Back to results
US 2018/0000079 A1Published application
Azoline compounds substituted by a carbocyclic condensed ring system
AssigneeBASF SE
InventorsPascal Bindschaedler, Gopal Krishna Datta, Wolfgang von Deyn, Franz-Josef Braun
Life of this patent
Estimating the term…
Abstract
Compounds of formula (I) as defined herein are provided. Uses of these compounds for controlling invertebrate pests, protecting plant propagation material and providing an agricultural and a veterinary composition including the compounds are also described. Compounds for use as intermediate compounds in the preparation of compounds I are also described.
Claims22
Azoline compounds of the formula I
- wherein:
- X1 is selected from O and CH2;
- A is a group selected from A1, A2 and A3;
- wherein
- A1 is a group —C(R7a)(R7b)—N(R51)—C(═O)—R61;
- A2 is a group —CH(═NNH—C(O)—NH—R62);
- and
- A3 is a heterocyclic ring selected from heterocyclic rings of formulae D-1 to D-66:
- wherein
- a zigzag line in the heterocyclic rings of formulae D-1 to D-66 denotes an attachment point to a remainder of the azoline compound;
- k is one of 0, 1, 2 and 3;
- and
- each R11 is independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl and C2-C4-haloalkynyl;
- B1, B2, B3, B4 and B5 are independently selected from a group consisting of N and CR2, wherein no more than one of B1, B2, B3, B4 and B5 is N;
- Rg1 and Rg2 form together a bridging group selected from —CH2CH2CH2— and —CH2CH2CH2CH2—;
- R1 is C1-haloalkyl;
- each R2 is independently selected from a group consisting of hydrogen, halogen, C1-C2-haloalkoxy and C1-C2-haloalkyl;
- R3a and R3b are independently selected from hydrogen and halogen;
- R7a and R7b are independently selected from hydrogen, cyano, methyl and C1-haloalkyl;
- R51 is selected from a group consisting of hydrogen, C1-C3-alkyl, C2-C3-alkenyl, C2-C3-alkynyl, C1-C3-alkoxymethyl and CH2—CN;
- R61 is selected from a group consisting of hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkyl substituted by up to two radicals R81, C1-C6-haloalkyl which carries one radical R81, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl which carries a CN substituent, C3-C6-halocycloalkyl, —N(R101a)R101b, —C(═O)N(R111a)R111b,
- —CH═NOR91, phenyl, phenyl which is substituted with up to 5 substituents R16 and a heterocyclic ring selected from rings of formulae E-1 to E-63;
- wherein
- a zigzag line in the rings of formulae E-1 to E-63 denotes an attachment point to a remainder of the azoline compound,
- k is one of 0, 1, 2 and 3,
- n is one of 0, 1 and 2, and
- R16 is as defined below;
- R62 is selected from a group consisting of hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C2-C4-haloalkynyl, C3-C5-cycloalkyl, C3-C5-halocycloalkyl, C3-C5-cycloalkyl-methyl-, C3-C5-cycloalkyl substituted with a CN group, C1-C4-alkyl substituted with a CN group, C1-C4-alkoxy and C1-C4-haloalkoxy;
- each R81 is independently selected from OH, CN, C3-C6-cycloalkyl C3-C6-cycloalkyl which carries a CN substituent, C3-C6-cycloalkyl which carries a C1-haloalkyl substituent, C3-C6-halocycloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, —C(═O)N(R101c)R101d, phenyl, phenyl substituted with up to 5 substituents R16, and the heterocyclic ring selected from the rings of formulae E-1 to E-63;
- R91 is selected from hydrogen, C1-C6-alkyl and C1-C6-haloalkyl;
- R101a, R101c and R111a are independently selected from hydrogen and C1-C6-alkyl;
- R101b is selected from hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C4-alkenyl, C2-C4-alkynyl, CH2—CN, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkylmethyl, C3-C6-halocycloalkylmethyl, phenyl, phenyl substituted with up to 5 substituents R16;
- and a heterocyclic ring selected from rings of formulae E-1 to E-42 as defined above;
- R101d and R111b are independently selected from hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C3-C6-cycloalkyl C3-C6-cycloalkyl which carries a CN substituent, C3-C6-halocycloalkyl, C3-C6-cycloalkylmethyl and C3-C6-halocycloalkylmethyl;
- each R16 is independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C2-C4-haloalkynyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl, C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, aminocarbonyl, C1-C4-alkylaminocarbonyl and di-(C1-C4-alkyl)aminocarbonyl;
- and at least one of the N-oxides, stereoisomers and agriculturally or veterinarily acceptable salts thereof.
33 more elements
(canceled)
(canceled)
Dependencies are inferred from the claim text.