Fluorinated cycloalkene functionalized silicas

A fluorinated cyclopentene moiety having a general chemical formula:

• wherein R1 is selected from the group consisting of substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, aryl, heteroaryl, and heterocycle;
• wherein Y is selected from the group consisting of F, OR2, SR2, and NR2R5 wherein R2 is selected from the group consisting of substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, aryl, heteroaryl, and heterocyclic;
• wherein R5 is selected from the group consisting of H, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, aryl, heteroaryl, and heterocyclic;
• and wherein at least one of R1 or R2 includes a reactive functional group selected from the group consisting of an alkene, an alkyne, and a hydrosilylation reaction product of the alkene or the alkyne, with a silane.