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US 2018/0081082 A1Published application
Retardation film and utilization thereof
AssigneeKaneka Corporation
InventorsHiroto KOMA, Ryutaro MUKAI, Tomohiro ABO
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Abstract
The retardation film according to the present invention is characterized by: including a polymer material that includes at least one cellulose derivative which includes specific monomer units; having an in-plane retardation Re(550) of 105-160 nm, reverse wavelength dispersion property, Re(450)/Re(550), of 0.80-0.89, and a thickness of 20-50 μm; and containing inorganic particles. In particular, the present invention exhibits the effect of reducing the photoelastic coefficient.
Claims21
1-17. (canceled)
18:
- A retardation film, comprising:
- a polymer material including at least one cellulose derivative having a monomeric unit of formula (1),
- where R1, R2, and R3 in the formula (1) are each independently hydrogen, a saturated aliphatic group, an unsaturated aliphatic group, or an aromatic group;
- and
- a plurality of inorganic particles,
- wherein the retardation film has an in-plane retardation Re(550) of 105 nm to 160 nm, a reverse wavelength dispersion property Re(450)/Re(550) of 0.80 to 0.89, and a thickness of 20 μm to 50 μm.
3 more elements
19:
- The retardation film of claim 18, wherein at least one of R1, R2, and R3 in the formula (1) is an aromatic group.
20:
- The retardation film of claim 19, wherein the cellulose derivative has a total degree of substitution D1 of 2.00 to 2.70 for substitution by a saturated aliphatic group or an unsaturated aliphatic group, and a degree of substitution D2 of 0.30 to 1.00 for substitution by an aromatic group, satisfying D1+D2≦3.0 in the cellulose derivative, and the polymer material has a total degree of substitution D3 of 0.40 to 0.50 for substitution by an aromatic group in the polymer material.
21:
- The retardation film of claim 19, wherein the aromatic group is an aromatic acyl group.
22:
- The retardation film of claim 18, wherein the retardation film has a photoelastic coefficient of less than 42.0×10−12 m2/N.
23:
- The retardation film of claim 18, wherein the inorganic particles comprise an inorganic material having an unsaturated bond.
24:
- The retardation film of claim 18, wherein the inorganic particles comprise an inorganic material having an acryloyl group.
25:
- The retardation film of claim 18, wherein the inorganic particles are included in an amount of from 5 parts by weight to 40 parts by weight with respect to 100 parts by weight of the cellulose derivative.
26:
- The retardation film of claim 18, wherein the inorganic particles comprise silica particles.
27:
- The retardation film of claim 18, wherein the inorganic particles have an average particle diameter of 5 nm to 30 nm.
28:
- The retardation film of claim 18, wherein the inorganic particles are spherical particles.
29:
- The retardation film of claim 18, wherein the cellulose derivative includes a saturated aliphatic group in the formula (1) which is an aliphatic alkyl group.
30:
- The retardation film of claim 29, wherein the aliphatic alkyl group is an ethyl group.
31:
- The retardation film of claim 18, wherein the at least one cellulose derivative comprises a plurality of cellulose derivatives.
32:
- The retardation film of claim 31, wherein each of the cellulose derivatives has a total degree of substitution D1 of 2.00 to 2.70 for substitution by a saturated aliphatic group or an unsaturated aliphatic group, and a degree of substitution D2 of 0.30 to 1.00 for substitution by an aromatic group, satisfying D1+D2≦3.0 in each of the cellulose derivatives, and the polymer material has a total degree of substitution D3 of 0.40 to 0.50 for substitution by an aromatic group in the polymer material.
33:
- The retardation film of claim 31, wherein each of the cellulose derivatives has a total degree of substitution D1 of 2.30 to 2.60 for substitution by a saturated aliphatic group or an unsaturated aliphatic group, and a degree of substitution D2 of 0.35 to 0.70 for substitution by an aromatic group, satisfying D1+D2≦3.0 in each of the cellulose derivatives, and the polymer material has a total degree of substitution D3 of 0.44 to 0.48 for substitution by an aromatic group in the polymer material.
34:
- A circular polarizer plate, comprising:
- one or more of the retardation film of claim 18.
35:
- An image display device, comprising:
- the circular polarizer plate of claim 34.
36:
- A method of manufacturing the retardation film of claim 18, comprising:
- drawing a production film comprising the polymer material at a draw ratio of 20% to 200%.
37:
- The method of claim 36, wherein the drawing is conducted at a temperature in a range of from (Tg−30) ° C. to (Tg+30) ° C., where Tg is a glass transition temperature of the production film.