# US 2018/0024284 A1 · Method For Manufacturing Retardation Film By Using Dual-Axial Stretching Process And A Retardation Film

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- Number: US 2018/0024284 A1
- Document ID: US20180024284A1
- Status: Published application
- Kind: A1
- Application number: 15/213,614
- Filed: 2016-07-19
- Published: 2018-01-25
- Earliest claimed: 2016-07-19
- Assignees: Entire Technology Co., Ltd.
- Applicants: Entire Technology Co., Ltd.
- Inventors: Peng-Yi Huang; Shi-Liang Chen; Cheng Lun Liao
- Web page: https://patentgrep.com/patent/US20180024284A1

## CPC

- G02B 5/3083: {Birefringent or phase retarding elements (G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001)}
- B29C 55/16: simultaneously
- B29D 11/00788: {Producing optical films}
- B29K 2033/12: {Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate}
- B29K 2995/0032: Birefringent
- B29L 2031/3475: {Displays, monitors, TV-sets, computer screens}
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00)
- B29D: PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE (making granules B29B9/00; making preforms B29B11/00)
- B29K: INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29L: INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES

## Abstract

A method for manufacturing a retardation film by using a dual-axial stretching process uses a PMMA to produce a cast film. The cast film is stretched in both a proceeding direction and a width direction simultaneously by 1.0˜5.0 times in both the length and the width. By using a predetermined annealing temperature to co-coordinate shrinking of the film in both directions simultaneously, decrease of the refraction ability caused by the stretching can be controlled. To attain high uniformity of the optical characteristics of the film, the surface temperature of the film during the stretching process is controlled within a predetermined range, then the optical variation thereof is improved, and thus the following optical characteristics are achieved: R0: 0˜3 nm and Rth: −40˜0 nm; wherein R0=α*ΔTe+β*ΔXe+γ*ΔTs+δ*ΔXs+C1 and Rth=a*ΔTe+b*ΔXe+c*ΔTs+d*ΔXs+C2.

## Claims

### Claim 1

A method for manufacturing a retardation film by using a dual-axial stretching process, comprising the steps of:
Step (A): providing a cast film;
Step (B): in a preheating process, at a predetermined preheating temperature, preheating the cast film;
Step (C): in a stretching process, at a predetermined stretching temperature, performing simultaneously dual-axial stretching upon the cast film; wherein, in this stretching process, the cast film is stretched by a vertical stretching magnification factor (MD) and a horizontal stretching magnification factor (TD), and both the MD and the TD are within 1.0˜5.0 times;
Step (D): in an annealing process, at a predetermined annealing temperature, annealing the cast film so as to shrink the cast film simultaneously in both a vertical direction and a horizontal direction; and
Step (E): in a cooling process, at a predetermined cooling temperature, cooling the cast film, and then outputting an output retardation film.

### Claim 2 (depends on 1)

The method for manufacturing a retardation film of claim 1, wherein:
the predetermined preheating temperature is within 100˜200° C., and, while in preheating, a preheating wind speed is within 5˜22 m/s;
the predetermined stretching temperature is within 120˜200° C., and, while in stretching, a stretching wind speed is within 5˜16 m/s so as to control a temperature of the cast film in the stretching process to be within 120˜170° C.;
the predetermined annealing temperature is within 80˜200° C., and, while in annealing, a annealing wind speed is within 5˜22 m/s;
the predetermined cooling temperature is within 25˜120° C., and, while in cooling, a cooling wind speed is within 5˜16 m/s; and,
in the annealing process, a shrinkage ratio for both the MD and the TD of the cast film is within 0˜18%.

### Claim 3 (depends on 1)

The method for manufacturing a retardation film of claim 1, wherein the predetermined stretching temperature (Text), the MD, the TD and the predetermined annealing temperature (Tshrink) fulfill mathematical criteria as follows:
R0=α*ΔTe+β*ΔXe+γ*ΔTs+δ*ΔXs+C1;
wherein:
R0 is an in-plane retardation value of the output retardation film and is within 0˜3 nm;
ΔTe is a temperature difference value in the stretching process, and ΔTe=Text−Tg;
ΔXe is a stretching magnification factor difference value in the stretching process, and ΔXe=MD−TD;
ΔTs is a temperature difference value in the annealing process, and ΔTs=Tshrink−Tg;
ΔXs is a shrinkage ratio value of the cast film in the annealing process, and ΔXs=[(1−MDshrink)*(1−TDshrink)−1], wherein the MDshrink is a shrinkage ration of the cast film in the vertical direction in the annealing process, wherein the TDshrink is a shrinkage ration of the cast film in the horizontal direction in the annealing process; and
α, β, γ, δ and C1 are all machine parameters, and Tg is a material parameter.

### Claim 4 (depends on 3)

The method for manufacturing a retardation film of claim 3, wherein α=−0.0879, β=−6.24, γ=0.011, δ=−12.8, Tg=118 and C1=2.19.

### Claim 5 (depends on 1)

The method for manufacturing a retardation film of claim 1, wherein the predetermined stretching temperature (Text), the MD, the TD, and the predetermined annealing temperature (Tshrink) fulfill mathematical criteria as follows:
Rth=a*ΔTe+b*ΔXe+c*ΔTs+d*ΔXs+C2;
wherein:
Rth is an in-depth retardation value of the output retardation film and is within −40˜0 nm;
ΔTe is a temperature difference value in the stretching process, and ΔTe=Text−Tg;
ΔXe is a stretching magnification factor difference value in the stretching process, and ΔXe=MD−TD;
ΔTs is a temperature difference value in the annealing process, and ΔTs=Tshrink−Tg;
ΔXs is a shrinkage ratio value of the cast film in the annealing process, and ΔXs=[(1−MDshrink)*(1−TDshrink)−1], wherein the MDshrink is a shrinkage ration of the cast film in the vertical direction in the annealing process, wherein the TDshrink is a shrinkage ration of the cast film in the horizontal direction in the annealing process; and
a, b, c, d and C2 are all machine parameters, and Tg is a material parameter.

### Claim 6 (depends on 5)

The method for manufacturing a retardation film of claim 5, wherein a=0.958, b=2.5, c=0.321, d=12.1, Tg=118 and C2=−39.4.

### Claim 7 (depends on 2)

The method for manufacturing a retardation film of claim 2, wherein:
the predetermined preheating temperature is within 145˜155° C.;
the predetermined stretching temperature is within 130˜150° C.;
the predetermined annealing temperature is within 120˜150° C.; and
the predetermined cooling temperature is within 25˜100° C.

### Claim 8 (depends on 1)

The method for manufacturing a retardation film of claim 1, wherein the cast film is made of a PMMA having a thickness within 250˜1200 μm and a width within 500˜980 μm.

### Claim 9 (depends on 1)

The method for manufacturing a retardation film of claim 1, wherein an in-plane retardation value R0 of the output retardation film is within 0˜3 nm, an in-depth retardation value Rth of the output retardation film is within −40˜0 nm, a refractive index Nx of the cast film in an in-plane slow axis direction is within 1.499900˜1.499995, a refractive index Ny of the cast film in an in-plane fast axis direction is within 1.499900˜1.499955, a refractive index Nz of the cast film in a thickness direction is within 1.500001˜1.500045, and a thickness of the output retardation film is within 38˜250 μm.

### Claim 10 (depends on 1)

A retardation film manufactured by the method of claim 1, wherein an in-plane retardation value R0 of the output retardation film is within 0˜3 nm, an in-depth retardation value Rth of the output retardation film is within −40˜0 nm, a refractive index Nx of the cast film in an in-plane slow axis direction is within 1.499900˜1.499995, a refractive index Ny of the cast film in an in-plane fast axis direction is within 1.499900˜1.499955, a refractive index Nz of the cast film in a thickness direction is within 1.500001˜1.500045, and a thickness of the output retardation film is within 38˜250 μm.