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US 2018/0261771 A1Published application
Fluoroalkylfluorene derivatives
AssigneeLomox Limited
InventorsLuke William Judd, Matthew Phillip Aldred, Gene Carl Koch
Life of this patent
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Abstract
Compounds of the formula D-S1-A-S2—B1 wherein A comprises a 2,7-disubstituted 9,9-fluoroalkyl fluorene diradical of the formula wherein S1, S2, D and B1 have meanings given in the description that are useful as charge transport and emissive materials for the fabrication of electronic devices such as diodes, transistors, and photovoltaic devices.
Claims20
A compound of Formula (I)
- D-S1-A-S2—B1, Formula (I)
- wherein:
- A represents —Ar1-(FL-Ar2)n- and comprises from 1 to 8 FL groups;
- Ar1 and Ar2 in each occurrence are independently selected from the group comprising Ara and a bond;
- Ara represents a diradical comprising 1 aromatic, heteroaromatic or FL moiety, or 2, 3, 4 or 5 aromatic, heteroaromatic and/or FL moieties mutually connected by a single bond;
- n is an integer from 1 to 8;
- FL is a fluorene moiety of the structure
- incorporated into the chain through covalent bonds at C-2 and C-7;
- the R groups of each FL moiety are identical and are selected from the group consisting of straight chain or branched achiral C1-C14 alkyl, C1-C14 haloalkyl, C1-C14 fluoroalkyl, C2-C14 alkenyl group, optionally wherein 1, 2, 3, 4 or 5 CH2 groups are replaced by an oxygen provided that no acetal, ketal, peroxide or vinyl ether is present in the R group;
- D represents a cross linkable group or, when B1 represents a hydrogen, D represents —B2—S3—B3—S1a-A-S2a—B1a, —S3(B2)—B3—S1a-A-S2a—B1a, —S3(B2)(B3)—S1a-A-S2a—B1a, —S3(B2)(B3), or a cross linkable group wherein the dash at the left-hand end of the chain represents the point of attachment to S1;
- B1 represents a cross linkable group or a hydrogen atom;
- B1a represents a cross linkable group or a hydrogen atom;
- B2 and B3 each represents a cross linkable group;
- S1, S2, S1a and S2a are flexible linker groups;
- and
- S3 is a spacer group.
13 more elements
A device comprising a polymer comprising 2,7-disubstituted 9,9-fluoroalkyl fluorene repeat units
- wherein R represents a straight chain or branched achiral C1-C14 alkyl, C1-C14 haloalkyl or C2-C14 alkenyl group, optionally wherein 1, 2, 3, 4 or 5 of the methylene groups of R are replaced by an oxygen atom provided that no acetal, ketal, peroxide or vinyl ether is present, and partially or fully fluorinated derivatives of these groups.
The compound
- wherein R in each case is a straight chain or branched achiral C1-C14 alkyl, C1-C14 haloalkyl, C1-C14 fluoroalkyl, C2-C14 alkenyl group, optionally wherein 1, 2, 3, 4 or 5 CH2 groups are replaced by an oxygen provided that no acetal, ketal, peroxide or vinyl ether is present in the R group.
Dependencies are inferred from the claim text.