Glasses with low excess modifier content
AssigneeCorning Incorporated
InventorsTimothy Michael Gross, Xiaoju Guo, Peter Joseph Lezzi, Alexandra Lai Ching Kao Andrews Mitchell, Rostislav Vatchev Roussev
Life of this patent
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Abstract
A glass composition includes: from 55.0 mol % to 70.0 mol % SiO2; from 12.0 mol % to 20.0 mol % Al2O3; from 5.0 mol % to 15.0 mol % Li2O; and from 4.0 mol % to 15.0 mol % Na2O. The glass composition has the following relationships −8.00 mol %≤R2O+RO−Al2O3−B2O3−P2O5≤−1.75 mol %, 9.00≤(SiO2+Al2O3+Li2O)/Na2O, and (Li2O+Al2O3+P2O5)/(Na2O+B2O3)≤3.50. The glass composition may be used in a glass article or a consumer electronic product.
Claims27
A glass composition comprising:
- from greater than or equal to 55.0 mol % to less than or equal to 70.0 mol % SiO2;
- from greater than or equal to 12.0 mol % to less than or equal to 20.0 mol % Al2O3;
- from greater than or equal to 5.0 mol % to less than or equal to 15.0 mol % Li2O;
- and
- from greater than or equal to 4.0 mol % to less than or equal to 15.0 mol % Na2O,
- wherein:
- −8.00 mol %≤R2O+RO−Al2O3−B2O3−P2O5≤−1.75 mol %,
- 9.10≤(SiO2+Al2O3+Li2O)/Na2O, and
- (Li2O+Al2O3+P2O5)/(Na2O+B2O3)≤3.50.
A glass article comprising:
- a first surface;
- a second surface opposite the first surface, wherein a thickness (t) of the glass article is measured as a distance between the first surface and the second surface;
- and
- a compressive stress layer extending from at least one of the first surface and the second surface into the thickness (t) of the glass article, wherein
- a central tension of the glass article is greater than or equal to 60 MPa,
- the compressive stress layer has a depth of compression that is from greater than or equal to 0.15t to less than or equal to 0.25t, and
- the glass article is formed from a glass comprising:
- from greater than or equal to 55.0 mol % to less than or equal to 70.0 mol % SiO2;
- from greater than or equal to 12.0 mol % to less than or equal to 20.0 mol % Al2O3;
- from greater than or equal to 5.0 mol % to less than or equal to 15.0 mol % Li2O;
- and
- from greater than or equal to 4.0 mol % to less than or equal to 15.0 mol % Na2O,
- wherein:
- −8.00 mol %≤R2O+RO−Al2O3−B2O3−P2O5≤−1.75 mol %,
- 9.00≤(SiO2+Al2O3+Li2O)/Na2O, and
- (Li2O+Al2O3+P2O5)/(Na2O+B2O3)≤3.50.
A glass article comprising:
- a first surface;
- a second surface opposite the first surface, wherein a thickness (t) of the glass article is measured as a distance between the first surface and the second surface;
- and
- a compressive stress layer extending from at least one of the first surface and the second surface into the thickness (t) of the glass article, wherein
- a central tension of the glass article is greater than or equal to 60 MPa,
- the compressive stress layer has a depth of compression that is from greater than or equal to 0.15t to less than or equal to 0.25t, and
- the glass article has a composition at a center depth of the glass article comprising:
- from greater than or equal to 55.0 mol % to less than or equal to 70.0 mol % SiO2;
- from greater than or equal to 12.0 mol % to less than or equal to 20.0 mol % Al2O3;
- from greater than or equal to 5.0 mol % to less than or equal to 15.0 mol % Li2O;
- and
- from greater than or equal to 4.0 mol % to less than or equal to 15.0 mol % Na2O,
- wherein:
- −8.00 mol %≤R2O+RO−Al2O3−B2O3−P2O5≤−1.75 mol %,
- 9.00≤(SiO2+Al2O3+Li2O)/Na2O, and
- (Li2O+Al2O3+P2O5)/(Na2O+B2O3)≤3.50.
A glass composition comprising:
- from greater than or equal to 60.0 mol % to less than or equal to 70.0 mol % SiO2;
- from greater than or equal to 12.0 mol % to less than or equal to 18.0 mol % Al2O3;
- from greater than or equal to 5.0 mol % to less than or equal to 10.0 mol % Li2O;
- from greater than or equal to 4.0 mol % to less than or equal to 10.0 mol % Na2O;
- and
- greater than or equal to 0.75 mol % P2O5,
- wherein:
- Li2O/Na2O greater than or equal to 1.00, and
- Al2O3+Li2O less than or equal to 25.25 mol %.
Dependencies are inferred from the claim text.