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US 2018/0000090 A1Published application
Microbiocidal benzoxaboroles
AssigneeSyngenta Participations AG
InventorsRamya RAJAN, Daniel STIERLI, Renaud BEAUDEGNIES, Peter RENOLD
Life of this patent
Estimating the term…
Abstract
Compounds of formula (I) are as defined in the claims, and their use in compositions and methods for the control and/or prevention of microbial infection, particularly fungal infection, in plants and to processes for the preparation of these compounds.
Claims10
A compound of formula (I)
- wherein
- Ra and Rb is H, fluorine, chlorine, bromine, cyano, nitro, C1-C4alkyl which can be substituted by one to five R5, C1-C4alkoxy which can be substituted by one to five R5, C1-C4haloalkyl which can be substituted by one to five Rya;
- Q is a five- to ten-membered monocyclic or bicyclic ring system linked via a carbon atom to the rest of the molecule, said ring system is aromatic and can contain 1 to 4 ring members selected from the group consisting of nitrogen, oxygen, —C(O)— and —S(O)m—, it not being possible for each ring system to contain more than 2 oxygen atoms and more than 2 sulfur atoms, said five- to ten-membered ring system which can be can be substituted by one to five R5;
- R5 is independently selected from halogen, —OH, —CN, —NO2, —NR6N7, C1-4alkyl, C1-4haloalkyl, C1-4alkoxy, C1-4haloalkoxy, C3-6cycloalkyl, C2-C6alkenyl, C2-6alkynyl, C1-4alkylthio, C1-4haloalkylthio, —C(O)H, —C(O)(C1-4 alkoxy), —C(O)(C1-4 alkyl), —C(O)—NH—(C1-4 alkyl), —C(O)—N(C1-4 alkyl)2, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4alkylthio, C1-C4alkoxy-C1-C4alkyl, C1-C4haloalkoxy, hydroxyimino, C1-C4alkoximino, C1-C4alkoximino C1-C4alkyl and C1-C4alkylendioxy;
- —C(O)NH(C1-4 alkyl), —C(O)N(C1-4 alkyl)(C1-4 alkyl), —OC(O)NH(C1-4 alkyl), —OC(O)N(C1-4 alkyl)(C1-4 alkyl), —NHC(O)(C1-4 alkyl), —NHC(O)(C1-4 alkoxy), —N(C1-4alkyl)C(O)(C1-4 alkyl), —N(C1-4 alkyl)C(O)(C1-4 alkoxy), —OC(O) (C1-4 alkyl), —C(═N—O—(C1-4 alkyl)-H, —C(═N—O—(C1-4 alkyl)-C1-C4alkyl;
- or R5 is independently selected from a —X-(6 to 10 membered-aryl) group which can be substituted by one to five substituents selected halogen, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, —CN, —NO2, —NR6N7, C3-C6cycloalkyl;
- or R5 is independently selected from a —X-linked-5- or 6-membered heteroaryl group which comprises one or two or three heteroatoms selected from or two N, O and S which can be substituted by one to five substituents selected from halogen, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, —CN, —NO2, —NR6R7, C3-C6cycloalkyl;
- or R5 is independently selected from a —X-linked-5- or 6-membered heterocycloalkyl group which comprises one or two or three heteroatoms selected from or two N, O and S which can be substituted by one to five substituents selected from halogen, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, —CN, —NO2, —NR6R7, C3-C6cycloalkyl;
- R5a is independently selected from C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy, —OH, —CN, —NO2;
- R6 and R7 are independently H, —C1-4alkyl —C2-4alkenyl, —C2-4alkynyl or combine with the interjacent nitrogen to form a five- or six-membered heterocyclic ring which may comprise additionally to the interjacent nitrogen atom one or two heteroatoms selected from N, O or S atoms, it not being possible for each ring system to contain more than 2 oxygen atoms and more than 2 sulfur atoms, and this five- or six-membered heterocyclic ring is unsubstituted or this five- or six-membered heterocyclic ring which can be substituted by one to five R5;
- X is a direct bond or a bridge selected from —O—, —S(O)m— or —NH—;
- m is 0, 1 or 2;
- or an agronomically acceptable salt or N-oxide thereof.
10 more elements
A compounds of formula (VIII)
- wherein
- HAL is halogen;
- and Ra and Rb independently are H, fluorine, chlorine, bromine, cyano, nitro, C1-C4alkyl, C1-C4alkoxy, C1-C4haloalkyl;
- or a compound according to the formula (I-A)
- wherein
- R1 and R2 independently are C1-C4alkyl, C1-C4haloalkyl, phenyl;
- and Ra and Rb independently are H, fluorine, chlorine, bromine, cyano, nitro, C1-C4alkyl, C1-C4alkoxy, C1-C4haloalkyl;
- or a compound according to the formula (I-B)
- wherein
- R3 and R4 independently are C1-C4alkyl, C1-C4haloalkyl, phenyl;
- and Ra and Rb independently are H, fluorine, chlorine, bromine, cyano, nitro, C1-C4alkyl, C1-C4alkoxy, C1-C4haloalkyl;
- or a compound according to the formula (I-C)
- wherein
- R3 and R4 independently are C1-C4alkyl, C1-C4haloalkyl, phenyl;
- and Ra and Rb independently are H, fluorine, chlorine, bromine, cyano, nitro, C1-C4alkyl, C1-C4alkoxy, C1-C4haloalkyl;
- or a compound according to the formula (I-D)
- wherein
- and Ra and Rb independently are H, fluorine, chlorine, bromine, cyano, nitro, C1-C4alkyl, C1-C4alkoxy, C1-C4haloalkyl;
- or a compound according to the formula (I-E)
- wherein
- and Ra and Rb independently are H, fluorine, chlorine, bromine, cyano, nitro, C1-C4alkyl, C1-C4alkoxy, C1-C4haloalkyl.
18 more elements
Dependencies are inferred from the claim text.