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US 2017/0362505 A1Published application
Compounds having a c-c triple bond
AssigneeMerck Patent GmbH
InventorsChristian JASPER, Constanze BROCKE, Detlef PAULUTH, Volker REIFFENRATH, Atsutaka MANABE
Life of this patent
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Abstract
Compounds containing at least one C—C triple bond within a chain of at least 3 ring systems which have positive dielectric anisotropy, the use thereof for high-frequency components, liquid-crystalline media containing these compounds, and high-frequency components, in particular antennae, especially for the gigahertz region, containing these media. The liquid-crystalline media serve, for example, for the phase shifting of microwaves for tuneable phased-array antennae.
Claims24
A compound of formula I
- in which
- H/F means F,
- A1-5 each, independently of one another, denotes
- L each denotes F,
- R1 denotes a halogenated or unsubstituted alkyl radical having 1 to 15 C atoms, in which one or more CH2 groups may each be replaced, independently of one another, by —C≡C—, —CH═CH—, —CF═CF—, —CF═CH—, —CH═CF—, —(CO)O—, —O(CO)—, —(CO)—, —O— or —S— in such a way that O or S atoms are not linked directly to one another,
- or denotes F, Cl, Br, CN, CF3, OCF3, SCN, NCS or SF5,
- X denotes
- Z1, Z2, Z4, Z5 each, independently of one another, denotes a single bond, —C≡C—, —CH═CH—, —CH2O—, —(CO)O—, —CF2O—, —CF2CF2—, —CH2CF2—, —CH2CH2—, —(CH2)4—, —CH═CF— or —CF═CF—, where asymmetrical bridges may be oriented to either side, and
- m, n, p, q independently denote 0 or 1, where m+n+p+q is 1, 2, 3 or 4.
6 more elements
2-3. (canceled)
(canceled)
9-12. (canceled)
(canceled)
Dependencies are inferred from the claim text.