# US 2018/0022689 A1 · Alkyl Aromatic Hydroalkylation For The Production of Plasticizers

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- Number: US 2018/0022689 A1
- Document ID: US20180022689A1
- Status: Published application
- Kind: A1
- Application number: 15/722,061
- Filed: 2017-10-02
- Published: 2018-01-25
- Earliest claimed: 2013-01-28
- Assignees: ExxonMobil Chemical Patents Inc.
- Applicants: ExxonMobil Chemical Patents Inc.
- Inventors: Jihad M. Dakka; Christine A. Costello; Edmund J. Mozeleski; Stephen Zushma; Diana S. Smirnova; Catherine A. Faler; Victor DeFlorio
- Web page: https://patentgrep.com/patent/US20180022689A1

## CPC

- C07C 69/76: Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C 2/68: with halides
- C07C 2/76: by condensation of hydrocarbons with partial elimination of hydrogen
- C07C 51/285: with peroxy-compounds
- C07C 67/08: by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
- C07C 67/39: by oxidation of groups which are precursors for the acid moiety of the ester
- C07C 69/78: Benzoic acid esters
- C08J 5/18: Manufacture of films or sheets
- C08K 3/10: Metal compounds
- C08K 5/10: Esters; Ether-esters
- C08K 5/101: of monocarboxylic acids
- C08K 5/103: with polyalcohols
- C08K 5/12: of cyclic polycarboxylic acids
- C09D 127/06: Homopolymers or copolymers of vinyl chloride
- D06M 13/224: Esters of carboxylic acids; Esters of carbonic acid
- D06N 3/0059: {Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes (D06N3/0065 takes precedence)}
- D06N 5/00: {Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch (compositions of bituminous materials C08L95/00, roof covering E04D5/00, roofing underlays E04D12/002)}
- D06N 7/0002: {Wallpaper or wall covering on textile basis}
- D21H 27/20: Flexible structures being applied by the user, e.g. wallpaper (printed wallpapers B41M3/18; paperhanging B44C7/00; pregummed wallpaper C09J7/21)
- H01B 3/443: {from vinylhalogenides or other halogenoethylenic compounds}
- C07C 2601/14: The ring being saturated
- C08J 2327/06: Homopolymers or copolymers of vinyl chloride
- C08K 2201/014: Additives containing two or more different additives of the same subgroup in C08K
- Y10T 428/2964: Artificial fiber or filament
- Y10T 428/31935: Ester, halide or nitrile of addition polymer
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)
- C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09)
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- D06M: TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06N: WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D21H: PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- H01B: CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES (selection for magnetic properties H01F1/00; waveguides H01P {; printed circuits H05K})
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

Provided are compounds of the following: wherein R1 is a saturated or unsaturated cyclic hydrocarbon optionally substituted with an alkyl and/or an OXO-ester, and R2 is a C4 to C14 hydrocarbyl, preferably the residue of a C4 to C14 OXO-alcohol. Also provided are processes for making the compounds and plasticized polymer compositions containing said compounds.

## Claims

### Claim at position 1

-38. (canceled)

### Claim 39

A mixture of compounds represented by the formulas:
and one or more of
and/or
and/or
wherein each R3 is, independently, —CO2R2*, R2 is a C4 to C14 hydrocarbyl, R2* is a C4 to C14 hydrocarbyl, that may be the same or different as R2.

### Claim 40 (depends on 39)

The mixture of claim 39, wherein each R2 is, independently, a C6 to C9 hydrocarbyl.

### Claim 41 (depends on 39)

The mixture of claim 39, wherein each R2 is, independently, a C6, C7, C8 or C9 alkyl.

### Claim 42 (depends on 39)

The mixture of claim 39, wherein each R2 is, independently, hexyl, heptyl, octyl or nonyl, or an isomer thereof.

### Claim 43 (depends on 39)

The mixture of claim 39, wherein the mixture comprises:
where each R2 is, independently, a C4 to C14 hydrocarbyl.