botrana, Loxagrotis albicosta, Lymantria dispar, Lyonetia clerkella, Mahasena corbetti, Mamestra brassicae, Manduca sexta, Maruca testulalis, Metisa plana, Mythimna unipuncta, Neoleucinodes elegantalis, Nymphula depunctalis, Operophtera brumata, Ostrinia nubilalis, Oxydia vesulia, Pandemis cerasana, Pandemis heparana, Papilio demodocus, Pectinophora gossypiella, Peridroma saucia, Perileucoptera coffeella, Phthorimaea operculella, Phyllocnistis citrella, Phyllonorycter blancardella, Pieris rapae, Plathypena scabra, Platynota idaeusalis, Plodia interpunctella, Plutella xylostella, Polychrosis viteana, Prays endocarpa, Prays oleae, Pseudaletia unipuncta, Pseudoplusia includens, Rachiplusia nu, Scirpophaga incertulas, Sesamia inferens, Sesamia nonagrioides, Setora nitens, Sitotroga cerealella, Sparganothis pilleriana, Spodoptera exigua, Spodoptera frugiperda, Spodoptera eridania, Thecla basilides, Tinea pellionella, Tineola bisselliella, Trichoplusia ni, Tuta absoluta, Zeuzera coffeae, and Zeuzea pyrina.

### Claim 45 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Mallophaga.

### Claim 46 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Gryllotalpa africana, Gryllotalpa australis, Gryllotalpa brachyptera, Gryllotalpa hexadactyla, and Locusta migratoria.

### Claim 47 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Siphonaptera.

### Claim 48 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Thysanoptera.

### Claim 49 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Caliothrips spp., Frankliniella spp., Scirtothrips spp., and Thrips spp.

### Claim 50 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Caliothrips phaseoli, Frankliniella bispinosa, Frankliniella fusca, Frankliniella occidentalis, Frankliniella schultzei, Frankliniella tritici, Frankliniella williamsi, Heliothrips haemorrhoidalis, Rhipiphorothrips cruentatus, Scirtothrips citri, Scirtothrips dorsalis, Taeniothrips rhopalantennalis, Thrips hawaiiensis, Thrips nigropilosus, Thrips orientalis, Thrips palmi, and Thrips tabaci.

### Claim 51 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is Lepisma spp.

### Claim 52 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Order Acarina.

### Claim 53 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Acarus spp., Aculops spp., Argus spp., Boophilus spp., Demodex spp., Dermacentor spp., Epitrimerus spp., Eriophyes spp., Ixodes spp., Oligonychus spp., Panonychus spp., Rhizoglyphus spp., and Tetranychus spp.

### Claim 54 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Acarapis woodi, Acarus siro, Aceria mangiferae, Aculops lycopersici, Aculus pelekassi, Aculus schlechtendali, Amblyomma americanum, Brevipalpus obovatus, Brevipalpus phoenicis, Dermacentor variabilis, Dermatophagoides pteronyssinus, Eotetranychus carpini, Liponyssoides sanguineus, Notoedres cati, Oligonychus coffeae, Oligonychus ilicis, Ornithonyssus bacoti, Panonychus citri, Panonychus ulmi, Phyllocoptruta oleivora, Polyphagotarsonemus latus, Rhipicephalus sanguineus, Sarcoptes scabiei, Tegolophus perseaflorae, Tetranychus urticae, Tyrophagus longior, and Varroa destructor.

### Claim 55 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Class Symphyla.

### Claim 56 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Phylum Nematoda.

### Claim 57 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Aphelenchoides spp., Belonolaimus spp., Criconemella spp., Ditylenchus spp., Globodera spp., Heterodera spp., Hirschmanniella spp., Hoplolaimus spp., Meloidogyne spp., Pratylenchus spp., and Radopholus spp.

### Claim 58 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is selected from the group consisting of Dirofilaria immitis, Globodera pallida, Heterodera glycines, Heterodera zeae, Meloidogyne incognita, Meloidogyne javanica, Onchocerca volvulus, Pratylenchus penetrans, Radopholus similis, and Rotylenchulus reniformis.

### Claim 59 (depends on 4)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 4, wherein said pest is from the Phylum Mollusca.

### Claim 60 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Coleoptera.

### Claim 61 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Cerotoma spp., Colaspis spp., Curculio spp., Diabrotica spp., and Meligethes spp.

### Claim 62 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Cerotoma trifurcata, Conoderus scalaris, Conoderus stigmosus, Epilachna varivestis, and Leptinotarsa decemlineata.

### Claim 63 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Diptera.

### Claim 64 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Bactrocera spp., Ceratitis spp., Contarinia spp., Culex spp., Delia spp., Drosophila spp., Liriomyza spp., and Musca spp.

### Claim 65 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Agromyza frontella, Anastrepha suspensa, Anastrepha ludens, Anastrepha obliqua, Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera invadens, Bactrocera zonata, Ceratitis capitata, Delia platura, Liriomyza brassicae, Liriomyza sativa, Musca autumnalis, Musca domestica, Psila rosae, Rhagoletis cerasi, Rhagoletis pomonella, and Rhagoletis mendax.

### Claim 66 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Hemiptera.

### Claim 67 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Aphis spp., Bemisia spp., Coccus spp., Empoasca spp., Euschistus spp., Lygus spp., Macrosiphum spp., Nephotettix spp., Nezara spp., Nilaparvata spp., Piezodorus spp., Planococcus spp., Pseudococcus spp., Rhopalosiphum spp., Saissetia spp., Toxoptera spp., Trialeurodes spp., Triatoma spp., and Unaspis spp.

### Claim 68 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Acyrthosiphon pisum, Aleyrodes proletella, Aleurodicus dispersus, Aonidiella aurantii, Aphis fabae, Aphis gossypii, Aphis glycines, Aphis pomi, Bactericera cockerelli, Bagrada hilaris, Bemisia argentifolii, Bemisia tabaci, Blissus leucopterus, Brevicoryne brassicae, Cacopsylla pyri, Cacopsylla pyricola, Cimex hemipterus, Cimex lectularius, Coccus pseudomagnoliarum, Dichelops furcatus, Diaphorina citri, Dysaphis plantaginea, Dysdercus suturellus, Edessa meditabunda, Empoasca vitis, Eriosoma lanigerum, Erythroneura elegantula, Eurygaster maura, Euschistus conspersus, Euschistus heros, Euschistus servus, Halyomorpha halys, Jacobiasca formosana, Lygus hesperus, Macrosiphum euphorbiae, Macrosiphum granarium, Macrosiphum rosae, Mahanarva frimbiolata, Myzus persicae, Nasonovia ribisnigri, Nephotettix cincticeps, Nezara viridula, Nilaparvata lugens, Paratrioza cockerelli, Piezodorus guildinii, Planococcus citri, Planococcus ficus, Pseudococcus brevipes, Quadraspidiotus perniciosus, Rhopalosiphum maidis, Rhopalosiphum padi, Schizaphis graminum, Sitobion avenae, Sogatella furcifera, Trialeurodes vaporariorum, Trialeurodes abutiloneus, and Unaspis yanonensis.

### Claim 69 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Hymenoptera.

### Claim 70 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Atta spp., Formica spp., Polistes spp., Solenopsis spp., Vespula spp., and Vespa spp.

### Claim 71 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Atta texana, Solenopsis invicta, Solenopsis geminata, Solenopsis molesta, Solenopsis richtery, and Solenopsis xyloni.

### Claim 72 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Isoptera.

### Claim 73 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is Reticulitermes spp.

### Claim 74 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Reticulitermes banyulensis, Reticulitermes grassei, Reticulitermes flavipes, Reticulitermes hageni, Reticulitermes hesperus, Reticulitermes santonensis, Reticulitermes speratus, Reticulitermes tibialis, and Reticulitermes virginicus.

### Claim 75 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Lepidoptera.

### Claim 76 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Adoxophyes spp., Agrotis spp., Argyrotaenia spp., Cacoecia spp., Caloptilia spp., Chilo spp., Chrysodeixis spp., Colias spp., Crambus spp., Diaphania spp., Diatraea spp., Earias spp., Ephestia spp., Epimecis spp., Feltia spp., Gortyna spp., Helicoverpa spp., Heliothis spp., Indarbela spp., Lithocolletis spp., Loxagrotis spp., Malacosoma spp., Nemapogon spp., Peridroma spp., Phyllonorycter spp., Pseudaletia spp., Plutella spp., Sesamia spp., Spodoptera spp., Synanthedon spp., and Yponomeuta spp.

### Claim 77 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Achaea janata, Adoxophyes orana, Agrotis ipsilon, Alabama argillacea, Amorbia cuneana, Amyelois transitella, Anacamptodes defectaria, Anarsia lineatella, Anomis sabulifera, Anticarsia gemmatalis, Archips argyrospila, Archips rosana, Argyrotaenia citrana, Autographa gamma, Bonagota cranaodes, Borbo cinnara, Bucculatrix thurberiella, Capua reticulana, Carposina niponensis, Chlumetia transversa, Choristoneura rosaceana, Cnaphalocrocis medinalis, Conopomorpha cramerella, Corcyra cephalonica, Cossus cossus, Cydia caryana, Cydia funebrana, Cydia molesta, Cydia nigricana, Cydia pomonella, Darna diducta, Diaphania nitidalis, Diatraea saccharalis, Diatraea grandiosella, Earias insulana, Earias vittella, Ecdytolopha aurantianum, Elasmopalpus lignosellus, Ephestia cautella, Ephestia elutella, Ephestia kuehniella, Epinotia aporema, Epiphyas postvittana, Erionota thrax, Estigmene acrea, Eupoecilia ambiguella, Euxoa auxiliaris, Galleria mellonella, Grapholita molesta, Hedylepta indicata, Helicoverpa armigera, Helicoverpa zea, Heliothis virescens, Hellula undalis, Keiferia lycopersicella, Leucinodes orbonalis, Leucoptera coffeella, Leucoptera malifoliella, Lobesia botrana, Loxagrotis albicosta, Lymantria dispar, Lyonetia clerkella, Mahasena corbetti, Mamestra brassicae, Manduca sexta, Maruca testulalis, Metisa plana, Mythimna unipuncta, Neoleucinodes elegantalis, Nymphula depunctalis, Operophtera brumata, Ostrinia nubilalis, Oxydia vesulia, Pandemis cerasana, Pandemis heparana, Papilio demodocus, Pectinophora gossypiella, Peridroma saucia, Perileucoptera coffeella, Phthorimaea operculella, Phyllocnistis citrella, Phyllonorycter blancardella, Pieris rapae, Plathypena scabra, Platynota idaeusalis, Plodia interpunctella, Plutella xylostella, Polychrosis viteana, Prays endocarpa, Prays oleae, Pseudaletia unipuncta, Pseudoplusia includens, Rachiplusia nu, Scirpophaga incertulas, Sesamia inferens, Sesamia nonagrioides, Setora nitens, Sitotroga cerealella, Sparganothis pilleriana, Spodoptera exigua, Spodoptera frugiperda, Spodoptera eridania, Thecla basilides, Tinea pellionella, Tineola bisselliella, Trichoplusia ni, Tuta absoluta, Zeuzera coffeae, and Zeuzea pyrina.

### Claim 78 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Mallophaga.

### Claim 79 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Gryllotalpa africana, Gryllotalpa australis, Gryllotalpa brachyptera, Gryllotalpa hexadactyla, and Locusta migratoria.

### Claim 80 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Siphonaptera.

### Claim 81 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Thysanoptera.

### Claim 82 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Caliothrips spp., Frankliniella spp., Scirtothrips spp., and Thrips spp.

### Claim 83 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Caliothrips phaseoli, Frankliniella bispinosa, Frankliniella fusca, Frankliniella occidentalis, Frankliniella schultzei, Frankliniella tritici, Frankliniella williamsi, Heliothrips haemorrhoidalis, Rhipiphorothrips cruentatus, Scirtothrips citri, Scirtothrips dorsalis, Taeniothrips rhopalantennalis, Thrips hawaiiensis, Thrips nigropilosus, Thrips orientalis, Thrips palmi, and Thrips tabaci.

### Claim 84 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is Lepisma spp.

### Claim 85 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Order Acarina.

### Claim 86 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Acarus spp., Aculops spp., Argus spp., Boophilus spp., Demodex spp., Dermacentor spp., Epitrimerus spp., Eriophyes spp., Ixodes spp., Oligonychus spp., Panonychus spp., Rhizoglyphus spp., and Tetranychus spp.

### Claim 87 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Acarapis woodi, Acarus siro, Aceria mangiferae, Aculops lycopersici, Aculus pelekassi, Aculus schlechtendali, Amblyomma americanum, Brevipalpus obovatus, Brevipalpus phoenicis, Dermacentor variabilis, Dermatophagoides pteronyssinus, Eotetranychus carpini, Liponyssoides sanguineus, Notoedres cati, Oligonychus coffeae, Oligonychus ilicis, Ornithonyssus bacoti, Panonychus citri, Panonychus ulmi, Phyllocoptruta oleivora, Polyphagotarsonemus latus, Rhipicephalus sanguineus, Sarcoptes scabiei, Tegolophus perseaflorae, Tetranychus urticae, Tyrophagus longior, and Varroa destructor.

### Claim 88 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Class Symphyla.

### Claim 89 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Phylum Nematoda.

### Claim 90 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Aphelenchoides spp., Belonolaimus spp., Criconemella spp., Ditylenchus spp., Globodera spp., Heterodera spp., Hirschmanniella spp., Hoplolaimus spp., Meloidogyne spp., Pratylenchus spp., and Radopholus spp.

### Claim 91 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is selected from the group consisting of Dirofilaria immitis, Globodera pallida, Heterodera glycines, Heterodera zeae, Meloidogyne incognita, Meloidogyne javanica, Onchocerca volvulus, Pratylenchus penetrans, Radopholus similis, and Rotylenchulus reniformis.

### Claim 92 (depends on 6)

A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a composition according to claim 6, wherein said active ingredient is selected from the group consisting of bifenthrin and lambda-cyhalothrin, wherein the weight ratio of said molecule in said composition to said active ingredient is 3:1 to 1:3, and wherein said pest is from the Phylum Mollusca.
