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US 2019/0040195 A1Published application
Surface treatment agent for substrate, comprising perfluoropolyether group-containing phosphate compound
AssigneeAsahi Glass Company, Limited
InventorKiyotaka TAKAO
Life of this patent
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Abstract
To provide a surface treatment agent capable of imparting excellent water/oil repellency, fingerprint stain removability, abrasion resistance and lubricity to the surface of a substrate. A surface treatment agent for a substrate, comprising a perfluoropolyether group-containing phosphate compound, a coating agent comprising the surface treatment agent and a liquid medium, and a substrate having a surface layer formed from the surface treatment agent or the coating agent.
Claims13
1:
- A surface treatment agent, comprising a perfluoropolyether group-containing phosphate compound, wherein the perfluoropolyether group-containing phosphate compound is a compound represented by formula (1):
- B1—(CmF2mO)n1-A1 (1)
- wherein A1 is a monovalent organic group having at least one phosphoric acid group at its terminal, B1 is RF1—O— or D1-Q1-O—CH2— and a compound represented by the formula (1) wherein A1 is a monovalent organic group having at least one phosphoric acid group at its terminal, B1 is A2-O—, wherein a content of the compound represented by the formula (1) wherein B1 is A2-O— is from 10 to 60 parts by mass, per 100 parts by mass in total of the compound represented by the formula (1) wherein B1 is RF1—O— or D1-O1—O—CH2—,
- wherein RF1 is a C1-6 perfluoroalkyl group, D1 is CF3— or CF3—O—, O1 is a C1-20 fluoroalkylene group comprising a hydrogen atom, a C2-20 fluoroalkylene group comprising a hydrogen atom and having an etheric oxygen atom between carbon-carbon atoms, a C1-20 alkylene group, or a C2-20 alkylene group having an etheric oxygen atom between carbon-carbon atoms, and A2 is a monovalent organic group having at least one phosphoric acid group at its terminal,
- m is an integer of from 1 to 6, and
- n1 is an integer of from 1 to 200, provided that when n1 is at least 2, (CmF2mO)n1 may be one composed of at least two types of (CmF2mO) different in m.
3 more elements
2:
- (canceled)
3:
- The surface treatment agent according to claim 1, wherein (CmF2mO)n1 is a group represented by formula (2-1):
- (CrF2rO)n2(CsF2sO)n3 (2-1)
- wherein r is an integer of from 1 to 3, s is an integer of from 3 to 6, provided that r and s are not both 3, n2 is an integer of at least 1, n3 is an integer of at least 1, provided that n2+n3 is an integer of from 2 to 200, and a bonding order of (CrF2rO) and (CsF2sO) is not limited.
4:
- The surface treatment agent according to claim 1, wherein (CmF2mO)n1 is a group represented by formula (2-2):
- (CF2O)n7(CF2CF2O)n8 (2-2)
- wherein n7 is an integer of at least 1, n8 is an integer of at least 1, provided that n7+n8 is an integer of from 2 to 200, and a bonding order of (CF2O) and (CF2CF2O) is not limited.
5:
- The surface treatment agent according to claim 1, wherein A1 is a group represented by formula (3):
- -QF1(CX2)w1-E1-Y1—O—P(═O)(OH)2 (3)
- wherein QF1 is a C1-20 perfluoroalkylene group, CX2 is CH2 or CHF, w1 is 0 or 1, E1 is a single bond, —C(═O)NH— (provided that Y1 is bonded to N), —OC(═O)NH— (provided that Y1 is bonded to N), —O—, —C(═O)O— (provided that Y1 is bonded to O), —OC(═O)O—, —NHC(═O)NH— or —NHC(═O)O— (provided that Y1 is bonded to O),
- wherein Y1 is an alkylene group, a poly(oxyalkylene)-alkylene group, a cycloalkylene group, an arylene group, or an alkylene group in which at least one of hydrogen atoms is substituted by a hydroxy group, provided that E1 is not —O—, —OC(═O)NH— or —OC(═O)O— when w1 is 0, and Y1 is not an alkylene group when w1 is 1, CX2 is CH2 and E1 is a single bond.
1 more element
6:
- The surface treatment agent according to claim 1, wherein Q1 is a group represented by formula (4-1), (4-2) or (4-3):
- -QF2-O—CHFCF2— (4-1)
- -QF2-CHFCF2— (4-2)
- -QF2-CzH2z— (4-3)
- wherein QF2 is a single bond, a C1-15 perfluoroalkylene group, or a C2-15 perfluoroalkylene group having an etheric oxygen atom between carbon-carbon atoms, QF2 is bonded to D1, and z is an integer of from 1 to 4, provided that QF2 is not a single bond in the formula (4-1) and (4-2) when D1 is CF3—O—.
2 more elements
7:
- The surface treatment agent according to claim 1, wherein a number average molecular weight (Mn) of the compound represented by the formula (1) is 2,000 to 10,000.
8:
- The surface treatment agent according to claim 1, wherein in the compound represented by the formula (1), B1 is RF1—O— or D1-Q1-O—CH2—.
9-10:
- (canceled)
11:
- The surface treatment agent according to claim 1, which is suitable for treating a surface of a sapphire substrate.
12:
- A coating agent comprising the surface treatment agent of claim 1 and a liquid medium.
13:
- A substrate having a surface layer formed from the surface treatment agent of claim 1.
14:
- (canceled)