Pesticidally active semi-carbazones and thiosemicarbazones derivatives

A compound of formula I,

• wherein,
• Ar1 and Ar2 are independently of each other phenyl, thienyl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, furanyl, wherein said phenyl, thienyl, pyridyl, pyrimidinyl, pyrazinyl, pyridazinyl, furanyl can be substituted by one to three substituents independently selected from the group consisting of hydrogen, C1-C4alkyl, C2-C4alkenyl, C2-C4alkynyl, C3-C6cycloalkyl, C1-C4haloalkyl, C2-C4haloalkenyl, C2-C4haloalkynyl, C3-C6halocycloalkyl, C1-C3haloalkyl-C3-C6cycloalkyl, C3-C6cycloalkoxy, halogen, cyano, cyano-C1-C4alkyl, cyano-C3-C6cycloalkyl nitro, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylthio, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4alkylsulfoximino, C1-C4alkylamino, C2-C6dialkylamino, C3-C6cycloalkylamino, C1-C4alkyl-C3-C6cycloalkylamino, C2-C4alkylcarbonyl, CHO, C2-C6alkoxycarbonyl, C2-C6haloalkoxycarbonyl, C2-C6alkylaminocarbonyl, C2-C6haloalkylaminocarbonyl or C2-C6 dialkylaminocarbonyl;
• X is a direct bond, O, S, SO2, CR4R6 or NR6;
• Y is oxygen or sulfur;
• R1 is hydrogen, C1-C6-alkyl, halo-C1-C6-alkyl, C3-C6-cycloalkyl or C1-C3-alkoxy;
• R2 and R3 are independently from each other hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, halo-C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6haloalkenyl, C2-C6-alkynyl, C2-C6haloalkynyl, C1-C4alkoxy-C1-C4alkyl, C1-C4haloalkylsulfinyl, C1-C4haloalkylsulfonyl, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C2-C4alkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6alkylaminocarbonyl, C3-C6dialkylaminocarbonyl, C2-C6alkoxycarbonyloxy, C2-C6alkylaminocarbonyloxy, C3-C6dialkylaminocarbonyloxy, or C1-C4alkoxyimino-C1-C4alkyl;
• provided that when R2 and R3 are different from hydrogen, R2 and R3 can be substituted by one to three substituents independently selected from the group consisting of C1-C4alkyl, C2-C4alkenyl, C2-C4alkynyl, C3-C6cycloalkyl, C1-C4haloalkyl, C2-C4haloalkenyl, C2-C4haloalkynyl, C3-C6halocycloalkyl, halogen, cyano, nitro, C1-C4alkoxy, C1-C4haloalkoxy, C1-C4alkylthio, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4alkylsulfoximino, C1-C4alkylamino, C2-C6dialkylamino, C3-C6cycloalkylamino, C1-C4alkyl-C3-C6cycloalkylamino, C2-C4alkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6alkylaminocarbonyl, and C2-C8 dialkylaminocarbonyl;
• R4, R5 and R6 are independently from each other hydrogen, C1-C6-alkyl, halo-C1-C6-alkyl, C3-C6-cycloalkyl or C1-C3-alkoxy;
• J is an aromatic or a non-aromatic bicyclic ring system selected from J1, J2 and J3
• wherein indicates that the ring is aromatic or non-aromatic;
• in which the arrows show the connectivity as depicted in formula (I) wherein
• A1 is nitrogen, N—R7a, sulfur, oxygen or C—R7b;
• A2 is nitrogen, N—R8a, sulfur, oxygen or C-R8b;
• A3 is nitrogen, N—R9a, sulfur, oxygen or C—R9b;
• B1 is nitrogen or C—R10;
• B2 is nitrogen or C—R11;
• B3 is nitrogen or C—R12;
• B4 is nitrogen or C—R13;
• B5 is nitrogen or C—R14;
• B6 is nitrogen or C—R15;
• C1 is nitrogen, C or C—R16;
• C2 is nitrogen, C or C—R17;
• with the provisos that
• a) not more than two substituents A can be oxygen or sulfur,
• b) when two substituents A are oxygen and/or sulphur, these substituents are A1 and A3, and A2 is C—R8b, and
• c) when C1 is N, then C2 is C or C—R16 and when C2 is N, then C1 is C or C—R17;
• each of R7a, R7b, R8a, R8b, R9a, R9b, R10, R11, R12, R13, R14, R15, R16 and R17 are independently from each other hydrogen, halogen, nitro, cyano, hydroxy, ═O, CHO, C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl, C3-C6cycloalkyl, C1-C6haloalkyl, C2-C6haloalkenyl, C2-C6haloalkynyl, C3-C6halocycloalkyl, C1-C4alkoxy, C1-C4alkoxy-C1-C4alkoxy-C1-C4alkyl, C1-C4haloalkoxy, C1-C4alkylthio, C1-C4haloalkylthio, C1-C4haloalkylsulfinyl, C1-C4haloalkylsulfonyl, C1-C4alkylsulfinyl, C1-C4alkylsulfonyl, C1-C4alkylsulfonyl-C1-C4alkyl, C1-C4alkylsulfoximino-C1-C4alkyl, C1-C4alkylamino, C2-C4dialkylamino, C3-C6cycloalkylamino, C1-C6alkyl-C3-C6cycloalkylamino, C2-C4alkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6alkylaminocarbonyl, C3-C6dialkylaminocarbonyl, C2-C6alkoxycarbonyloxy, C2-C6alkylaminocarbonyloxy, C3-C6dialkylaminocarbonyloxy, C1-C4alkoxyimino-C1-C4alkyl, —CONHSO2—C1-C6-alkyl, —CONHSO2N(C1-C6-alkyl)2, or C3-C6trialkylsilyl;
• or an agrochemically acceptable salt, stereoisomer, tautomer and N-oxide of the compounds of formula I.