Cross-linkable masses based on organosilicon compounds
AssigneeWacker Chemie AG
InventorsUwe SCHEIM, Hartmut ACKERMANN, Volker STANJEK
Life of this patent
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Abstract
The invention relates to cross-linkable compositions comprising (A) organosiloxanes consisting of units RcSiO4-c/2 (I) and R5(OR4)mSiO3-m/2 (II), (B) silanes R5Si(OR4)3 (II) and/or partial hydrolysates thereof in amounts of 5 to 20 parts by weight, based on 100 parts by weight of component (A), (C) organosiloxanes consisting of units R6a(R7O)bSiO(4-a-b)/2 (IV) in amounts of 1 to 30 parts by weight, (D) organosilicon compounds comprising units of the formula DfSi(OR9)eR8dO(4-d-e-f)/2 (V), in amounts of 0.1 to 2 parts by weight. The compositions are particularly useful as anti-graffiti coating.
Claims13
-10. (canceled)
A cross-linkable composition comprising
- (A) one or more organosiloxanes consisting of units of the formulae
- RcSiO4-c/2 (I)
- and
- R5(OR4)mSiO3-m/2 (II),
- where
- R are the same or different monovalent, optionally substituted hydrocarbon radicals,
- R4 are the same or different and are monovalent, optionally substituted hydrocarbon radicals,
- R5 is a group —CH2—NR2R3,
- R2 are hydrogen or monovalent, optionally substituted linear or branched hydrocarbon radicals having 1 to 6 carbon atoms,
- R3 are monovalent, optionally substituted linear or branched hydrocarbon radicals having 1 to 6 carbon atoms or a cyclic saturated hydrocarbon radical having 5 or 6 carbon atoms or a phenyl radical,
- c is 1 or 2 and
- m is 0, 1 or 2,
- with the proviso that at least two R5 radicals and at least four (OR4) groups are present per molecule,
- (B) silanes of the formula
- R5Si(OR4)3 (III)
- and/or partial hydrolysates thereof, and component (B) is present in amounts of 5 to 20 parts by weight, based on 100 parts by weight of component(A),
- (C) organosiloxanes consisting of units of the formula
- R6a(R7O)bSiO(4-a-b)/2 (IV),
- where
- R6 are the same or different and are monovalent, SiC-bonded hydrocarbon radicals optionally substituted by one or more halogen atoms, or an Si-bonded halogen atom,
- R7 are the same or different and are monovalent, optionally substituted hydrocarbon radicals,
- a is 0 or 1 and
- b is 0, 1, 2 or 3,
- with the proviso that, in formula (IV), the sum of a+b is <4, the organosiloxane has 2 to 30 units of the formula (IV) and at least one unit is present per molecule where b is other than 0,
- and component C is present in amounts of 1 to 30 parts by weight, based on 100 parts by weight of component (A),
- (D) organosilicon compounds comprising units of the formula
- DfSi(OR9)eR8dO(4-d-e-f)/2 (V),
- where
- R8 are the same or different and are monovalent, optionally substituted SiC-bonded organic radicals free of nitrogen,
- R9 are the same or different and are hydrogen or optionally substituted hydrocarbon radicals,
- D are the same or different and are monovalent, SiC-bonded radicals having at least one nitrogen atom that is not bonded to a carbonyl group (C═O),
- d is 0 or 1,
- e is 0, 1, 2 or 3, and
- f is 0 or 1,
- with the proviso that the sum of d+e+f is less than or equal to 4, at least one radical D is present per molecule and at least one radical D bears an NH2 group per molecule, and component (D) is present in amounts of 0.1 to 2 parts by weight, based on 100 parts by weight of component (A).
Dependencies are inferred from the claim text.