# US 2019/0040318 A1 · Lyotropic liquid crystal polymer and small molecule solutions and films

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- Number: US 2019/0040318 A1
- Document ID: US20190040318A1
- Status: Published application
- Kind: A1
- Application number: 16/050,371
- Filed: 2018-07-31
- Published: 2019-02-07
- Earliest claimed: 2017-08-02
- Assignees: Light Polymers Holding
- Applicants: Light Polymers Holding
- Inventors: Valeriy Kuzmin; Evgeny Morozov
- Web page: https://patentgrep.com/patent/US20190040318A1

## CPC

- C09K 19/066: {containing one heterocyclic ring having oxygen as heteroatom}
- C09K 19/322: {Compounds containing a naphthalene ring or a completely or partially hydrogenated naphthalene ring}
- C09K 19/54: Additives having no specific mesophase {characterised by their chemical composition}
- G02B 5/3016: {involving passive liquid crystal elements (optical properties of liquid crystals G02F1/0063; polarising elements associated with active liquid crystal devices G02F1/133528)}
- G02B 5/3025: {Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state (G02B5/3008, G02B5/3016 take precedence)}
- G02B 5/3083: {Birefringent or phase retarding elements (G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001)}
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS

## Abstract

A composition includes an aqueous mixture of birefringent small molecules and a birefringent polymer. The birefringent small molecules are of a structure: or a salt thereof. The birefringent polymer is of a structure: or salt thereof, where n is an integer in a range from 25 to 10,000.

## Claims

### Claim 1

A composition comprising:
an aqueous mixture comprising birefringent small molecules and a birefringent polymer, wherein the birefringent small molecules are of a structure:
or a salt thereof.

### Claim 2 (depends on 1)

The composition according to claim 1, wherein the birefringent polymer is of a structure:
or a salt thereof,
wherein n is an integer in a range from 25 to 10,000.

### Claim 3 (depends on 2)

The composition according to claim 2, wherein the birefringent polymer is present in the composition in a range from 50 to 90 wt. % dry solids.

### Claim 4 (depends on 3)

The composition according to claim 3, wherein the birefringent polymer is present in the composition in a range from 60 to 80 wt. % dry solids.

### Claim 5 (depends on 1)

The composition according to claim 1, wherein the birefringent small molecules are present in the composition in a range from 50 to 10 wt. % dry solids.

### Claim 6 (depends on 5)

The composition according to claim 5, wherein the birefringent small molecules are present in the composition in a range from 40 to 20 wt. % dry solids.

### Claim 7 (depends on 2)

The composition according to claim 2, wherein the birefringent small molecules are present in the composition in a range from 30 to 25 wt. % dry solids, and the birefringent polymer is present in the composition in a range from 70 to 75 wt. % dry solids.

### Claim 8 (depends on 2)

The composition according to claim 2, wherein the birefringent small molecules are present in the composition in a range from 35 to 30 wt. % dry solids, and the birefringent polymer is present in the composition in a range from 65 to 70 wt. % dry solids.

### Claim 9

A composition comprising:
an aqueous mixture comprising birefringent small molecules and a birefringent polymer, wherein the birefringent small molecules are of a structure:
or a salt thereof; and
the birefringent polymer is of a structure:
or salt thereof,
wherein n is an integer in a range from 25 to 10,000; and the birefringent polymer is present in the composition in a range from 50 to 90 wt. % dry solids, and the birefringent small molecules are present in the composition in a range from 50 to 10 wt. % dry solids.

### Claim 10 (depends on 9)

The composition according to claim 9, wherein the birefringent small molecules are present in the composition in a range from 30 to 25 wt. % dry solids, and the birefringent polymer is present in the composition in a range from 70 to 75 wt. % dry solids.

### Claim 11 (depends on 9)

The composition according to claim 9, wherein the birefringent small molecules are present in the composition in a range from 35 to 30 wt. % dry solids, and the birefringent polymer is present in the composition in a range from 65 to 70 wt. % dry solids.

### Claim 12 (depends on 9)

A method of forming a retarder layer comprising:
shear coating the composition of claim 9 onto a substrate along a shear coating direction to form an aligned aqueous layer;
drying the aligned aqueous layer to form a retarder layer.

### Claim 13 (depends on 12)

The method according to claim 12, wherein the drying step forms a retarder layer with a thickness in a range from 1 to 10 micrometers, or in a range from 1 to 5 micrometers.

### Claim 14

A retarder layer comprising:
birefringent small molecules and a birefringent polymer, wherein the birefringent small molecules are of a structure:
or a salt thereof; and
the birefringent polymer is of a structure:
or a salt thereof,
wherein n is an integer in a range from 25 to 10,000.

### Claim 15 (depends on 14)

The retarder layer according to claim 14, wherein the birefringent polymer is present in the retarder layer in a range from 50 to 90 wt. % dry solids, or from 60 to 80 wt. % dry solids, and the birefringent small molecules are present in the retarder layer in a range from 50 to 10 wt. % dry solids, or from 40 to 20 wt. % dry solids.

### Claim 16 (depends on 14)

The retarder layer according to claim 14, wherein the birefringent small molecules are present in the retarder layer in a range from 30 to 25 wt. % dry solids, and the birefringent polymer is present in the retarder layer in a range from 70 to 75 wt. % dry solids.

### Claim 17 (depends on 14)

The retarder layer according to claim 14, wherein the birefringent small molecules are present in the retarder layer in a range from 35 to 30 wt. % dry solids, and the birefringent polymer is present in the retarder layer in a range from 65 to 70 wt. % dry solids.

### Claim 18 (depends on 14)

The retarder layer according to claim 14, wherein the retarder layer has a thickness in a range from 1 to 10 micrometers.

### Claim 19 (depends on 18)

The retarder layer according to claim 18, wherein the retarder layer has a thickness in a range from 1 to 5 micrometers.

### Claim 20 (depends on 14)

A circular polarizer comprising:
a linear polarizer; and
a retarder, according to claim 14, in optical communication with the linear polarizer.

### Claim 21 (depends on 14)

A display comprising:
a display panel;
a polarizer; and
a retarder, according to claim 14, optically positioned between the display panel and the polarizer.

### Claim 22 (depends on 21)

The display according to claim 21, wherein the display panel comprises a liquid crystal display panel.

### Claim 23 (depends on 21)

The display according to claim 21, wherein the display panel comprises an organic light emitting diode display panel.

### Claim 24 (depends on 21)

The display according to claim 21 wherein the polarizer and the retarder form a circular polarizer.
