Moisture and Radiation Curable Adhesive Composition and the Use Thereof

A moisture and radiation curable adhesive composition, comprising:

• (a) at least one mono(meth)acryloxy terminated polyorganosiloxane represented by the formula:
• wherein,
• R1 to R9 are each independently selected from the group consisting of C1-C20 alkyl, C1-C20 alkoxyl, C2-C20 alkenyl, C3-C20 cycloalkyl, and C7-C22 aralkyl, with the proviso that at least one of R1 to R9 is C1-C20 alkoxyl,
• m is an integer of from 1 to 1000,
• A1 is represented by the formula (2):
• (R10)a(R11)b(R12)cR13 (2)
• wherein:
• R10 is C1-C20 alkylene,
• R11 is C6-C21 arylene,
• R12 is C1-C20 alkylene,
• R13 is (meth)acryloxy,
• a is an integer of from 0 to 10,
• b is an integer of from 0 to 10, and
• c is an integer of from 0 to 10;
• (b) at least one di(meth)acryloxy terminated polyorganosiloxane represented by the formula:
• wherein:
• R14 to R21 are each independently selected from the group consisting of C1-C20 alkyl, C1-C20 alkoxyl, C2-C20 alkenyl, C3-C20 cycloalkyl, and C7-C22 aralkyl,
• with the proviso that at least one of R1 to R9 is C1-C20 alkoxyl,
• n is an integer of from 1 to 1000,
• A2 and A3 are each independently represented by the formula:
• (R22)d(R23)e(R24)fR25 (4)
• wherein:
• R22 is C1-C20 alkylene,
• R23 is C6-C21 arylene,
• R24 is C1-C20 alkylene,
• R25 is (meth)acryloxy,
• d is an integer of from 0 to 10,
• e is an integer of from 0 to 10, and
• f is an integer of from 0 to 10;
• (c) a photoinitiator;
• (d) a moisture curing catalyst;
• (e) optionally, a chain extender;
• and
• (f) optionally, a moisture crosslinker.