Solid electrolyte for reram
AssigneeHeraeus Deutschland GmbH & Co. KG
InventorChristian NEUMANN
Life of this patent
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Abstract
A composition comprising (i) a matrix comprising a metal oxide, metal sulphide and/or metal selenide as the matrix material, the metal oxide, metal sulphide and/or metal selenide comprising at least two metals M1 and M2, and (ii) a metal M3 which is mobile in the matrix. The atomic ratio of M1 to M2 is within the range of 75:25 to 99.99:0.01; the valence states of M1, M2 and M3 are all positive; the valence state of M1 is larger than the valence state of M2; the valence state of M2 is equal to or larger than the valence state of M3; and the metals M1, M2 and M3 are different.
Claims20
A composition comprising:
- a matrix comprising one or more of a metal oxide, metal sulphide or metal selenide as the matrix material, the metal oxide, metal sulphide and metal selenide comprising at least two metals M1 and M2, and
- a metal M3 which is mobile in the matrix,
- wherein
- the atomic ratio of M1 to M2 is within the range of 75:25 to 99.99:0.01;
- the valence states of M1, M2 and M3 are all positive;
- the valence state of M1 is larger than the valence state of M2;
- the valence state of M2 is equal to or larger than the valence state of M3;
- and
- the metals M1, M2 and M3 are different.
A composition comprising:
- a matrix comprising one or more of a metal oxide, metal sulphide or metal selenide as the matrix material, the metal oxide, metal sulphide or metal selenide comprising at least two metals M1 and M2, and a metal M3 which is mobile in the matrix,
- wherein
- the atomic ratio of M1 to M2 is within the range of 75:25 to 99.99:0.01;
- the valence states of M1, M2 and M3 are all positive;
- the valence state of M1 is +III, +IV or +V and is larger than the valence state of M2;
- the valence state of M2 is equal to or larger than the valence state of M3;
- the metals M1, M2 and M3 are different, with M1 being selected from Si, Hf, Ta, Zr, Ti, Al, W or Ge, M2 being selected from the group consisting of B, Al, Ga, In, Tl, Sc, Y, La, Ac or mixtures thereof, and M3 being selected from the group consisting of Ag or Cu;
- the ratio of the diffusion coefficient of M3 in the composition to the diffusion coefficient of M2 in the composition is at least 1000:1;
- the total concentration of alkaline metals and alkaline-earth metals is below 100 ppm, based on the total weight of the composition;
- the amount of M2 is 0.01 to 25 atom % based on the entirety of metals present in the composition;
- and
- the amount of M3 is 0.01 to 10 atom % based on the entirety of metals present in the composition.
A composition comprising:
- a matrix comprising one or more of a metal oxide, metal sulphide or metal selenide as the matrix material, the metal oxide, metal sulphide or metal selenide comprising at least two metals M1 and M2, and a metal M3 which is mobile in the matrix,
- wherein
- the atomic ratio of M1 to M2 is within the range of 90:10 to 99.99:0.01;
- the valence states of M1, M2 and M3 are all positive;
- the valence state of M1 is +III, +IV or +V and is larger than the valence state of M2;
- the valence state of M2 is equal to or larger than the valence state of M3;
- the metals M1, M2 and M3 are different, with M1 being selected from Si or Ta, M2 being selected from the group consisting of Al or Ga, and M3 is Cu;
- the ratio of the diffusion coefficient of M3 in the composition to the diffusion coefficient of M2 in the composition is at least 1000:1;
- the total concentration of alkaline metals and alkaline-earth metals is below 100 ppm, based on the total weight of the composition;
- the amount of M2 is 0.01 to 25 atom % based on the entirety of metals present in the composition;
- and
- the amount of M3 is 0.01 to 10 atom % based on the entirety of metals present in the composition.
Dependencies are inferred from the claim text.