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US 2018/0237459 A1Published application
Method for coupling an aromatic or vinylic compound to a boron-containing compound
AssigneeDow Global Technologies LLC
InventorsPatrick S. Hanley, Matthias S. Ober, William J. Kruper
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Abstract
In one aspect, there is provided a method of coupling an aromatic or vinylic compound having a fluorosulfonate substituent to a boron-containing compound. In another aspect, there is provided a method of coupling an aromatic or vinylic compound having a hydroxyl substituent to a boron-containing compound in a one-pot reaction.
Claims17
A method of coupling an aromatic or vinylic compound to a boron-containing compound, the method comprising:
- providing the aromatic or vinylic compound having a fluorosulfonate substituent;
- providing the boron-containing compound;
- and
- reacting the aromatic or vinylic compound and the boron-containing compound in a reaction mixture, the reaction mixture including a catalyst having at least one group 10 atom, the reaction mixture under conditions effective to couple the aromatic or vinylic compound to the boron-containing compound thereby forming a new carbon-boron bond between the aromatic or vinylic compound and the boron-containing compound.
1 more element
A method of coupling an aromatic or vinylic compound to a boron-containing compound, the method comprising:
- providing the aromatic or vinylic compound having a hydroxyl substituent;
- providing sulfuryl fluoride in the presence of a base;
- reacting the aromatic or vinylic compound and the sulfuryl fluoride in a reaction mixture, the reaction mixture under conditions effective to couple the sulfur atom of the sulfuryl fluoride to the oxygen of the hydroxyl group;
- providing to the reaction mixture the boron-containing compound;
- providing to the reaction mixture a catalyst having at least one group 10 atom;
- and
- reacting the aromatic or vinylic compound and the boron-containing compound in the reaction mixture, the reaction mixture under conditions effective to couple the aromatic or vinylic compound to the boron-containing compound.
4 more elements
Dependencies are inferred from the claim text.