Polyurethane foams comprising a mixture obtained in the production of tolylene diisocyanate (tdi) as bottoms residue
AssigneeCovestro Deutschland AG
InventorsSven MEYER-AHRENS, Tim LODDENKEMPER, Chenxi ZHANG, Liqiang LI
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Abstract
The present invention relates to a process for producing polyurethane foams, preferably moulded flexible polyurethane foams, by reacting an isocyanate component which is a mixture obtained in the production of tolylene diisocyanate as a bottoms residue, and at least one further isocyanate component with a component reactive toward isocyanates. The invention further relates to polyurethane foams produced by the process according to the invention and to the use thereof.
Claims14
A process for producing polyurethane foams by reacting a component A comprising
- A1 at least one polyether polyol having a functionality of 2 to 8, a polyoxyethylene (EO) content of 0% to 30% by weight, and an OH number according to DIN 53240 of ≥10 mg KOH/g to ≤112 mg KOH/g,
- A2 optionally,. at least one polyether polyol having a functionality of 2 to 8, a polyoxyethylene (EO) content of >60% by weight, and an OH number according to DIN 53240 of ≥10 mg KOH/g to ≤112 mg KOH/g,
- A3 optionally, at least one dispersion of a polymer in a polyether polyol, where the OH number according to DIN 53240 of the dispersion is within a range from 10 to 60 mg KOH/g and wherein the polyether polyol has a hydroxyl functionality of 2 to 6, a polyoxypropylene (PO) content in an amount of 70% to 90% by weight and an EO content in an amount of 10% to 30% by weight;
- A4 water and/or physical blowing agents,
- A5 optionally, compounds having hydrogen atoms that are reactive toward isocyanates, having an OH number of 140 mg KOH/g to 900 mg KOH/g,
- A6 optionally, auxiliaries and additives, preferably at least one component selected from catalysts, surface-active additions, additives, pigments or flame retardants or a combination thereof;
- and a component B comprising
- B1 the distillation product of at least one bottoms residue which is obtained in tolylene diisocyanate (TDI) production, in the last distillation step,
- B2 further di- and/or polyisocyanates,
- wherein the reaction of component A with component B is conducted at an isocyanate index of 75 to 120, and wherein all parts by weight figures for components A1 to A6 are normalized such that the sum total of parts by weight A1+A2+A3 in the composition adds up to 100 parts by weight.
The process according to claim1, wherein 0.05 to 10 parts by weight of A6 are present, based on 100 parts by weight of the sum total of A1 to A3.
The process according to claim1, wherein A6 comprises one or more catalysts, surface-active additions, additives, pigments, antioxidants, flame retardants or a combination thereof.
Dependencies are inferred from the claim text.