Reactive silica in epoxidized polybutadiener
AssigneesCompagnie Generale Des Etablissements Michelin, Michelin Recherche et Technique S.A.
InventorsJessica MCDOWELL, Christopher PAPPAS, Xavier SAINTIGNY, Didier VASSEUR
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Abstract
A rubber composition that is based upon a cross-linkable elastomer composition comprising, per 100 parts by weight of rubber (phr) between 70 phr and 100 phr of an epoxidized rubber component selected from an epoxidized polybutadiene rubber (eBR), an epoxidized styrene-butadiene rubber (eSBR), or combinations thereof, wherein the epoxidized rubber component has a Tg of between −80° C. and −110° C. and an epoxy-function content of between 1 mol % and 25 mol %; between 30 phr and 150 phr of a plasticizing resin; and a quickly reactive silica that provides a macro dispersion Z-value of at least 50 in a defined rubber composition; and a non-silol coupling agent.
Claims19
A rubber composition that is based upon a cross-linkable elastomer composition, the cross-linkable elastomer composition comprising, per 100 parts by weight of rubber (phr):
- between 70 phr and 100 phr of an epoxidized rubber component selected from an epoxidized polybutadiene rubber (eBR), an epoxidized styrene-butadiene rubber (eSBR), or combinations thereof, wherein the epoxidized rubber component has a Tg of between −80° C. and −110° C. and an epoxy-function content of between 1 mol % and 25 mol %;
- between 30 phr and 150 phr of a plasticizing resin;
- a quickly reactive silica that provides a macro dispersion Z-value of at least 50 in a defined rubber composition;
- and
- a coupling agent corresponding to
- Z-A-Sz-A-Z
- wherein x is an integer between 2 and 8, A is a divalent hydrocarbon radical and Z corresponds to one of the following:
- wherein R1 radicals are the same or different and are a C1-C18 alkyl, C5-C18 cycloalkyl or C6-C18 aryl group, R2 radicals are the same or different and are C1-C18 alkoxyl or C5-C18 cycloalkoxyl group and wherein R2 radicals are not a hydroxyl radical.
The rubber composition of 18, wherein the plasticizing resin is a terpene phenolic resin.
Dependencies are inferred from the claim text.